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We present the specific heat, magnetization, optical spectroscopy measurements and the firstprinciple calculations on the Weberite structure Ca2Os2O7 single crystal/polycrystalline sample. The Ca2Os2O7 shows a Curie-Weiss nature at high…

Strongly Correlated Electrons · Physics 2015-06-11 P. Zheng , Y. G. Shi , Q. S. Wu , G. Xu , T. Dong , Z. G. Chen , R. H. Yuan , B. Cheng , K. Yamaura , J. L. Luo , N. L. Wang

A single crystal of the Co2+ based pyrochlore NaCaCo2F7 was studied by inelastic neutron scattering. This frustrated magnet with quenched exchange disorder remains in a strongly correlated paramagnetic state down to one 60th of the…

Strongly Correlated Electrons · Physics 2016-02-03 Kate A. Ross , Jason W. Krizan , Jose A. Rodriguez-Rivera , Robert J. Cava , Collin L. Broholm

The layered ATMPn$_2$ (A = alkali earth or rare earth atom, TM = transition metal, Pn = Sb, Bi) compounds are widely studied for their rich magnetism and electronic structure topology. Here, we characterize the physical properties of…

At room temperature, the normal oxide spinels NiCr_2O_4 and CuCr_2O_4 are tetragonally distorted and crystallize in the I4_1/amd space group due to cooperative Jahn-Teller ordering driven by the orbital degeneracy of tetrahedral Ni$^{2+}$…

Materials Science · Physics 2012-09-11 Matthew R. Suchomel , Daniel P. Shoemaker , Lynn Ribaud , Moureen C. Kemei , Ram Seshadri

We investigated the crystal and magnetic structures of the spin-1/2 frustrated antiferromagnet Cu3Mo2O9 in which the spin system consists of antiferromagnetic chains and dimers. The space group at room temperature has been reported to be…

The crystal structure and the magnetism of BaMn$_2$O$_3$ have been studied by thermodynamic and by diffraction techniques using large single crystals and powders. BaMn$_2$O$_3$ is a realization of a $S = 5/2$ spin ladder as the magnetic…

Strongly Correlated Electrons · Physics 2015-05-20 M. Valldor , O. Heyer , A. C. Komarek , A. Senyshyn , M. Braden , T. Lorenz

Crystal structure, electronic state of Ir$^{4+}$, and magnetic properties of the antifluorite compound K$_2$IrBr$_6$ are studied using high-resolution synchrotron x-ray diffraction, resonant inelastic x-ray scattering (RIXS), thermodynamic…

Strongly Correlated Electrons · Physics 2021-04-02 Nazir Khan , Danil Prishchenko , Mary H. Upton , Vladimir G. Mazurenko , Alexander A. Tsirlin

We have studied the phase diagram of La$_{1-x}$Ca$_{x}$MnO$_{3}$ for $0.5\leq x\leq 0.9$ using neutron powder diffraction and magnetization measurements. At 300 K all samples are paramagnetic and single phase with crystallographic symmetry…

Strongly Correlated Electrons · Physics 2009-11-07 M. Pissas , G. Kallias

Temperature and field-dependent magnetization $M(H,T)$ measurements and neutron scattering study of a single crystal CeSb$_2$ are presented. Several anomalies in the magnetization curves have been confirmed at low magnetic field, i.e., 15.6…

Materials Science · Physics 2020-08-26 B. Liu , L. Wang , I. Radelytskyi , Y. Zhang , M. Meven , H. Deng , F. Zhu , Y. Su , X. Zhu , S. Tan , A. Schneidewind

Cu(1,3-benzenedicarboxylate) [Cu(1,3-bdc)] contains structurally perfect kagom\'{e} planes formed by Cu$^{2+}$ ions without the presence of diamagnetic defects. This organometallic compound should have served as a precious platform to…

Strongly Correlated Electrons · Physics 2015-10-07 Zheng Liu , Jia-Wei Mei , Feng Liu

We have successfully synthesized single crystals, solved the crystal structure, and studied the magnetic properties of a new family of copper halides (C$_4$H$_{14}$N$_2$)Cu$_2X_6$ ($X$= Cl, Br). These compounds crystallize in an…

Materials Science · Physics 2023-06-28 P. Biswal , S. Guchhait , S. Ghosh , S. N. Sarangi , D. Samal , Diptikant Swain , Manoranjan Kumar , R. Nath

LaCoO3 (LCO) nanoparticles were synthesized and their magnetic and structural properties were examined using SQUID magnetometery and neutron diffraction. The nanoparticles exhibit ferromagnetic long-range order beginning at T_C…

Strongly Correlated Electrons · Physics 2013-11-04 A. M. Durand , D. P. Belanger , F. Ye , S. Chi , J. A. Fernandez-Baca , C. H. Booth , M. Bhat

Magnetic and crystallographic properties of the mineral langite Cu$_4$(OH)$_6$SO$_4\cdot 2$H$_2$O are reported. Its layered crystal structure features a peculiar spatial arrangement of spin-$\frac12$ Cu$^{2+}$ ions that arises from a…

Strongly Correlated Electrons · Physics 2017-02-10 Stefan Lebernegg , Alexander A. Tsirlin , Oleg Janson , Günther J. Redhammer , Helge Rosner

The magnetic and structural properties of MnAs are studied with ab initio methods, and by mapping total energies onto a Heisenberg model. The stability of the different phases is found to depend mainly on the volume and on the amount of…

Materials Science · Physics 2009-11-11 Ivan Rungger , Stefano Sanvito

The quantum kagome antiferromagnets YCu3(OH)6OxCl3-x (x=0,1/3) are produced using a unified solid state synthesis route for polycrystalline samples. From structural refinements based on neutron diffraction data, we clarify the structure of…

A structural transition at $T\approx 322$ K from the $Pmmm$ to $Pmma$ phase is found to coincide with an anomaly of resistivity. Another structural phase transition doubling the lattice parameter $c$, which has been postulated earlier to…

The magnetic behavior of the Ca3Co2O6 spin chain compound is characterized by a large Ising-like character of its ferromagnetic chains, set on triangular lattice, that are antiferromagnetically coupled. At low temperature, T < 7K, the 3D…

Strongly Correlated Electrons · Physics 2007-05-23 A. Maignan , V. Hardy , S. Hebert , M. Drillon , M. R. Lees , O. Petrenko , D. Mc K. Paul , D. Khomskii

We present the crystal structure and magnetic properties of Y$_{3}$Cu$_{9}$(OH)$_{19}$Cl$_{8}$, a stoichiometric frustrated quantum spin system with slightly distorted kagome layers. Single crystals of Y$_{3}$Cu$_{9}$(OH)$_{19}$Cl$_{8}$…

Neutron diffraction studies have been carried out on a single crystal of oxygen-deficient perovskite NdBaCo2O5 in the temperature range of 7-370 K. There have been observed, with decreasing temperature T, two magnetic transitions…

Strongly Correlated Electrons · Physics 2009-11-10 Minoru Soda , Yukio Yasui , Masafumi Ito , Satoshi Iikubo , Masatoshi Sato , Kazuhisa Kakurai

We present the results of magnetic measurements on Nd6Co(1.67)Si3, a compound recently reported to crystallize in a hexagonal structure (space group P6_3/m) and to undergo long range magnetic ordering below 84 K. The results reveal that the…

Strongly Correlated Electrons · Physics 2009-11-13 Niharika Mohapatra , S. Narayana Jammalamadaka , Sitikantha D. Das , E. V. Sampathkumaran