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Through a combination of monitoring the Raman spectral characteristics of 2D materials grown on copper catalyst layers, and wafer scale automated detection of the fraction of transferred material, we reproducibly achieve transfers with over…

We have studied, both experimentally and theoretically, the change of the so-called 2D band of the Raman scattering spectrum of graphene (the two-phonon peak near 2700 cm-1) in an external magnetic field applied perpendicular to the…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 C. Faugeras , P. Kossacki , D. M. Basko , M. Amado , M. Sprinkle , C. Berger , W. A. de Heer , M. Potemski

The folding of monolayer graphene leads to new layered systems, termed twisted bilayer graphene (TBG), generally displaying a certain interlayer rotation away from crystallographic alignment. We here present an atomic force microscopy study…

Materials Science · Physics 2016-08-30 Johannes C. Rode , Christopher Belke , Hennrik Schmidt , Rolf J. Haug

The polarization dependence of the double resonant Raman scattering (2D) band in bilayer graphene (BLG) is studied as a function of the excitation laser energy. It has been known that the complex shape of the 2D band of BLG can be…

Mesoscale and Nanoscale Physics · Physics 2014-03-17 Jae-Ung Lee , Ngor Mbaye Seck , Duhee Yoon , Seon-Myeong Choi , Young-Woo Son , Hyeonsik Cheong

The symmetry group analysis is applied to classify the phonon modes of $N$-stacked graphene layers (NSGL's) with AB- and AA-stacking, particularly their infra-red and Raman properties. The dispersions of various phonon modes are calculated…

Materials Science · Physics 2008-06-30 Jin-Wu Jiang , Hui Tang , Bing-Shen Wang , Zhao-Bin Su

A new type of two-dimensional layered semiconductor with weak electrostatic but not van der Waals interlayer interactions, Bi2O2Se, has been recently synthesized, which shown excellent air stability and ultrahigh carrier mobility. Herein,…

Mesoscale and Nanoscale Physics · Physics 2018-08-20 Ting Cheng , Congwei Tan , Shuqing Zhang , Teng Tu , Hailin Peng , Zhirong Liu

Raman scattering is a ubiquitous phenomenon in light-matter interactions which reveals a material's electronic, structural and thermal properties. Controlling this process would enable new ways of studying and manipulating fundamental…

We show that graphene deposited on a substrate has a non-negligible density of atomic scale defects. This is evidenced by a previously unnoticed D peak in the Raman spectra with intensity of about 1% with respect to the G peak. We evaluated…

Mesoscale and Nanoscale Physics · Physics 2010-10-15 Z. H. Ni , L. A. Ponomarenko , R. R. Nair , R. Yang , S. Anissimova , I. V. Grigorieva , F. Schedin , Z. X. Shen , E. H. Hill , K. S. Novoselov , A. K. Geim

We present a comparative measurement of the G-peak oscillations of phonon frequency, Raman intensity and linewidth in the Magneto-Raman scattering of optical E2g phonons in mechanically exfoliated ABA- and ABC-stacked trilayer graphene…

We have investigated the vibrational properties of van der Waals heterostructures of monolayer transition metal dichalcogenides (TMDs), specifically MoS2/WSe2 and MoSe2/MoS2 heterobilayers as well as twisted MoS2 bilayers, by means of…

The effect of grain boundaries and wrinkles on the electrical properties of polycrystalline graphene is pronounced. Here we investigate the stitching between grains of polycrystalline graphene, specifically, overlapping of layers at the…

Materials Science · Physics 2014-06-09 Rahul Rao , Neal Pierce , Avetik R. Harutyunyan

Second-order Raman scattering has been extensively studied in carbon-based nanomaterials, \emph{e.g.} nanotube and graphene, because it activates normally forbidden Raman modes that are sensitive to crystal disorder, such as defects,…

The bands of graphite are extremely sensitive to topological defects which modify the electronic structure. In this paper we found non-dispersive flat bands no farther than 10 meV of the Fermi energy in slightly twisted bilayer graphene as…

Mesoscale and Nanoscale Physics · Physics 2010-12-21 E. Suárez Morell , J. D. Correa , P. Vargas , M. Pacheco , Z. Barticevic

Raman scattering data were collected on graphite monochromator. Spectra were interpreted in terms of the space group $P6_3mc$, a subgroup of space group $P6_3/mmc$. The latter has commonly been used for the interpretation of Raman…

Materials Science · Physics 2007-05-23 Y. Fujioka , J. Frantti , E. Yasuda , Y. Tanabe , M. Kakihana

Raman spectroscopic studies of graphene have attracted much interest. The G-band Raman intensity of a single layer graphene on Si substrate with 300 nm SiO2 capping layer is surprisingly strong and is comparable to that of bulk graphite. To…

Materials Science · Physics 2009-11-13 Yingying Wang , Zhenhua Ni , Zexiang Shen , Haomin Wang , Yihong Wu

Polarized Raman scattering has been performed on CaC6 superconductor. We identify two of the three Raman active Eg phonon modes at 440 and 1508 cm-1 expected for the R-3m space group of CaC6. These first order scattering modes appear along…

Materials Science · Physics 2009-11-13 A. Mialitsin , J. S. Kim , R. K. Kremer , G. Blumberg

We report multiphonon Raman scattering in graphene samples. Higher order combination modes involving 3 phonons and 4 phonons are observed in single-layer (SLG), bi-layer (BLG), and few layer (FLG) graphene samples prepared by mechanical…

Mesoscale and Nanoscale Physics · Physics 2015-05-30 Rahul Rao , Derek Tishler , Jyoti Katoch , Masa Ishigami

Raman spectroscopy is one of the widely used methods in the analysis of various samples including carbon-based materials. This study aimed to identify the number of layers and defects in graphene using micro-Raman spectroscopy. More…

Optics · Physics 2024-03-21 Somayeh Gholipour , Maryam Bahreini , Mohamad Reza Jafarfard

The unusual transport properties of graphene are the direct consequence of a peculiar bandstructure near the Dirac point. We determine the shape of the pi bands and their characteristic splitting, and the transition from a pure 2D to…

Materials Science · Physics 2007-05-23 Taisuke Ohta , Aaron Bostwick , J. L. McChesney , Thomas Seyller , Karsten Horn , Eli Rotenberg

Hybridisation of electronic bands of two-dimensional materials, assembled into twistronic heterostructures, enables one to tune their optoelectronic properties by selecting conditions for resonant interlayer hybridisation. Resonant…