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Single linear polymer chains in dilute solutions under good solvent conditions are studied by Monte Carlo simulations with the pruned-enriched Rosenbluth method up to the chain length $N \sim {\cal O}(10^4)$. Based on the standard simple…

Soft Condensed Matter · Physics 2015-06-24 Hsiao-Ping Hsu

We study uniform 3-star polymers with one branch tethered to an attractive surface and another branch pulled by a force away from the surface. Each branch of the 3-star lattice is modelled as a self-avoiding walk on the simple cubic lattice…

Statistical Mechanics · Physics 2019-05-30 C J Bradly , A L Owczarek

The structural features of polystyrene brushes grafted on spherical silica nanoparticles immersed in polystyrene are investigated by means of a Monte Carlo methodology based on polymer mean field theory. The nanoparticle radii (either 8 nm…

Soft Condensed Matter · Physics 2014-01-17 Georgios G. Vogiatzis , Doros N. Theodorou

We grafted polyacrylic acid brushes containing cysteine side chains at a defined surface density on planar lipid membranes. Specular X-ray reflectivity data indicated that the addition of Cd2+ ions induces the compaction of the polymer…

Soft Condensed Matter · Physics 2022-03-29 Felix Weissenfeld , Lucia Wesenberg , Masaki Nakahata , Marcus Müller , Motomu Tanaka

Using extensive Monte Carlo simulations, we investigate the surface adsorption of self-avoiding trails on the triangular lattice with two- and three-body on-site monomer-monomer interactions. In the parameter space of two-body, three-body,…

Statistical Mechanics · Physics 2020-01-01 Nathann T. Rodrigues , Tiago J. Oliveira , Thomas Prellberg , Aleksander L. Owczarek

Polymer adsorption on fractally rough walls of varying dimensionality is studied by renormalization group methods on hierarchical lattices. Exact results are obtained for deterministic walls. The adsorption transition is found continuous…

Statistical Mechanics · Physics 2007-05-23 G. Giugliarelli , A. L. Stella

In this paper we present simulations of a surface-adsorbed polymer subject to an elongation force. The polymer is modelled by a self-avoiding walk on a regular lattice. It is confined to a half-space by an adsorbing surface with attractions…

Statistical Mechanics · Physics 2007-05-23 J. Krawczyk , T. Prellberg , A. Rechnitzer , A. L. Owczarek

We study the problem of adsorption of self-interacting linear polymers situated in fractal containers that belong to the three-dimensional (3d) Sierpinski gasket (SG) family of fractals. Each member of the 3d SG fractal family has a fractal…

Statistical Mechanics · Physics 2009-11-07 S. Elezovic-Hadzic , I. Zivic , S. Milosevic

We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the…

Soft Condensed Matter · Physics 2016-10-05 Sidney J. de Carvalho , Ralf Metzler , Andrey G. Cherstvy

The irreversible adsorption of polymers to a two-dimensional solid surface is studied. An operator formalism is introduced for chemisorption from a polydisperse solution of polymers which transforms the analysis of the adsorption process to…

Chemical Physics · Physics 2009-11-13 Radek Erban , Jonathan Chapman

The adsorption of a single polymer to a flat surface in shear is investigated using Brownian hydrodynamics simulations and scaling arguments. Competing effects are disentangled: in the absence of hydrodynamic interactions, shear drag…

Soft Condensed Matter · Physics 2015-05-20 Andreas Serr , Christian Sendner , Florian Mueller , Thomas R. Einert , Roland R. Netz

Nonequilibrium molecular dynamics simulations are used to study the shear thinning behavior of immiscible symmetric polymer blends. The phase separated polymers are subjected to a simple shear flow imposed by moving a wall parallel to the…

Soft Condensed Matter · Physics 2009-11-07 Sandra Barsky , Mark O. Robbins

The adsorption of a single ideal polymer chain on energetically heterogeneous and rough surfaces is investigated using a variational procedure introduced by Garel and Orland (Phys. Rev. B 55 (1997), 226). The mean polymer size is calculated…

Statistical Mechanics · Physics 2009-10-31 Gregor Huber , Thomas A. Vilgis

We study the effect of interfacial phenomena in two-dimensional perfect and random (or disordered) $q$-state Potts models with continuous phase transitions, using, mainly, Monte Carlo techniques. In particular, for the total interfacial…

Statistical Mechanics · Physics 2015-08-10 N. G. Fytas , A. Malakis , W. Selke , L. N. Shchur

We deduce the qualitative phase diagram of a long flexible neutral polymer chain immersed in a poor solvent near an attracting surface using phenomenological arguments. The actual positions of the phase boundaries are estimated numerically…

Statistical Mechanics · Physics 2009-11-07 R. Rajesh , Deepak Dhar , Debaprasad Giri , Sanjay Kumar , Yashwant Singh

Hydrophobically modified polymers are good candidates for the stabilization of liquid interfaces thanks to the high anchoring energy of the hydrophobic parts. In this article we probe the interfacial anchoring of a series of home-made…

Applied Physics · Physics 2019-03-04 C. Trégouët , Thomas Salez , N. Pantoustier , P. Perrin , M. Reyssat , C. Monteux

Large scale Monte Carlo simulations of dense layers of grafted polymer chains in good solvent conditions are used to explore the relaxation of a polymer brush. Monomer displacements are analyzed for the directions parallel and perpendicular…

Soft Condensed Matter · Physics 2021-04-13 Michael Lang , Marco Werner , Ron Dockhorn , Torsten Kreer

Using non-equilibrium Brownian dynamics computer simulations, we have investigated the steady state statistics of a polymer chain under three different shear environments: i) linear shear flow in the bulk (no walls), ii) shear vorticity…

Soft Condensed Matter · Physics 2015-05-14 Gui-Li He , René Messina , Hartmut Löwen

The behavior of a polyelectrolyte adsorbed on a charged surface of high-dielectric constant is studied by both Monte-Carlo simulation and analytical methods. It is found that in a low ionic strength medium, the transition is first-order…

Soft Condensed Matter · Physics 2007-05-23 Chi-Ho Cheng , Pik-Yin Lai

We study the influence of chain stiffness on droplet flow in a nano-channel, coated with semiflexible hydrophobic polymers by means of non-equilibrium molecular-dynamics simulations. The studied system is then a moving droplet in the slit…

Soft Condensed Matter · Physics 2017-10-18 Kevin Speyer , Claudio Pastorino
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