Related papers: CO adsorption on neutral iridium clusters
The adsorption kinetics of CO on PdAu bimetallic clusters, containing 140 $\pm$ 12 atoms and a composition varying between 0% and 55% of Pd atoms, is investigated by a pulsed molecular beam method (MBRS). The clusters are grown on a…
A sample of 59 sight lines to reddened Galactic OB stars was examined for correlations of the strength of the CO Fourth Positive (A - X) absorption band system with the ultraviolet interstellar extinction curve parameters. We used archival…
Boron clusters have been widely studied theoretically for their geometrical properties and electronic structure using a variety of methodologies. An important cluster of boron is the B$_{12}$ cluster whose two main isomers have distinct…
Data from the Five College Radio Astronomy Observatory CO Mapping Survey of the Taurus molecular cloud are combined with extinction data for a sample of 292 background field stars to investigate the uptake of CO from the gas to icy grain…
The adsorption of CO molecules at the Ca3Ru2O7(001) surface was studied using low-temperature scanning tunneling microscopy (STM) and density functional theory (DFT). Ca3Ru2O7 can be easily cleaved along the (001) plane, yielding a smooth,…
We present the first large sample of absorption systems in paired QSOs consisting of 691 absorption systems in the spectra of 310 QSOs including 170 pairings. All these absorption systems have metal lines, usually C IV or Mg II. We see 17…
The adsorption of CO on unreconstructed and reconstructed Ir{100} has been studied, using a combination of density functional theory and thermodynamics, to determine the relative stability of the two phases as a function of CO coverage,…
Using first-principles calculations, we systematically study the adsorption behaviors of molecular CO on the Be (0001) surface. By calculating the potential energy surfaces, we find that CO molecularly adsorbs on the Be surface with small…
The linear optical absorption spectra in neutral boron cluster B$_{6}$ and cationic B$_{6}^{+}$ are calculated using a first principles correlated electron approach. The geometries of several low-lying isomers of these clusters were…
Using Voigt-profile-fitting procedures on Keck HIRES spectra of nine QSOs we identify 1099 CIV absorber components clumped in 201 systems outside the Lyman forest over 1.6 < z < 4.4. With associated SiIV, CII, SiII and NV where available we…
The high resolution (R=25,000) infrared M band spectrum of the massive protostar NGC 7538 : IRS9 shows a narrow absorption feature at 4.779 um (2092.3 cm-1) which we attribute to the vibrational stretching mode of the 13CO isotope in pure…
Far-infrared vibrational spectroscopy by multiple photon dissociation has proven to be a very useful technique for the structural fingerprinting of small metal clusters. Contrary to previous studies on cationic V, Nb and Ta clusters,…
Overdense, metal-rich regions, shielded from stellar radiation might remain neutral throughout reionization and produce metal as well as 21 cm absorption lines. Simultaneous absorption from metals and 21 cm can complement each other as…
To investigate the composition and evolution of circumstellar ice around low-mass YSOs, we observed ice absorption bands in the near infrared (NIR) towards eight YSOs ranging from class 0 to class II, among which seven are associated with…
Narrow absorption lines seen in the 2-10 keV spectra of active galaxies and Galactic black holes are normally attributed to iron in high velocity outflows or inflows. We consider the possibility that such features could arise naturally in…
Both high resolution spectra of QSOs observed at the 8-10m telescopes and advanced methods of data analysis are crucial for accurate measurements of the chemical composition and physical parameters of the intervening clouds. An overview of…
Contents: 5.1 Introduction 5.2 Concepts and definitions 5.3 The tight-binding picture of bonding 5.4 Adsorption of isolated adatoms 5.5 Alkali-metal adsorption: the traditional picture of on-surface adsorption 5.6 Substitutional adsorption…
In this paper we propose a tight-binding molecular dynamics with parameters fitted to first-principles calculations on the smaller clusters and with an environment correction, to be a powerful technique for studying large transition/noble…
Carbon monoxide (CO) is a significant indicator gas with considerable application value in atmospheric monitoring, industrial production and medical diagnosis. Its fundamental vibrational band locates around 4.6 $\upmu$m and has larger…
With the recent radioastronomical detection of cis-trans-carbonic acid (H$_2$CO$_3$) in a molecular cloud toward the galactic center, the more stable but currently unobserved cis-cis conformer is shown here to have strong IR features. While…