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We consider the van der Waals interaction of an excited atom and a ground state atom across a vacuum-medium interface under the circumstances of the resonant coupling of the excited atom to a surface polariton mode of the system. We…

Quantum Physics · Physics 2015-05-13 Marin-Slobodan Tomas

When the vacuum is partitioned by material boundaries with arbitrary shape, one can define the zero-point energy and the free energy of the electromagnetic waves in it: this can be done, independently of the nature of the boundaries, in the…

Quantum Physics · Physics 2007-05-23 Roger Balian , Bertrand Duplantier

The van der Waals interaction between two polarizable atoms is considered. In three dimensions the standard form with an attractive $1/|R|^6$ potential is obtained from second-order quantum perturbation theory. When the electron motion is…

Quantum Physics · Physics 2015-01-22 A. C. Ipsen , K. Splittorff

We consider the interatomic van der Waals interaction energy between two neutral ground-state atoms moving in the vacuum space with the same uniform acceleration. We assume the acceleration orthogonal to their separation, so that their…

Quantum Physics · Physics 2013-07-25 Antonio Noto , Roberto Passante

It is familiar that the Casimir self-energy of a homogeneous dielectric ball is divergent, although a finite self-energy can be extracted through second order in the deviation of the permittivity from the vacuum value. The exception occurs…

High Energy Physics - Theory · Physics 2018-03-02 Kimball Milton , Iver Brevik

We calculate the Casimir force or dispersive van der Waals force between a spherical nanoparticle and a planar substrate, both with arbitrary dielectric properties. We show that the force between a sphere and a plane can be calculated…

Other Condensed Matter · Physics 2007-05-23 Cecilia Noguez , C. Roman-Velazquez

We have calculated dynamical Casimir-Polder interaction force between a moving ground state atom and a flat polarizable surface. The velocity of an atom can be close to the velocity of light. The material properties are taken into account…

Other Condensed Matter · Physics 2015-05-28 G. V. Dedkov , A. A. Kyasov

Initially, we make a detailed historical survey of van der Waals forces, collecting the main references on the subject. Then, we review a method recently proposed by Eberlein and Zietal to compute the dispersion van der Waals interaction…

Quantum Physics · Physics 2016-07-25 Reinaldo de Melo e Souza , W. J. M. Kort-Kamp , C. Sigaud , C. Farina

We examine the dipole approximated Pauli-Fierz Hamiltonians of the nonrelativistic QED. We assume that the Coulomb potential of the nuclei together with the Coulomb interaction between the electrons can be approximated by harmonic…

Mathematical Physics · Physics 2020-04-28 Tadahiro Miyao

We consider the the van der Waals force involving excited atoms in general environments, constituted by magnetodielectric bodies. We develop a dynamical approach studying the dynamics of the atoms and the field, mutually coupled. When only…

Quantum Physics · Physics 2017-02-24 Pablo Barcellona , Roberto Passante , Lucia Rizzuto , Stefan Yoshi Buhmann

The structure and stability of atomic and molecular systems with van der Waals (vdW) bonding are often determined by the interplay between attractive dispersion interactions and repulsive interactions caused by electron confinement. Arising…

Chemical Physics · Physics 2022-02-17 Ornella Vaccarelli , Dmitry V. Fedorov , Martin Stöhr , Alexandre Tkatchenko

This contribution briefly reviews some recent work demonstrating the partial breakdown of the colloidal fluid <--> atomic fluid analogy. The success of liquid state theory for atomic fluids stems in part from the van der Waals picture,…

Soft Condensed Matter · Physics 2009-11-07 A. A. Louis

By using the recently generalized version of Newton Shell Theorem [3] analytical equations are derived to calculate the electric interaction energy between two charged spheres, a small one is located within a larger one, and each sphere is…

Soft Condensed Matter · Physics 2021-04-13 István P. Sugár

Values for the vacuum energy of scalar fields under Dirichlet and Neuman boundary conditions on an infinite clylindrical surface are found, and they happen to be of opposite signs. In contrast with classical works, a complete zeta function…

High Energy Physics - Theory · Physics 2009-10-31 P. Gosdzinsky , A. Romeo

We consider a multiatomic system where the nuclei are assumed to be point charges at fixed positions. Particles interact via Coulomb potential and electrons have pseudo-relativistic kinetic energy. We prove the van der Waals-London law,…

Mathematical Physics · Physics 2022-11-16 Jean-Marie Barbaroux , Michael Hartig , Dirk Hundertmark , Semjon Vugalter

The interactions between atoms and molecules may be described by a potential energy function of the nuclear coordinates. Non-bonded interactions are dominated by repulsive forces at short range and attractive dispersion forces at long…

A calculation of the inelastic scattering rate of Xe atoms on Cu(111) is presented. We focus in the regimes of low and intermediate velocities, where the energy loss is mainly associated to the excitation electron-hole pairs in the…

Materials Science · Physics 2007-05-23 Maider Machado , Daniel Sanchez-Portal

We propose a practical approach to spin-polarized systems within the van der Waals density functional (vdW-DF). The method was applied to a gas phase oxygen molecule and a parallel (H-type) pair of oxygen molecules. It was found that vdW-DF…

Materials Science · Physics 2013-10-16 Masao Obata , Makoto Nakamura , Ikutaro Hamada , Tatsuki Oda

We studied the van der Waals interactions of two finite, solid, cylindrical rods at arbitrary angle and position with respect to each other. An analytic interpolative formula for the interaction potential energy is constructed, based on…

Soft Condensed Matter · Physics 2018-10-03 Jack A. Logan , Alexei V. Tkachenko

Theories for the effective polarisability of a small particle in a medium are presented using different levels of approximation: we consider the virtual cavity, real cavity and the hard-sphere models as well as a continuous interpolation of…