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Related papers: Calorimetric study of the nematic to smectic-A pha…

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A high-resolution calorimetric study has been carried out on nano-colloidal dispersions of aerosils in the liquid crystal 4-\textit{n}-pentylphenylthiol-4'-\textit{n}-octyloxybenzoate ($\bar{8}$S5) as a function of aerosil concentration and…

Soft Condensed Matter · Physics 2009-11-11 A. Roshi , G. S. Iannacchione , P. S. Clegg , R. J. Birgeneau , M. E. Neubert

The effects of dispersed aerosil nanoparticles on two of the phase transitions of the thermotropic liquid crystal material 4-n-pentylphenylthiol-4'-n-octyloxybenzoate 8barS5 have been studied using high-resolution x-ray diffraction…

Soft Condensed Matter · Physics 2009-11-10 P. S. Clegg , R. J. Birgeneau , S. Park , C. W. Garland , G. S. Iannacchione , R. L. Leheny , M. E. Neubert

Nanoconfined liquid crystals (LCs) and their nanocomposites are driving the next generation of photonic applications. Consequently, deepening our understanding of mesophase stability, defect topology, and the dynamic response of LCs at the…

High-resolution ac-calorimetry has been carried out on dispersions of aerosils in the liquid crystal octyloxycyanobiphenyl (8OCB) as a function of aerosil concentration and temperature spanning the crystal to isotropic phases. The…

Soft Condensed Matter · Physics 2016-08-31 A. Roshi , G. S. Iannacchione , P. S. Clegg , R. J. Birgeneau

Comprehensive x-ray scattering studies have characterized the smectic ordering of octylcyanobiphenyl (8CB) confined in the hydrogen-bonded silica gels formed by aerosil dispersions. For all densities of aerosil and all measurement…

Soft Condensed Matter · Physics 2009-11-07 R. L. Leheny , S. Park , R. J. Birgeneau , J. -L. Gallani , C. W. Garland , G. S. Iannacchione

We have studied the effects of quenched random disorder created by dispersed aerosil nanoparticle gels on the nematic to smectic-A (N-SmA) and smectic-A to reentrant nematic (SmA- RN) phase transitions of thermotropic liquid crystal…

Soft Condensed Matter · Physics 2009-11-13 M. Ramazanoglu , S. Larochelle , C. W. Garland , R. J. Birgeneau

The effect on the nematic to smectic-A transition in octylcyanobiphenyl (8CB) due to dispersions of hydrogen-bonded silica (aerosil) particles is characterized with high-resolution x-ray scattering. The particles form weak gels in 8CB…

Soft Condensed Matter · Physics 2009-11-07 S. Park , R. L. Leheny , R. J. Birgeneau , J. -L. Gallani , C. W. Garland , G. S. Iannacchione

Recently we have observed in compounds of the 4,n-alkyloxybenzoic acid series, with the homologous index n ranging from 6 to 9, a texture transition in the nematic range which subdivides the nematic phase in two sub-phases displaying…

Soft Condensed Matter · Physics 2007-06-25 A. Sparavigna , A. Mello , B. Montrucchio

It has been found that in mixtures of nematic E7 and smectogenic cholesteryl oleyl carbonate (COC) the S$_A$-N* transition temperature is substantially (by ~20 K) increased, as compared with pure COC, at E7 concentrations around ~40%.…

High-resolution X-ray scattering studies of the nonpolar thermotropic liquid crystal 4-n-pentylphenylthiol-4'-n-octyloxybenzoate (\bar{8}S5) in aerosil gel nano-networks reveal that the aerosil-induced disorder significantly alters both the…

Soft Condensed Matter · Physics 2015-05-28 B. Freelon , M. Ramazanoglu , P. J. Chung , P. Valdivia , C. W. Garland , R. J. Birgeneau

We resolve the old riddle related to the critical behavior of the heat capacity near the smectic A -- hexatic second order phase transition. Experiment suggests a "large" positive specific heat critical exponent inconsistent with the…

Soft Condensed Matter · Physics 2016-03-18 E. I. Kats , V. V. Lebedev , A. R. Muratov

We report a high-resolution x-ray scattering study of the smectic liquid crystal octylcyanobiphenyl (8CB) confined to aligned colloidal aerosil gels. The aligned gels introduce orientational fields that promote long-range nematic order…

Disordered Systems and Neural Networks · Physics 2015-06-25 Dennis Liang , Robert L. Leheny

Many bent-core nematic liquid crystals exhibit unusual physical properties due to the presence of smectic clusters, known as "cybotactic" clusters in the nematic phase. Effect of these clusters on complex shear modulus ($G^*(\omega)$) of…

The nebular phase of lanthanide-rich ejecta of a neutron star merger (NSM) is studied by using a one-zone model, in which the atomic properties are represented by a single species, neodymium (Nd). Under the assumption that beta-decay of…

High Energy Astrophysical Phenomena · Physics 2021-07-21 Kenta Hotokezaka , Masaomi Tanaka , Daiji Kato , Gediminas Gaigalas

Three liquid crystalline equimolar mixtures are formulated, each containing the MHPOBC compound and the homolog from the 3FmHPhF6 series with m = 4, 5, and 6. The properties of the mixtures are investigated by differential scanning…

Soft Condensed Matter · Physics 2025-06-19 Aleksandra Deptuch , Anna Paliga , Anna Drzewicz , Michał Czerwiński , Ewa Juszyńska-Gałązka

Adiabatic scanning calorimetry (ASC) is capable of providing simultaneously the specific enthalpy h(T) and the specific heat capacity cp(T), and is an important tool to determine the order of transitions and to render high-resolution…

Soft Condensed Matter · Physics 2023-01-25 Jan Thoen , George Cordoyiannis , Wanhe Jiang , Georg H. Mehl , Christ Glorieux

In equilibrium hard-rod fluids, and in effective hard-rod descriptions of anisotropic soft-particle systems, the transition from the isotropic (I) phase to the nematic phase (N) is observed above the rod aspect ratio L/D = 3.70 as predicted…

Soft Condensed Matter · Physics 2023-02-22 Jayeeta Chattopadhyay , Sriram Ramaswamy , Chandan Dasgupta , Prabal K. Maiti

We report on X-ray studies of freely suspended hexatic films of three different liquid crystal compounds. By applying angular X-ray cross-correlation analysis (XCCA) to the measured diffraction patterns the parameters of the…

Twist-bend (Ntb) and ferroelectric (NF) nematic liquid crystals exhibit several novel effects and new physical properties. The question of what happens in binary mixtures is interesting as a matter of curiosity and pure science. Here, we…

Soft Condensed Matter · Physics 2023-08-07 Abinash Barthakur , Jakub Karcz , Przemyslaw Kula , Surajit Dhara

Molecular dynamics (MD) simulations were conducted using the generalized replica exchange method (gREM) on the 4-cyano-4$^{\prime}$-$n$-alkylbiphenyl ($n$CB) system with $n=5$, 6, 7, and 8, which exhibits a nematic-isotropic (NI) phase…

Soft Condensed Matter · Physics 2025-02-06 Shunsuke Ogita , Yoshiki Ishii , Go Watanabe , Hitoshi Washizu , Kang Kim , Nobuyuki Matubayasi
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