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Thermo-Kinetic relations bound thermodynamic quantities such as entropy production with statistics of dynamical observables. We introduce a Thermo-Kinetic Relation to bound the entropy production or the non-adiabatic (Hatano-Sasa, excess)…

Statistical Mechanics · Physics 2022-06-06 Jean-Charles Delvenne , Gianmaria Falasco

Given the evolution of an arbitrary open quantum system, we formulate a general and unambiguous method to separate the internal energy change of the system into an entropy-related contribution and a part causing no entropy change,…

Quantum Physics · Physics 2022-10-26 S. Alipour , A. T. Rezakhani , A. Chenu , A. del Campo , T. Ala-Nissila

The thermodynamic uncertainty relation expresses a universal trade-off between precision and entropy production, which applies in its original formulation to current observables in steady-state systems. We generalize this relation to…

Statistical Mechanics · Physics 2018-12-06 Timur Koyuk , Udo Seifert , Patrick Pietzonka

The existence and exact form of the continuum expression of the discrete nonlogarithmic $q$-entropy is an important open problem in generalized thermostatistics, since its possible lack implies that nonlogarithmic $q$-entropy is irrelevant…

Statistical Mechanics · Physics 2018-01-10 Thomas Oikonomou , G. Baris Bagci

Drawing inspiration from transportation theory, in this work we introduce the notions of "well-structured" and "stable" Gibbs states and we investigate their implications for quantum thermodynamics and its resource theory approach via…

Quantum Physics · Physics 2024-12-10 Frederik vom Ende , Emanuel Malvetti

We generalize the thermodynamic uncertainty relation, providing an entropic upper bound for average fluxes in time-continuous steady-state systems (Gingrich et al., Phys. Rev. Lett. 116, 120601 (2016)), to time-discrete Markov chains and to…

Statistical Mechanics · Physics 2017-10-11 Karel Proesmans , Christian Van den Broeck

A theory for non-equilibrium systems is derived from a maximum entropy approach similar in spirit to the equilibrium theory given by Gibbs. Requiring Hamilton's principle of stationary action to be satisfied on average during a trajectory,…

Statistical Mechanics · Physics 2019-02-04 David M. Rogers , Susan B. Rempe

We investigate fundamental connections between thermodynamics and quantum information theory. First, we show that the operational framework of thermal operations is nonequivalent to the framework of Gibbs-preserving maps, and we comment on…

Quantum Physics · Physics 2016-07-13 Philippe Faist

Entropy generation in a chemical reaction is analyzed without using the general formalism of non-equilibrium thermodynamics at a level adequate for advanced undergraduates. In a first approach to the problem, the phenomenological kinetic…

General Physics · Physics 2015-06-11 E. N. Miranda

We give meaning to the first and second laws of thermodynamics in case of mesoscopic out-of-equilibrium systems which are driven by diffusion processes. The notion of the entropy production is analyzed. The role of the Helmholtz extremum…

Statistical Mechanics · Physics 2008-11-26 Piotr Garbaczewski

We show that Abe's general pseudoadditivity for entropy prescribed by thermal equilibrium in nonextensive systems holds not only for entropy, but also for energy. The application of this general pseudoadditivity to Tsallis entropy tells us…

Statistical Mechanics · Physics 2009-11-07 Qiuping A. Wang , Laurent Nivanen , Alain Le Mehaute , Michel Pezeril

We analyze a gas of noninteracting fermions confined to a one-dimensional harmonic oscillator potential, with the aim of distinguishing between two proposed definitions of the thermodynamic entropy in the microcanonical ensemble, namely the…

Statistical Mechanics · Physics 2017-03-13 Kenneth J. Higginbotham , Daniel E. Sheehy

The extension of equilibrium thermodynamics to non-equilibrium systems is based on the assumption of "local equilibrium," followed by the assumption that an entropy-density function may be defined, and that this entropy-density would have…

Chemical Physics · Physics 2018-03-12 Arieh Ben-Naim

Firstly, we calculate quantitatively decrease of entropy by the known formulas in the ordering phenomena and nucleation of thermodynamics of microstructure. They show again that a necessary condition of decrease of entropy in isolated…

General Physics · Physics 2009-05-04 Yi-Fang Chang

Entropy production and dynamical activity are two complementary aspects in nonequilibrium physics. The asymmetry of cross-correlation, serving as a distinctive feature of nonequilibrium, also finds widespread utility. In this Letter, we…

Statistical Mechanics · Physics 2024-04-09 Jie Gu

From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…

Mathematical Physics · Physics 2014-11-21 Gian Paolo Beretta , Enzo Zanchini

In this paper we develop a generalized formalism for equilibrium thermodynamic systems when an information is shared between the system and the reservoir. The information results in a correction to the entropy of the system. This extension…

Statistical Mechanics · Physics 2013-05-10 Alessio Gagliardi , Aldo Di Carlo

We develop the framework of classical Observational entropy, which is a mathematically rigorous and precise framework for non-equilibrium thermodynamics, explicitly defined in terms of a set of observables. Observational entropy can be seen…

Statistical Mechanics · Physics 2020-09-09 Dominik Šafránek , Anthony Aguirre , J. M. Deutsch

This paper presents a thermodynamically consistent model for multicomponent electrolyte solutions. The first part of this paper derives the general governing equations for nonequilibrium systems within the theory of nonequilibrium…

Analysis of PDEs · Mathematics 2016-05-25 Matthias Herz , Peter Knabner

We define and analyse the concept of entanglement production during the evolution of a general quantum mechanical dissipative system. While it is important to minimise entropy production in order to achieve thermodynamical efficiency,…

Quantum Physics · Physics 2007-06-22 V. Vedral