English
Related papers

Related papers: Conformational Studies of bottle-brush polymers ab…

200 papers

We study the conformational behavior of a polymer adsorbed at an attractive nanostring and construct the complete structural phase diagram in dependence of the binding strength and effective thickness of the string. For this purpose, Monte…

Soft Condensed Matter · Physics 2011-03-11 Thomas Vogel , Michael Bachmann

The influence of long-range correlated surface and decaying near surface disorder with quenched defects is studied. We consider a correlation function for the defects of the form $\frac{e^{-z/\xi}}{r^{a}}$, where $a<d-1$ and $z$ being the…

Soft Condensed Matter · Physics 2009-10-08 Z. Usatenko , J. -U. Sommer

We use density functional theory to investigate adsorption of liquid mixtures on solid surfaces modified with end-grafted chains. The chains are modelled as freely joined spheres. The fluid molecules are spherical. All spherical species…

Soft Condensed Matter · Physics 2016-03-08 M. Borówko , T. Staszewski

A comparative simulation study of polymer brushes formed by grafting at a planar surface either flexible linear polymers (chain length $N_L$) or (non-catenated) ring polymers (chain length $N_R=2 N_L$) is presented. Two distinct off-lattice…

Soft Condensed Matter · Physics 2015-05-28 Daniel Reith , Andrey Milchev , Peter Virnau , Kurt Binder

We analyze equilibrium properties and adsorption desorption phase transition behaviour of a linear semiflexible copolymer chain under constrained geometrical situation on square lattice in a good solvent. One dimensional stair shaped line…

Statistical Mechanics · Physics 2010-06-04 Pramod Kumar Mishra

The behavior of a strongly charged polymer adsorbed on an oppositely charged surface of low-dielectric constant is formulated by the functional integral method. By separating the translational, conformational, and fluctuational degrees of…

Soft Condensed Matter · Physics 2007-05-23 Chi-Ho Cheng , Pik-Yin Lai

Lattice model of directed self avoiding walk has been solved analytically to investigate adsorption desorption phase transition behaviour of a semiflexible sequential copolymer chain on a two dimensional impenetrable surface perpendicular…

Statistical Mechanics · Physics 2010-02-23 Pramod Kumar Mishra

The monolayer adsorption process of interacting binary mixtures of species $A$ and $B$ on square lattices is studied through grand canonical Monte Carlo simulation in the framework of the lattice-gas model. Four different energies have been…

Chain-like macromolecules (polymers) show characteristic adsorption properties due to their flexibility and internal degrees of freedom, when attracted to surfaces and interfaces. In this review we discuss concepts and features that are…

Soft Condensed Matter · Physics 2009-11-07 Roland Netz , David Andelman

We report molecular dynamics simulation results on the equilibrium properties of polymer thin films adsorbed onto flat and curved substrates. We first systematically determine the contact angle of polymer droplets on flat substrates as a…

Soft Condensed Matter · Physics 2023-12-15 Gabriel Catalini , Nicolás A. García , Daniel A. Vega , Arash Nikoubashman

Non equilibrium coarse grained, dissipative particle dynamics simulations of complex fluids, made up of polymer brushes tethered to planar surfaces immersed in a solvent yield non monotonic behavior of the friction coefficient as a function…

Soft Condensed Matter · Physics 2017-02-01 E. Mayoral , J. Klapp , A. Gama Goicochea

We present a Monte Carlo study of the surface anchoring of a nematic fluid on swollen layers of grafted liquid crystalline chain molecules. The liquid crystalline particles are modeled by soft repulsive ellipsoids, and the chains are made…

Materials Science · Physics 2009-11-07 Harald Lange , Friederike Schmid

We review quantum Monte Carlo results on energetic and structure properties of quantum fluids adsorbed in a bundle of carbon nanotubes. Using realistic interatomic interactions the different adsorption sites that a bundle offer are…

Materials Science · Physics 2015-05-13 M. C. Gordillo , J. Boronat

Using a coarse-grained bead-spring model for semi-flexible macromolecules forming a polymer brush, structure and dynamics of the polymers is investigated, varying chain stiffness and grafting density. The anchoring condition for the grafted…

Soft Condensed Matter · Physics 2014-01-28 Andrey Milchev , Kurt Binder

A comparative dynamic Monte Carlo simulation study of polydisperse living polymer brushes, created by surface initiated living polymerization, and conventional polymer monodisperse brush, comprising linear polymer chains, grafted to a…

Soft Condensed Matter · Physics 2012-12-04 K. Jalili , F. Abbasi , A. Milchev

We propose a theoretical investigation of the physical adsorption of neutral comb-polymers with an adsorbing skeleton and non-adsorbing side-chains on a flat surface. Such polymers are particularly interesting as "dynamic coating" matrices…

Soft Condensed Matter · Physics 2009-11-11 Anna Sartori , Albert Johner , Jean-Louis Viovy , Jean-Francois Joanny

The subject of this work is the adsorption transition of a long flexible self-avoiding polymer chain onto a rigid thin rod. The rod is represented by a cylinder of radius R with a short-ranged attractive surface potential for the chain…

Statistical Mechanics · Physics 2009-11-11 Andreas Hanke

Polymer brushes normally swell in a good solvent and collapse in a poor solvent. An abnormal response of polymer brushes, so-called co-nonsolvency, is the phenomenon where the brush counter-intuitively collapses in a good solvent mixture.…

Soft Condensed Matter · Physics 2019-08-26 Gyehyun Park , YounJoon Jung

Using Molecular Dynamics simulations, we study the force-induced detachment of a coarse-grained model polymer chain from an adhesive substrate. One of the chain ends is thereby pulled at constant speed off the attractive substrate and the…

Soft Condensed Matter · Physics 2015-06-22 J. Paturej , A. Erbas , A. Milchev , V. G. Rostiashvili

Conformations of partially or fully adsorbed semiflexible polymer chains are studied varying both contour length $L$, chain stiffness, $\kappa$, and the strength of the adsorption potential over a wide range. Molecular Dynamics simulations…

Soft Condensed Matter · Physics 2019-10-02 Andrey Milchev , Kurt Binder