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A convenient model for estimating the total entropy ({\Sigma}Si) of atmospheric gases based on physical action is proposed. This realistic approach is fully consistent with statistical mechanics, but uses the properties of translational,…

Chemical Physics · Physics 2021-10-26 Ivan R. Kennedy , Harold Geering , Michael T. Rose , Angus N. Crossan

It is a great challenge of nonequilibrium statistical mechanics to calculate entropy production within a microscopic theory. In the framework of linear irreversible thermodynamics, we combine the Mori-Zwanzig-Forster projection operator…

Statistical Mechanics · Physics 2014-01-28 Raphael Wittkowski , Hartmut Löwen , Helmut R. Brand

This work is concerned with our recently developed formalism of non-equilibrium thermodynamics. This formalism extends the classical irreversible thermodynamics which leads to classical thermodynamics and can not describe physical phenomena…

Analysis of PDEs · Mathematics 2018-09-06 Zaibao Yang , Wen-An Yong , Yi Zhu

It has been suggested recently that `$q$-exponential' distributions which form the basis of Tsallis' non-extensive thermostatistical formalism may be viewed as mixtures of exponential (Gibbs) distributions characterized by a fluctuating…

Statistical Mechanics · Physics 2007-05-23 Hugo Touchette

We consider the problem of defining free energy and other thermodynamic functions when the entropy is given as a general function of the probablity distribution, including that for non extensive forms. We find that the free energy, which is…

Statistical Mechanics · Physics 2007-11-07 Fariel Shafee

The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…

Chemical Physics · Physics 2009-12-03 Chi-Ho Cheng

The emerging field of stochastic thermodynamics extends classical ideas of entropy, heat and work to non-equilibrium systems. One notable finding is that the second law of thermodynamics typically only holds after taking appropriate…

Statistical Mechanics · Physics 2024-02-27 Paul C Bressloff

We derive Tsallis entropy, Sq, from universal thermostat independence and obtain the functional form of the corresponding generalized entropy-probability relation. Our result for finite thermostats interprets thermodynamically the subsystem…

High Energy Physics - Phenomenology · Physics 2014-05-19 T. S. Biró , G. G. Barnaföldi , P. Ván

What is the best description that we can construct of a thermodynamic system that is not in equilibrium, given only one, or a few, extra parameters over and above those needed for a description of the same system at equilibrium? Here, we…

Statistical Mechanics · Physics 2007-07-05 Gavin E. Crooks

A generalization of the thermodynamic uncertainty relations is proposed. It is done by introducing of an additional term proportional to the interior energy into the standard thermodynamic uncertainty relation that leads to existence of the…

General Relativity and Quantum Cosmology · Physics 2007-05-23 A. E. Shalyt-Margolin , A. Ya. Tregubovich

Relativistic irreversible thermodynamics is reformulated following the conventional approach proposed by Meixner in the non-relativistic case. Clear separation between mechanical and non-mechanical energy fluxes is made. The resulting…

General Relativity and Quantum Cosmology · Physics 2015-06-25 L. S. Garcia-Colin , A. Sandoval-Villalbazo

We derive the entropy production for transport of multi-phase fluids in a non-deformable, porous medium exposed to differences in pressure, temperature, and chemical potentials. Thermodynamic extensive variables on the macro-scale are…

Fluid Dynamics · Physics 2020-12-03 Signe Kjelstrup , Dick Bedeaux , Alex Hansen , Bjørn Hafskjold , Olav Galteland

The nonequilibrium thermodynamics feature of a Brownian motor operating between two different heat baths is explored as a function of time $t$. Using the Gibbs entropy and Schnakenberg microscopic stochastic approach, we find exact closed…

Statistical Mechanics · Physics 2015-07-08 Mesfin Asfaw Taye

The generalized Gibbs ensemble introduced for describing few body correlations in exactly solvable systems following a quantum quench is related to the nonergodic way in which operators sample, in the limit of infinite time after the…

Statistical Mechanics · Physics 2012-02-13 Miguel A. Cazalilla , A. Iucci , Ming-Chiang Chung

It is known that the equilibrium properties of open classical systems that are strongly coupled to a heat bath are described by a set of thermodynamic potentials related to the system's Hamiltonian of mean force. By adapting this framework…

Statistical Mechanics · Physics 2017-06-28 Harry J. D. Miller , Janet Anders

The use of statistical methods to model gravitational systems is crucial to physics practice, but the extent to which thermodynamics and statistical mechanics genuinely apply to these systems is a contentious issue. This paper provides new…

History and Philosophy of Physics · Physics 2025-02-04 Lorenzo Lorenzetti

A variant of continuous nonequilibrium thermodynamic theory based on the postulate of the scale invariance of the local relation between generalized fluxes and forces has been proposed. This single postulate replaces the assumptions on…

Statistical Mechanics · Physics 2015-06-05 Leonid M. Martyushev , V. D. Seleznev

In this chapter we address the topic of quantum thermodynamics in the presence of additional observables beyond the energy of the system. In particular we discuss the special role that the generalized Gibbs ensemble plays in this theory,…

Quantum Physics · Physics 2019-05-01 Erick Hinds Mingo , Yelena Guryanova , Philippe Faist , David Jennings

The dissipation generated during a quasistatic thermodynamic process can be characterised by introducing a metric on the space of Gibbs states, in such a way that minimally-dissipating protocols correspond to geodesic trajectories. Here, we…

Quantum Physics · Physics 2019-10-25 Matteo Scandi , Martí Perarnau-Llobet

Recently, some of us developed a novel model glass-forming liquid with k extra interactions with pseudo neighbours to each liquid particle over and above the regular interactions with its neighbours. Analysis of the structure and dynamics…