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Measuring the transport of electrons through a graphene sheet necessarily involves contacting it with metal electrodes. We study the adsorption of graphene on metal substrates using first-principles calculations at the level of density…

Materials Science · Physics 2015-05-13 P. A. Khomyakov , G. Giovannetti , P. C. Rusu , G. Brocks , J. van den Brink , P. J. Kelly

We propose a mechanism by which chloromethane and dichloromethane decomposition reaction occurs on the surfaces of graphene. To this end we have performed calculations on the graphene surface with metal adsorption on the sheet on the…

Chemical Physics · Physics 2016-02-23 Y. P. Ortiz , A. F. Jalbout

We investigate the chemisorptions of oxygen molecules on bilayer graphene (BLG) and its electrically modified charge-doping effect using conductivity measurement of the field effect transistor channeled with BLG. We demonstrate that the…

Mesoscale and Nanoscale Physics · Physics 2011-08-10 Yoshiaki Sato , Kazuyuki Takai , Toshiaki Enoki

Molecular adsorption at the surface of a 2D material poses numerous questions regarding the modification to the band structure and interfacial states, which of course deserve full attention. In line with this, first-principle density…

Materials Science · Physics 2020-03-27 Tanmay Das , Sesha Vempati

Adsorption of ammonia at NH3/NH2/H covered GaN(0001) surface was analyzed using results of ab initio calculations. The whole configuration space of partially NH3/NH2/H covered GaN(0001) surface was divided into zones differently pinned…

Materials Science · Physics 2016-11-09 Pawel Kempisty , Stanislaw Krukowski

It is shown that adsorption energy at semiconductor surfaces critically depends on the charge transfer to or from the adsorbed species. For the processes without the charge transfer, such as molecular adsorption of closed shell systems, the…

Materials Science · Physics 2013-08-23 Paweł Kempisty , Paweł Strak , Konrad Sakowski , Stanisław Krukowski

The optical absorption properties of graphene wrapped dielectric particles have been investigated by using Mie scattering theory and exact multi-scattering method. It is shown that subwavelength strong absorption in infrared spectra can…

Optics · Physics 2015-02-11 Bing Yang , Tong Wu , Yue Yang , Xiangdong Zhang

Making devices with graphene necessarily involves making contacts with metals. We use density functional theory to study how graphene is doped by adsorption on metal substrates and find that weak bonding on Al, Ag, Cu, Au and Pt, while…

Materials Science · Physics 2009-11-13 G. Giovannetti , P. A. Khomyakov , G. Brocks , V. M. Karpan , J. van den Brink , P. J. Kelly

Extensive Langevin dynamics simulations are used to characterize the adsorption transition of a flexible magnetic filament grafted onto an attractive planar surface. Our results identify different structural transitions at different ratios…

Graphene adsorption on Au(111) surface was explored to identify their common surface structures by means of van der Waals corrected density functional theory calculations. The alignment of graphene in the form of certain rotational angles…

Strongly Correlated Electrons · Physics 2020-05-13 Merve Yortanlı , Ersen Mete

Motivated by the idea of smart metasurfaces, we will demonstrate a graphene-based tunable absorber in which perfect absorption can be achieved for all angles of incidence, only by tuning the Fermi level of graphene. We place an unpatterned…

Applied Physics · Physics 2018-03-23 Xu-Chen Wang , Sergei A. Tretyakov

The electronic structure of the zero-gap two-dimensional graphene has a charge neutrality point exactly at the Fermi level that limits the practical application of this material. There are several ways to modify the Fermi-level-region of…

Materials Science · Physics 2017-09-13 Elena Voloshina , Denis Usvyat , Martin Schuetz , Yuriy Dedkov , Beate Paulus

Though weak surface interactions and adsorption can play an important role in plasma processing and materials science, they are not necessarily simple to model. A boron adatom adsorbed on a graphene sheet serves as a case study for how…

Computational Physics · Physics 2024-01-08 S. Jubin , A. Rau , Y. Barsukov , S. Ethier , I. D. Kaganovich

Chemical adsorption of the species at semiconductor surfaces is analyzed showing the existence of the two contributions to adsorption energy: bond creation and charge transfer. It is shown that the energy of quantum surface states is…

Materials Science · Physics 2013-08-20 Stanislaw Krukowski , Pawel Kempisty , Pawel Strak

We highlight a new metal-molecule charge transfer process by tuning the Fermi energy of plasmonic silver nanoparticles (AgNPs) in-situ. The strong adsorption of halide ions upshifts the Fermi level of AgNPs by up to ~0.3 eV in the order:…

The spatial arrangement of adsorbates deposited onto a clean surface in vacuum typically cannot be reversibly tuned. Here we use scanning tunneling microscopy to demonstrate that molecules deposited onto graphene field-effect transistors…

We study optical absorption at graphene edges in a transversal magnetic field. The magnetic field bends the trajectories of particle- and hole excitations into antipodal direction which generates a directed current. We find a rather strong…

Mesoscale and Nanoscale Physics · Physics 2021-08-02 Friedemann Queisser , Sascha Lang , Ralf Schützhold

The inter-band optical absorption in graphene characterized by its fine-structure constant has a universal value of 2.3\% independent of the material parameters. However, for several graphene-based photonic applications, enhanced optical…

Materials Science · Physics 2016-03-23 Shaloo Rakheja , Parijat Sengupta

Experimental realization of efficient graphene-based absorbers is a challenging task due to the low carrier mobility in processed graphene. In this paper, we circumvent this problem by placing uniform graphene sheets on metallic…

Applied Physics · Physics 2020-03-24 Xuchen Wang , Sergei A. Tretyakov

We present a combined experimental and theoretical study of the self-diffusion of ammonia on exfoliated graphite. Using neutron time-of-flight spectroscopy we are able to resolve the ultrafast diffusion process of adsorbed ammonia, NH$_3$,…

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