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The fluorescent nitrogen-vacancy (NV) defect in diamond has remarkable photophysical properties, including high photostability, which allows stable fluorescence emission for hours; as a result, there has been much interest in using…

In this paper, we study the photoinduced switching of the nitrogen-vacancy (NV) center between two different charge states - negative (NV-) and neutral (NV0) at liquid helium temperature. The conversion of NV- to NV0 on a single defect is…

Quantum Physics · Physics 2013-04-17 P. Siyushev , H. Pinto , A. Gali , F. Jelezko , J. Wrachtrup

We investigate the effect of surface termination on the charge state of nitrogen vacancy centers, which have been ion-implanted few nanometers below the surface of diamond. We find that, when changing the surface termination from oxygen to…

Fluorescent nanodiamonds containing negatively-charged nitrogen-vacancy (NV$^-$) centers are promising for a wide range of applications, such as for sensing, as fluorescence biomarkers, or to hyperpolarize nuclear spins. NV$^-$ centers are…

The negatively charged nitrogen-vacancy (NV) center in diamond is a leading solid-state quantum emitter, offering spin-photon interfaces over a wide temperature range with applications from electromagnetic sensing to bioimaging. While NV…

Although the spin properties of superficial shallow nitrogen-vacancy (NV) centers have been the subject of extensive scrutiny, considerably less attention has been devoted to studying the dynamics of NV charge conversion near the diamond…

Mesoscale and Nanoscale Physics · Physics 2018-07-03 Siddharth Dhomkar , Harishankar Jayakumar , Pablo R. Zangara , Carlos A. Meriles

The negatively charged nitrogen-vacancy defect (NV)$^-$ in diamond has attracted much attention in recent years in qubit and biological applications. The negative charge is donated from nearby nitrogen donors that could limit or stem the…

Materials Science · Physics 2009-02-16 Adam Gali

Formation and excitation energies as well charge transition levels, are determined forthe substitutional nitrogen (Ns),the vacancy (V) and related point defects (NV, NVH, N2, N2V and V2) by screened non-local hybrid density functional…

Materials Science · Physics 2013-11-27 Peter Deák , Bálint Aradi , Moloud Kaviani , Thomas Frauenheim , Adam Gali

The conversion of neutral nitrogen-vacancy centers to negatively charged nitrogen-vacancy centers is demonstrated for centers created by ion implantation and annealing in high-purity diamond. Conversion occurs with surface exposure to an…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 K. -M. C. Fu , C. Santori , P. E. Barclay , R. G. Beausoleil

Shallow nitrogen-vacancy (NV-) centers in diamond are among the most promising quantum sensors, offering high sensitivity and nanoscale spatial resolution. These systems are, however, prone to decoherence due to coupling with surface…

Materials Science · Physics 2025-05-19 Arsineh Apelian , Mariya Romanova , Vojtech Vlcek

Although chemical vapor deposition (CVD) is one of the preferred routes to synthetic diamond crystals, a full knowledge of the point defects produced during growth is still incomplete. Here we exploit the charge and spin properties of…

Materials Science · Physics 2020-05-20 A. Lozovoi , D. Daw , H. Jayakumar , C. A. Meriles

We present the first evidence of nitrogen vacancy (NV) photoluminescence from a nanodiamond suspended in a free-space optical dipole trap at atmospheric pressure. The photoluminescence rates are shown to decrease with increasing trap laser…

Characterizing the local internal environment surrounding solid-state spin defects is crucial to harnessing them as nanoscale sensors of external fields. This is especially germane to the case of defect ensembles which can exhibit a complex…

The nitrogen-vacancy (NV) center in diamond is the prototype quantum defect that enables a variety of diamond-based quantum technologies. However, charge-state instability and spectral diffusion, often induced by substitutional nitrogen…

Materials Science · Physics 2026-05-26 Chandan Kumar Vishwakarma , J. K. Nangoi , Mark E. Turiansky , Chris G. Van de Walle

The photophysics and charge state dynamics of the nitrogen vacancy (NV) center in diamond has been extensively investigated but is still not fully understood. In contrast to previous work, we find that NV$^{0}$ converts to NV$^{-}$ under…

Materials Science · Physics 2016-07-13 Peng Ji , M. V. Gurudev Dutt

The nitrogen-vacancy (NV) centre in diamond is emerging as a promising platform for solid-state quantum information processing and nanoscale metrology. Of interest in these applications is the manipulation of the NV charge, which can be…

The nitrogen-vacancy centre (NV) has drawn much attention for over a decade, yet detailed knowledge of the photophysics needs to be established. Under typical conditions, the NV can have two stable charge states, negative (NV-) or neutral…

Quantum Physics · Physics 2017-10-20 N. Aslam , G. Waldherr , P. Neumann , F. Jelezko , J. Wrachtrup

As a potential candidate for quantum computation and metrology, the nitrogen vacancy (NV)center in diamond presented both challenges and opportunities resulted from charge state conversion. By utilizing different lasers for the…

Quantum Physics · Physics 2014-10-20 Xiangdong Chen , Changling Zou , Zhaojun Gong , Chunhua Dong , Guangcan Guo , Fangwen Sun

The performance of nitrogen vacancy (NV$^{-}$) based magnetic sensors strongly depends on the stability of nitrogen vacancy centers near the diamond surface. The sensitivity of magnetic field detection is diminished as the NV$^{-}$ turns…

Mesoscale and Nanoscale Physics · Physics 2016-11-18 Arthur N. Newell , Dontray A. Dowdell , D. H. Santamore

Single charge detection with nanoscale spatial resolution in ambient conditions is a current frontier in metrology that has diverse interdisciplinary applications. Here, such single charge detection is demonstrated using two…

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