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Three different film systems have been systematically investigated to understand the effects of strain and substrate constraint on the phase transitions of perovskite films. In SrTiO$_3$ films, the phase transition temperature T$_C$ was…

Other Condensed Matter · Physics 2007-05-23 Feizhou He , B. O. Wells , Z. -G. Ban , S. P. Alpay , S. Grenier , S. M. Shapiro , Weidong Si , A. Clark , X. X. Xi

Strain and domain engineering offer powerful routes to control phase and domain stability in ferroelectric thin films. While most studies have focused on (100)-oriented growth, the impact of lower-symmetry orientations remains…

Materials Science · Physics 2026-05-11 Lan-Tien Hsu , Takeshi Nishimatsu , Anna Grünebohm

A combined experimental and computational investigation of coupling between polarization and epitaxial strain in highly polar ferroelectric PbZr_0.2Ti_0.8O_3 (PZT) thin films is reported. A comparison of the properties of relaxed…

X-ray analysis of ferroelectric thin layers of Ba1/2Sr1/2TiO3 with different thickness reveals the presence of internal strain gradients across the film thickness and allows us to propose a functional form for the internal strain profile.…

Materials Science · Physics 2009-11-10 G. Catalan , B. Noheda , J. McAneney , L. Sinnamon , J. M. Gregg

The experimental data on the thermal properties of the nanostructured perovskite ferroelectrics are presented and analysed. The ability of the modified 3w method for specific heat measurements is discussed and illustrated by the thermal…

Materials Science · Physics 2007-05-23 B. Strukov , S. Davitadze , V. Lemanov , S. Shulman , Y. Uesu , S. Asanuma

Epitaxial strain can be used to modify the properties of ferroelectric thin films. From the experimental viewpoint, the challenge is to fine-tune the magnitude of the strain. We illustrate how, by using a suitable combination of composition…

Materials Science · Physics 2015-05-20 Gijsbert Rispens , Jeroen A. Heuver , Beatriz Noheda

Experimental results on Bi2FeCrO6 (BFCO) epitaxial films deposited by laser ablation on SrTiO3 substrates are presented. It has been theoretically predicted using first-principles density functional theory that BFCO is ferrimagnetic (with a…

Materials Science · Physics 2009-03-12 R. Nechache , C. Harnagea , L. -P. Carignan , D. Menard , A. Pignolet

We demonstrate that SrRuO3 and CaRuO3 thin films undergo a room temperature structural phase transition driven by the substrate imposed epitaxial biaxial strain. As tensile strain increases, ARuO3 (A=Ca, Sr) films transform from the…

Materials Science · Physics 2009-11-13 Arturas Vailionis , Wolter Siemons , Gertjan Koster

Epitaxial strain is a proven route to enhancing the properties of complex oxides, however, the details of how the atomic structure accommodates strain are poorly understood due to the difficulty of measuring the oxygen positions in thin…

Materials Science · Physics 2015-05-18 S. J. May , J. -W. Kim , J. M. Rondinelli , E. Karapetrova , N. A. Spaldin , A. Bhattacharya , P. J. Ryan

A comparative theoretical study is presented for the rhombohedral R3 and R3m phase HfO2, of two possible forms in its heavily Zr-doped ferroelectric thin films found recently in experiments. Their structural stability and polarization under…

Materials Science · Physics 2023-07-03 Wenbin Ouyang , Fanghao Jia , Wei Ren

In spite of being highly relevant for the development of a new generation of information storage devices, not many single-phase materials displaying magnetic and ferroelectric orders above room temperature are known. Moreover, these…

A structural transition in an ABO$_{3}$ perovskite thin film involving the change of the BO$_{6}$ octahedral rotation pattern can be hidden under the global lattice symmetry imposed by the substrate and often easily overlooked. We carried…

Strongly Correlated Electrons · Physics 2019-11-04 W. T. Jin , H. Gretarsson , S. Y. Jang , Chang-Yong Kim , T. W. Noh , Young-june Kim

We have grown lead iron niobate thin films with composition Pb(Fe1/2Nb1/2)O3 (PFN) on (0 0 1) SrTiO3 substrates by pulsed laser deposition. The influence of the deposition conditions on the phase purity was studied. Due to similar…

Materials Science · Physics 2009-03-02 W. Peng , N. Lemée , J Holc , M. Kosec , R. Blinc , M. G. Karkut

In this work multiferroic thin films of Bi containing perovskite oxides are discussed, where the driving force for ferroelectricity are the Bi3+ lone-pair electrons. First, a brief introduction of Bi containing multiferroic perovskite…

Strongly Correlated Electrons · Physics 2014-02-11 Rainer Schmidt , Eric Langenberg , Jofre Ventura , Manuel Varela

We study how the ferroelastic domain structure sets in in an epitaxial film of a material with second order proper ferroelastic transition. The domain structures considered are similar to either $a_{1}/a_{2}/a_{1}/a_{2}$ or $c/a/c/a$…

Statistical Mechanics · Physics 2009-11-07 A. M. Bratkovsky , A. P. Levanyuk

Temperature dependent structural phase transitions of SrRuO3 thin films epitaxially grown on SrTiO3(001) single crystal substrates have been studied using high-resolution x-ray diffraction. In contrast to bulk SrRuO3, coherently strained…

Materials Science · Physics 2009-11-13 Arturas Vailionis , Wolter Siemons , Gertjan Koster

We have carried out extensive comparative studies of the structural and transport properties of CaRuO$_3$ thin films grown under various oxygen pressure. We find that the preferred orientation and surface roughness of the films are strongly…

Strongly Correlated Electrons · Physics 2020-09-11 Gopi Nath Daptary , Chanchal Sow , Suman Sarkar , Santosh Chiniwar , P. S. Anil Kumar , Anomitra Sil , Aveek Bid

The balance between interfacial chemistry, electrostatics, and epitaxial strain plays a crucial role in stabilizing polarization in ferroelectric thin films. Here, we bring these contributions into competition in BiFeO$_3$ (BFO) thin films…

Materials Science · Physics 2026-01-27 Elzbieta Gradauskaite , Natascha Gray , Quintin N. Meier , Marta D. Rossell , Morgan Trassin

Ferroelectric thin films under epitaxial strain exhibit a variety of vortex-like topological polarization textures. To analyze them, we build on the Ginzburg-Landau-Devonshire framework and extend the previously introduced soft-domain…

Materials Science · Physics 2025-09-09 Léo Boron , Anaïs Sené , Yuri Tikhonov , Anna Razumnaya , Igor Lukyanchuk , Svitlana Kondovych

Strain effects on epitaxial thin films of LaNiO3 grown on different single crystalline substrates are studied by Raman scattering and first-principles simulation. New Raman modes, not present in bulk or fully-relaxed films, appear under…