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Broadening of the Raman scattering (RS) spectra was studied in monolayer graphene samples irradiated with various dose of ions followed by annealing of radiation damage at different temperatures. It is shown that the width {\Gamma} (full…

Mesoscale and Nanoscale Physics · Physics 2019-12-13 I. Shlimak , A. Butenko , E. Kogan , M. Kaveh

The band structure of bilayer graphene is tunable by introducing a relative twist angle between the two layers, unlocking exotic phases, such as superconductor and Mott insulator, and providing a fertile ground for new physics. At…

Mesoscale and Nanoscale Physics · Physics 2021-07-28 Matthew C. DeCapua , Yueh-Chun Wu , Takashi Taniguchi , Kenji Watanabe , Jun Yan

Results of room temperature Raman scattering studies of ultrathin graphitic films supported on Si (111)/SiO2 substrates are reported. The results are significantly different from those known for graphite. Spectra were collected using 514 nm…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Awnish Gupta , Gugang Chen , P. Joshi , S. Tadigadapa , P. C. Eklund

We report generation of cascaded rotational Raman scattering up to 58th orders in coherently excited CO_2 molecules. The high-order Raman scattering, which produces a quasiperiodic frequency comb with more than 600 sidebands, is obtained…

Raman spectroscopy is the prime non-destructive characterization tool for graphene and related layered materials. The shear (C) and layer breathing modes (LBMs) are due to relative motions of the planes, either perpendicular or parallel to…

Two new Raman modes below 100 cm^-1 are observed in twisted bilayer graphene grown by chemical vapor deposition. The two modes are observed in a small range of twisting angle at which the intensity of the G Raman peak is strongly enhanced,…

Mesoscale and Nanoscale Physics · Physics 2013-08-16 Rui He , Ting-Fung Chung , Conor Delaney , Courtney Keiser , Luis A. Jauregui , Paul M. Shand , C. C. Chancey , Yanan Wang , Jiming Bao , Yong P. Chen

We investigated Raman spectra of single-layer and multi-layer graphene under ultraviolet laser excitation at the wavelength of 325 nm. It was found that while the G peak of graphene remains pronounced in UV Raman spectra, the 2D band…

Materials Science · Physics 2015-05-13 Irene Calizo , Igor Bejenari , Muhammad Rahman , Guanxiong Liu , Alexander A. Balandin

The line shape of the double-resonant $2D$ Raman mode in bilayer graphene is often considered to be characteristic for a certain laser excitation energy. Here, in a joint experimental and theoretical study, we analyze the dependence of the…

Mesoscale and Nanoscale Physics · Physics 2018-12-19 Felix Herziger , Christoph Tyborski , Oliver Ochedowski , Marika Schleberger , Janina Maultzsch

The most important bands for the evaluation of strain in graphene (the 2D and 2D prime modes) are investigated. It is shown that for Bernal-stacked bilayers, the two-phonon Raman features have three different components that can be assigned…

Materials Science · Physics 2021-07-27 Sara D Costa , Johan Ek Weis , Otakar Frank , Michaela Fridrichová , Martin Kalbac

We study theoretically the Raman spectrum of the rotated double-layer graphene, consisting of two graphene layers rotated with respect to each other by an arbitrary angle \theta. We find a relatively simple dependence of the Raman G peak…

Mesoscale and Nanoscale Physics · Physics 2013-11-05 Sinisa Coh , Liang Z. Tan , Steven G. Louie , Marvin L. Cohen

In this work we study the behavior of the optical phonon modes in bilayer graphene devices by applying top gate voltage, using Raman scattering. We observe the splitting of the Raman G band as we tune the Fermi level of the sample, which is…

Mesoscale and Nanoscale Physics · Physics 2012-06-07 D. L. Mafra , P. Gava , L. M. Malard , R. S. Borges , G. G. Silva , J. A. Leon , F. Plentz , F. Mauri , M. A. Pimenta

Layered materials such as graphite and transition metal dichalcogenides have extremely anisotropic mechanical properties owing to orders of magnitude difference between in-plane and out-of-plane interatomic interaction strengths. Although…

Materials Science · Physics 2017-11-10 Jae-Ung Lee , Sungjong Woo , Jaesung Park , Hee Chul Park , Young-Woo Son , Hyeonsik Cheong

Two-dimensional (2D) layered materials have been extensively studied owing to their fascinating and technologically relevant properties. Their functionalities can be often tailored by the interlayer stacking pattern. Low-frequency (LF)…

Mesoscale and Nanoscale Physics · Physics 2017-10-06 Liangbo Liang , Alexander A. Puretzky , Bobby G. Sumpter , Vincent Meunier

We report the growth of thickness-controlled rotationally faulted multilayer graphene (rf-MLG) on Ni foils by low-pressure chemical vapor deposition and their characterization by micro-Raman spectroscopy. The surface morphology and…

Materials Science · Physics 2018-09-25 H. Kato , N. Itagaki , H. J. Im

We uncover the interlayer shear mode of multi-layer graphene samples, ranging from bilayer-graphene (BLG) to bulk graphite, and show that the corresponding Raman peak measures the interlayer coupling. This peak scales from~43cm-1 in bulk…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 P. H. Tan , W. P. Han , W. J. Zhao , Z. H. Wu , K. Chang , H. Wang , Y. F. Wang , N. Bonini , N. Marzari , G. Savini , A. Lombardo , A. C. Ferrari

Using very uniform large scale chemical vapor deposition grown graphene transferred onto silicon, we were able to identify 15 distinct Raman lines associated with graphene monolayers. This was possible thanks to a combination of different…

Mesoscale and Nanoscale Physics · Physics 2012-11-07 Simon Bernard , Eric Whiteway , Victor Yu , D. G. Austing , Michael Hilke

In this work, we study the Raman spectra of twisted bilayer graphene samples as a function of their twist-angles ($\theta$), ranging from 0.03$^\circ$ to 3.40$^\circ$, where local $\theta$ are determined by analysis of their associated…

We investigate the ultralow-frequency Raman response of atomically thin ReS2, a special type of two-dimensional (2D) semiconductors with unique distorted 1T structure. Bilayer and few-layer ReS2 exhibit rich Raman spectra at frequencies…

Mesoscale and Nanoscale Physics · Physics 2016-02-16 Rui He , Jia-An Yan , Zongyon Yin , Zhipeng Ye , Gaihua Ye , Jason Cheng , Ju Li , C. H. Lui

Direct, tunable coupling between individually assembled graphene layers is a next step towards designer two-dimensional (2D) crystal systems, with relevance for fundamental studies and technological applications. Here we describe the…

By performing density functional theory-based ab-initio calculations, Raman active phonon modes of novel single-layer two-dimensional (2D) materials and the effect of in-plane biaxial strain on the peak frequencies and corresponding…

Mesoscale and Nanoscale Physics · Physics 2018-04-04 M. Yagmurcukardes , C. Bacaksiz , E. Unsal , B. Akbali , R. T. Senger , H. Sahin