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Newly published diffraction data on hexagonal YMnO3 at a temperature of 10 K are shown to be consistent with a trusted expression of the magnetic symmetry, although the data alone are not definitive [M. Ramakrishnan et al., Phys. Rev.…

Strongly Correlated Electrons · Physics 2023-05-10 S. W. Lovesey

We report inelastic neutron scattering measurements of the phonon spectra in a pure powder sample of the multiferroic material BiFeO3. A high-temperature range was covered to unravel the changes in the phonon dynamics across the Neel (T_N ~…

Materials Science · Physics 2015-03-19 M. Zbiri , H. Schober , N. Choudhury , R. Mittal , S. L. Chaplot , S. J. Patwe , S. N. Achary , A. K. Tyagi

The X-ray diffraction, Raman and infrared spectroscopies and magnetic measurements were used to explore the correlated changes of the structure, lattice dynamics and magnetic properties of the LuFeO3 nanoparticles, which appear in…

Group theoretical aspects of the three temperature-dependent and temperature-reversible experimentally observed phase transitions in the KNbO3 crystal (cubic-tetragonal, tetragonal-orthorhombic, orthorhombic-rhombohedral) in the framework…

Materials Science · Physics 2024-11-05 R. A. Evarestov , Yu. E. Kitaev , S. S. Novikov

The structural properties of BiMn$O_3$ were determined from neutron powder diffraction data as a function of temperature and magnetic field. The structure at all temperatures was found to be centrosymmetric with space group $C2/c$, which is…

Strongly Correlated Electrons · Physics 2009-11-13 E. Montanari , G. Calestani , L. Righi , E. Gilioli , F. Bolzoni , K. S. Knight , P. G. Radaelli

We report a detailed high-temperature powder neutron diffraction investigation of the structural behavior of the multiferroic GaFeO3 between 296 and 1368 K. Temperature dependent neutron diffraction patterns do not show any appreciable…

Materials Science · Physics 2015-06-12 S. K. Mishra , R. Mittal , R. Singh , M. Zbiri , T. Hansen , H. Schober

The present study reports on the structural and magnetic phase transitions in Pr-doped polycrystalline Tb0.6Pr0.4MnO3, using high-resolution neutron powder diffraction (NPD) collected at SINQ spallation source (PSI), to emphasize the…

Materials Science · Physics 2021-07-07 Harshit Agarwal , Jose A Alonso , Ángel Muñoz , R J Choudhary , O N Srivastava , M A Shaz

Hexagonal RMnO3 manganites are improper ferroelectrics in which the electric polarization is a by-product of the tripling of the unit cell. In YMnO3, there is a second transition at ~ 920K whose nature remains unexplained. We argue that…

Materials Science · Physics 2014-08-12 A. Cano

A detailed investigation using variable temperature powder neutron diffraction demonstrates that BiFeO3 undergoes a phase transition from the ferroelectric alpha phase (rhombohedral, R3c) to a paraelectric beta phase (orthorhombic, Pbnm)…

Materials Science · Physics 2009-08-21 Donna C. Arnold , Kevin S. Knight , Finlay D. Morrison , Philip Lightfoot

Up to now the crystallographic structure of the magnetoelectric perovskite EuTiO3 was considered to remain cubic down to low temperature. Here we present high resolution synchrotron X-ray powder diffraction data showing the existence of a…

An ac photopyroelectric calorimeter has been used to simultaneously measure the specific heat, thermal conductivity, and thermal diffusivity around the antiferromagnetic to paramagnetic phase transition in KMnF3. It has been found that the…

Materials Science · Physics 2016-09-08 A. Salazar , M. Massot , A. Oleaga , A. Pawlak , W. Schranz

Terahertz and far-infrared electric and magnetic responses of hexagonal piezomagnetic YMnO3 single crystals are investigated. Antiferromagnetic resonance is observed in the spectra of magnetic permeability mu_a [H(omega) oriented within the…

Materials Science · Physics 2012-02-13 C. Kadlec , V. Goian , K. Z. Rushchanskii , P. Kuzel , M. Lezaic , K. Kohn , R. V. Pisarev , S. Kamba

Contrary to previous studies that identified the ground state crystal structure of the entire R_3Co series (R is a rare earth) as orthorhombic Pnma, we show that Y_3Co undergoes a structural phase transition at T_t=160K. Single crystal…

Materials Science · Physics 2013-07-18 A. Podlesnyak , G. Ehlers , H. Cao , M. Matsuda , M. Frontzek , O. Zaharko , V. A. Kazantsev , A. F. Gubkin , N. V. Baranov

The crystal and magnetic structures of single-crystalline hexagonal LuFeO$_3$ films have been studied using x-ray, electron and neutron diffraction methods. The polar structure of these films are found to persist up to 1050 K; and the…

We have carried out the powder x-ray diffraction and dielectric studies on multiferroic particulate composite xNi0.9Zn0.1Fe2O4/(1-x)PbZr0.52Ti0.48O3 with x=0.15, 0.30, 0.45, 0.60, 0.75 and 0.90 to explore the structural and ferroelectric…

Materials Science · Physics 2014-02-20 Rishikesh Pandey , Braj Raj Meena , Akhilesh Kumar Singh

Specific heat studies of the Sr$_{1-x}$Ba$_x$Mn$_{1-y}$Ti$_y$O$_3$ polycrystalline samples performed by the relaxation and DSC methods over the temperature range 2 - 450 K are reported. Anomalies accompanying the…

Statistical Mechanics · Physics 2025-07-31 J. Wieckowski , A. Szewczyk , M. U. Gutowska , B. Dabrowski

The switching characteristics of ferroelectrics and multiferroics are influenced by the interaction of topological defects with domain-walls. We report on the pinning of polarization due to antiphase boundaries in thin films of the…

Materials Science · Physics 2024-12-04 Guodong Ren , Pravan Omprakash , Xin Li , Yu Yun , Arashdeep S. Thind , Xiaoshan Xu , Rohan Mishra

Pb(Fe$_{0.5}$Nb$_{0.5}$)O$_3$ (PFN), one of the few relaxor multiferroic systems, has a $G$-type antiferromagnetic transition at $T_N$ = 143 K and a ferroelectric transition at $T_C$ = 385 K. By using high-resolution neutron-diffraction…

The (H,T)-phase diagram of the multiferroic perovskite TbMnO$_3$ was studied by high-resolution thermal expansion $\alpha(T)$ and magnetostriction $\Delta L(H)/L$ measurements. Below $T_{N}\simeq 42$ K, TbMnO$_3$ shows antiferromagnetic…

Strongly Correlated Electrons · Physics 2009-11-13 D. Meier , N. Aliouane , D. N. Argyriou , J. A. Mydosh , T. Lorenz

YCrO3 which has a monoclinic structure, shows weak ferromagnetism below 140 K (TN) and a ferroelectric transition at 473 K accompanied by hysteresis. We have determined the structure and energetics of YCrO3 with ferromagnetic and…

Materials Science · Physics 2007-05-23 Claudy Rayan Serrao , Asish K. Kundu , S. B. Krupanidhi , Umesh V. Waghmare , C. N. R. Rao
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