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We describe a novel method to obtain thermodynamic properties of quantum systems using Baysian Inference -- Maximum Entropy techniques. The method is applicable to energy values sampled at a discrete set of temperatures from Quantum Monte…

Condensed Matter · Physics 2009-10-31 Carey Huscroft , Richard Gass , Mark Jarrell

The superstatistics approach recently introduced by Beck [C. Beck and E.G.D. Cohen, Physica A 322, 267 (2003)] is a formalism that aims to deal in a unifying way with a large variety of complex nonequilibrium systems, for which…

Statistical Mechanics · Physics 2007-05-23 Fabio Sattin

The Carnot theory is unique among the theories of heat developed before the emergence of thermodynamics because it considers the relationship between heat and work. The theory is contained in Carnot's book published in 1824, which includes…

History and Philosophy of Physics · Physics 2025-08-26 Mário José de Oliveira

Thermodynamic fluctuation theory originated with Einstein who inverted the relation $S=k_B\ln\Omega$ to express the number of states in terms of entropy: $\Omega= \exp(S/k_B)$. The theory's Gaussian approximation is discussed in most…

Statistical Mechanics · Physics 2015-05-19 George Ruppeiner

The concepts of quantity of heat and work are deduced in the non-extensive statistical mechanics context, following steps in parallel to those employed in the extensive statistical mechanics.

Statistical Mechanics · Physics 2009-11-10 A. K. Rajagopal

We have developed a theoretical formalism to introduce temperature as a parameter into the framework of non-relativistic quantum mechanics using the laws of classical thermodynamics and the canonical ensemble scheme of statistical…

Quantum Physics · Physics 2021-03-08 Ashkan Shekaari , Mahmoud Jafari

We present some basic inequalities between the classical and quantum values of free energy, entropy and mean energy. We investigate the transition from the deterministic case (classical mechanics) to the probabilistic case (quantum…

Mathematical Physics · Physics 2022-07-12 Lev Sakhnovich

The three and five-dimensional convex sets of two-level complex and quaternionic quantum systems are studied in the Bayesian thermostatistical framework introduced by Lavenda. Associated with a given parameterization of each such set is a…

Quantum Physics · Physics 2007-05-23 Paul B. Slater

Dunkel and Hilbert, "Consistent thermostatistics forbids negative absolute temperatures," Nature Physics, {\bf 10}, 67 (2014), and Hilbert, H\"anggi, and Dunkel, "Thermodynamic laws in isolated systems," Phys. Rev. E {\bf 90}, 062116 (2014)…

Statistical Mechanics · Physics 2015-07-09 Jian-Sheng Wang

Counting ad infinitum is the holographic observable to a statistical dynamics with finite states under independent repeated sampling. Entropy provides the infinitesimal probability for an observed frequency $\hat{\boldsymbol{\nu}}$ w.r.t. a…

Statistical Mechanics · Physics 2025-01-14 Hong Qian

The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…

Soft Condensed Matter · Physics 2009-10-30 Elliott H. Lieb , Jakob Yngvason

A simple and effective approach to thermodynamics is suggested, which solves the major difficulties in the traditional presentation of the subject. The internal energy is introduced from the behavior of deformable bodies, whereas the…

General Physics · Physics 2012-03-13 Rodrigo de Abreu , Vasco Guerra

Thermalization of isolated many-body systems is demonstrated by generalizing an approach originally due to von Neumann: For arbitrary initial states with a macroscopically well-defined energy, quantum mechanical expectation values become…

Statistical Mechanics · Physics 2015-07-02 Peter Reimann

Entropy is the distinguishing and most important concept of our efforts to understand and regularize our observations of a very large class of natural phenomena, and yet, it is one of the most contentious concepts of physics. In this…

Quantum Physics · Physics 2007-05-23 Elias P. Gyftopoulos

We consider the problem of defining free energy and other thermodynamic functions when the entropy is given as a general function of the probablity distribution, including that for non extensive forms. We find that the free energy, which is…

Statistical Mechanics · Physics 2007-11-07 Fariel Shafee

These lectures concern two topics that are becoming increasingly important in the analysis of High Energy Physics (HEP) data: Bayesian statistics and multivariate methods. In the Bayesian approach we extend the interpretation of probability…

Data Analysis, Statistics and Probability · Physics 2010-12-17 G. Cowan

In this study, the internal energy and the specific heat of the one- dimensional Ising model obtained in the frame of the generalized statistical thermodynamics by Andrade [Physica A175 (1991) 285], have been extended somewhat and compared…

Statistical Mechanics · Physics 2008-02-03 Ugur Tirnakli , Dogan Demirhan , Fevzi Buyukkilic

We investigate properties of the entropy density related to a generalized extensive statistics and derive the thermodynamic Bethe ansatz equation for a system of relativistic particles obeying such a statistics. We investigate the conformal…

High Energy Physics - Theory · Physics 2011-08-17 Andrei G. Bytsko

Ensuring a satisfactory statistical convergence of anharmonic thermodynamic properties requires sampling of many atomic configurations, however the methods to obtain those necessarily produce correlated samples, thereby reducing the…

Statistical Mechanics · Physics 2022-06-07 Erki Metsanurk

The key problem of statistical physics standing over one hundred years is how to exactly calculate the partition function (or free energy) of many-body interaction systems, which severely hinders application of the theory for realistic…

Statistical Mechanics · Physics 2019-04-26 Bo-Yuan Ning , Le-Cheng Gong , Tsu-Chien Weng , Xi-Jing Ning