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Temperature-dependent FAR-infrared reflectivity spectra of partially ordered magnetodielectric La2CoMnO6 is presented, from room temperature up to 675 K. A clear first-ordered structural phase transition (SPT) from a monoclinic structure…

Materials Science · Physics 2018-02-22 R. X. Silva , A. Nonato , R. L. Moreira , R. M. Almeida , C. W. A. Paschoal

Neutron scattering techniques have been used to study the relaxor ferroelectric 0.68PbMg1/3Nb2/3O3-0.32PbTiO3 denoted in this paper as 0.68PMN-0.32PT. On cooling, these relaxor ferroelectrics have a long-range ordered ferroelectric phase…

Materials Science · Physics 2007-05-23 S. N. Gvasaliya , B. Roessli , R. A. Cowley , S. Kojima , S. G. Lushnikov

We report on TmMnO3 far infrared emissivity and reflectivity spectra from 1910 K to 4 K. At the highest temperature the number of infrared bands is lower than that predicted for centrosymmetric P63/mmc (D6h4) (Z=2) space group due high…

The dielectric constant of multiferroic hexagonal HoMnO_3 exhibits an unprecedented diversity of anomalies at low temperatures (1.8 K< T <10 K) and under external magnetic fields related to magnetic phase transitions in the coupled system…

Strongly Correlated Electrons · Physics 2009-11-11 F. Yen , C. R. dela Cruz , B. Lorenz , Y. Y. Sun , Y. Q. Wang , M. M. Gospodinov , C. W. Chu

We report the temperature dependent THz to mid-infrared response of hexagonal-ErMnO3 using absorption, reflectivity, and emissivity techniques from 2 K to 1700 K. At low temperatures, lowest frequency vibrational modes coexist with…

Polycrystalline sample of (Ba_{0.90}Pb_{0.10})(Ti_{0.90}Sn_{0.10})O_3 was obtained by means of a conventional ceramic technology. The dielectric measurements were performed depending on temperature and frequency of electric measuring field.…

Materials Science · Physics 2013-09-25 C. Kajtoch , W. Bąk , B. Garbarz-Glos

Piezoelectric and ferroelectric ceramics with a high Curie temperature (Tc) have attracted a growing attention owning to their applications under severe environments. In this work, phase structure, dielectric, ferroelectric and…

The authors of paper commented claim that trimethylammonium tetrachlorozincate crystal shows at 282 K the ferroelectric-paraelectric phase transition. But no ferroelectric hysteresis loop was observed below this temperature. Moreover, in…

Materials Science · Physics 2016-04-07 Zbigniew Tylczynski

Dielectric study over a broadband was carried out from 10 to 70 K on ceramic Gd1-xYxMnO3 (x= 0.2, 0.3, and 0.4). For all the compositions, a prominent sharp peak about ~18K was observed in the temperature dependence of both {\epsilon}'(T)…

Materials Science · Physics 2017-06-28 R. M. Sarguna , V. Sridahran , A. M. Awasthi , N. Subramanian

We report the magnetic susceptibility, specific heat and dielectric constant on high purity polycrystalline samples of three hexagonal manganites: YMnO_3, LuMnO_3 and ScMnO_3. These materials can exhibit a ferroelectric transition at very…

Materials Science · Physics 2007-05-23 D. G. Tomuta , S. Ramakrishnan , G. J. Nieuwenhuys , J. A. Mydosh

The structural and magnetic properties of YVO3, NdVO3 and TbVO3 were investigated by single-crystal and powder neutron diffraction. YVO3 shows a structural phase transition at 200 K from an orthorhombic structure with the space group Pbnm…

Strongly Correlated Electrons · Physics 2009-11-11 M. Reehuis , C. Ulrich , P. Pattison , B. Ouladdiaf , M. C. Rheinstadter , M. Ohl , L. P. Regnault , M. Miyasaka , Y. Tokura , B. Keimer

We report on the microwave, terahertz (THz), infrared and Raman spectroscopic studies of $BiMn_{7}O_{12}$ ceramics, shedding more light into the nature of two structural phase transitions and their possible relation with ferroelectricity in…

Materials Science · Physics 2024-01-08 A. Maia , M. Kempa , V. Bovtun , R. Vilarinho , C. Kadlec , J. Agostinho Moreira , A. A. Belik , P. Proschek , S. Kamba

The interaction of coexisting structural instabilities in multiferroic materials gives rise to intriguing coupling phenomena and extraordinarily rich phase diagrams, both in bulk materials and strained thin films. Here we investigate the…

We report an investigation of hexagonal Y_(1-x)Eu_xMnO_3 ceramics with x=0, 0.1 and 0.2 using infrared and THz spectroscopies in the temperature range between 5 and 900 K. The temperature dependence of the THz permittivity reveals a kink…

Materials Science · Physics 2012-02-13 V. Goian , S. Kamba , C. Kadlec , D. Nuzhnyy , P. Kuzel , J. Agostinho Moreira , A. Almeida , P. B. Tavares

Motivated by the recent neutron diffraction experiment on $YVO_3$, we consider a microscopic model where each $V^{3+}$ ion is occupied by two 3d electrons of parallel spins with two fold degenerate orbital configurations. The mean field…

Strongly Correlated Electrons · Physics 2007-05-23 Theja N. De Silva , Anuvrat Joshi , Michael Ma , Fu Chun Zhang

Hexagonal rare-earth ferrite RFeO$_3$ family represents a unique class of multiferroics exhibiting weak ferromagnetism, and a strong coupling between magnetism and structural trimerization is predicted. However, the hexagonal structure for…

We report inelastic neutron scattering measurements over 7-1251 K in CaMnO3 covering various phase transitions, and over 6-150 K in PrMnO3 covering the magnetic transition. The excitations around 20 meV in CaMnO3 and at 17 meV in PrMnO3 are…

Materials Science · Physics 2016-06-29 S. K. Mishra , M. K. Gupta , R. Mittal , A. I. Kolesnikov , S. L. Chaplot

We study the interplay of structural and polar distortions in hexagonal YMnO3 and short-period PbTiO3/SrTiO3 superlattices by means of first-principles calculations at constrained electric displacement field D. We find that in YMnO3 the…

Materials Science · Physics 2015-06-05 Massimiliano Stengel , Craig J. Fennie , Philippe Ghosez

Experimental and theoretical studies of unusual polar, dielectric and magnetic properties of room temperature multiferroics, such as perovskites Pb(Fe$_{1/2}$Nb$_{1/2}$)O$_3$ (PFN) and Pb(Fe$_{1/2}$Ta$_{1/2}$)O$_3$ (PFT), are very…

We report on the lattice evolution of BiFeO3 as function of temperature using far infrared emissivity, reflectivity, and X-ray absorption local structure. A power law fit to the lowest frequency soft phonon in the magnetic ordered phase…