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Related papers: Vibrational stabilization of ultracold KRb molecul…

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Determining the vibrational structure of a molecule is central to fundamental applications in several areas, from atmospheric science to catalysis, fuel combustion modeling, biochemical imaging, and astrochemistry. However, when significant…

Quantum Physics · Physics 2021-12-22 Nicolas P. D. Sawaya , Francesco Paesani , Daniel P. Tabor

This paper deals with the electronic structure of RbSr, a molecule possessing both a permanent magnetic and electric dipole moment in its own frame allowing its manipulation with external fields. Two complementary ab-initio approaches are…

Chemical Physics · Physics 2014-07-16 Piotr S. Żuchowski , Romain Guerout , Olivier Dulieu

We show that quantum rotational wavepacket dynamics in molecules can be described by a new system-environment model, which consists of a rotational subsystem coupled to a magnetically tunable spin bath formed by the nuclear spins within the…

Quantum Physics · Physics 2025-02-25 Timur V. Tscherbul , Lincoln D. Carr

We investigate the possibility of forming deeply bound ultracold RbCs molecules by a two-color photoassociation experiment. We compare the results with those for Rb_2 in order to understand the characteristic differences between…

Atomic Physics · Physics 2010-06-16 Subhas Ghosal , Richard J. Doyle , Christiane P. Koch , Jeremy M. Hutson

We report continuous direct photoassociative formation of ultracold KRb molecules in the lowest vibrational levels $(v"=0 -10)$ of the electronic ground state $(X ^1\Sigma^+)$, starting from $^{39}$K and $^{85}$Rb atoms in a magneto-optical…

Quantum sensitivity is an important issue in the field of quantum metrology where sub-Planck scale structures play crucial role in the Heisenberg limited measurement. We investigate the mesoscopic superposition structures, particularly for…

Quantum Physics · Physics 2015-06-24 Suranjana Ghosh , Utpal Roy

Ultracold LiCs molecules in the absolute ground state X$^1\Sigma^+$, v"=0, J"=0 are formed via a single photo-association step starting from laser-cooled atoms. The selective production of v"=0, J"=2 molecules with a 50-fold higher rate is…

Quantum Physics · Physics 2010-08-09 J. Deiglmayr , A. Grochola , M. Repp , K. Mörtlbauer , C. Glück , J. Lange , O. Dulieu , R. Wester , M. Weidemüller

We have produced ultracold heteronuclear YbRb$^*$ molecules in a combined magneto-optical trap by photoassociation. The formation of electronically excited molecules close to the dissociation limit was observed by trap loss spectroscopy in…

Quantum Physics · Physics 2016-01-20 N. Nemitz , F. Baumer , F. Münchow , S. Tassy , A. Görlitz

The vibrational branching ratios from the lowest excited electronic state for $\textrm{SrOCH}_3$, $\textrm{SrNH}_2$, and $\textrm{SrSH}$ are measured at the $< 0.1\%$ level. Spectra are obtained by driving the $\tilde{X} - \tilde{A}$…

Atomic Physics · Physics 2025-10-07 Alexander Frenett , Zack Lasner , Lan Cheng , John M. Doyle

We present spectra of ultracold $^7$Li$^{85}$Rb molecules in their electronic ground state formed by spontaneous decay of weakly bound photoassociated molecules. Beginning with atoms in a dual species magneto-optical trap (MOT), weakly…

Atomic Physics · Physics 2014-12-24 John Lorenz , Adeel Altaf , Sourav Dutta , Yong P. Chen , D. S. Elliott

We suggest and analyze a novel technique for efficient and robust creation of dense ultracold molecular ensembles in their ground rovibrational state. In our approach a molecule is brought to the ground state through a series of…

Quantum Physics · Physics 2009-11-13 Elena Kuznetsova , Philippe Pellegrini , Robin Côté , M. D. Lukin , S. F. Yelin

A theoretical framework is presented for the computation of rovibrational polaritonic states of a molecule in a lossless infrared (IR) microcavity. In the proposed approach the quantum treatment of the rotational and vibrational motion of…

Chemical Physics · Physics 2023-10-30 Tamás Szidarovszky

We study, both theoretically and experimentally, the dynamical polarizability $\alpha(\omega)$ of $\textrm{Rb}_2$ molecules in the rovibrational ground state of $\mathrm{a}^3\Sigma_u^+$. Taking all relevant excited molecular bound states…

We investigate a resonantly modulated harmonic mode, dispersively coupled to a nonequilibrium few-level quantum system. We focus on the regime where the relaxation rate of the system greatly exceeds that of the mode, and develop a quantum…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Z. Maizelis , M. Rudner , M. I. Dykman

Ultra-cold RbCs molecules in high-lying vibrational levels of the a$^3\Sigma^+$ ground electronic state are confined in an optical trap. Inelastic collision rates of these molecules with both Rb and Cs atoms are determined for individual…

With a specific choice of laser parameters resulting into a so-called exceptional point in the wavelength-intensity plane, it is possible to produce the coalescence of two Floquet resonances describing the photodissociation of the molecule…

Quantum Physics · Physics 2010-11-12 Osman Atabek , Roland Lefebvre , M. Lepers , Amine Jaouadi , Olivier Dulieu , V. Kokoouline

We present a novel method for probing the alignment of the molecular axis of an ultracold, nonpolar dimer. These results are obtained using diatomic $^{87}\textrm{Rb}_2$ molecules in the vibrational ground state of the lowest triplet…

Atomic Physics · Physics 2015-01-15 Markus Deiß , Björn Drews , Benjamin Deissler , Johannes Hecker Denschlag

We investigate the ultracold collisions of rotationally excited dipolar molecules in free-space, taking the hetero-nuclear bi-alkali molecule of KRb as an example. We show that we can sharply tune the elastic, inelastic and reactive rate…

Atomic Physics · Physics 2015-03-31 Gaoren Wang , Goulven Quéméner

The propagation of the arbitrarily polarized pulse of the weak probe field through the resonant medium of Lambda-type three-level atoms with degenerate levels adiabatically driven by the coherent coupling field is considered. It is shown…

Optics · Physics 2014-10-17 V. A. Reshetov , I. V. Meleshko

State-of-the-art {\em ab initio} techniques have been applied to compute the potential energy curves for the SrYb molecule in the Born-Oppenheimer approximation for the ground state and first fifteen excited singlet and triplet states…