Related papers: Small Volume Fraction Limit of the Diblock Copolym…
We present the first of two articles on the small volume fraction limit of a nonlocal Cahn-Hilliard functional introduced to model microphase separation of diblock copolymers. Here we focus attention on the sharp-interface version of the…
This is the first in a series of two papers in which we derive a $\Gamma$-expansion for a two-dimensional non-local Ginzburg-Landau energy with Coulomb repulsion, also known as the Ohta-Kawasaki model in connection with diblock copolymer…
We study a variational model for a diblock-copolymer/homopolymer blend. The energy functional is a sharp-interface limit of a generalisation of the Ohta-Kawasaki energy. In one dimension, on the real line and on the torus, we prove…
This paper is concerned with the macroscopic behavior of global energy minimizers in the three-dimensional sharp interface unscreened Ohta-Kawasaki model of diblock copolymer melts. This model is also referred to as the nuclear liquid drop…
In this paper we study a new model for patterns in two dimensions, inspired by diblock copolymer melts with a dominant phase. The model is simple enough to be amenable not only to numerics but also to analysis, yet sophisticated enough to…
For a diblock copolymer with total chain length $\gamma>0$ and mass ratio $m\in(-1,1)$, we consider the problem of minimizing the doubly nonlocal free energy $$ \mathcal{E}_{\varepsilon}(u) =\mathcal{H}(u) +\frac{1}{\varepsilon^{2s}}…
We discuss two doubly degenerate Cahn-Hilliard (DDCH) models for isotropic surface diffusion. Degeneracy is introduced in both the mobility function and a restriction function associated to the chemical potential. Our computational results…
This is the second in a series of papers in which we derive a $\Gamma$-expansion for the two-dimensional non-local Ginzburg-Landau energy with Coulomb repulsion known as the Ohta-Kawasaki model in connection with diblock copolymer systems.…
We consider a diffuse interface model describing a ternary system constituted by a conductive diblock copolymer and a homopolymer acting as solvent. The resulting dynamics is modeled by two Cahn--Hilliard--Oono equations for the copolymer…
We study a two-dimensional ternary inhibitory system derived as a sharp-interface limit of the Nakazawa-Ohta density functional theory of triblock copolymers. This free energy functional combines an interface energy favoring micro-domain…
A diffused interface model describing the evolution of two conterminous incompressible fluids in a porous medium is discussed. The system consists of the Cahn-Hilliard equation with Flory-Huggins logarithmic potential, coupled via surface…
We identify the $\Gamma$-limit of a nanoparticle-polymer model as the number of particles goes to infinity and as the size of the particles and the phase transition thickness of the polymer phases approach zero. The limiting energy consists…
We address small volume-fraction asymptotic properties of a nonlocal isoperimetric functional with a confinement term, derived as the sharp interface limit of a variational model for self-assembly of diblock copolymers under confinement by…
We investigate the mass-preserving $L^2$-gradient flow associated with a generalized Cahn--Hilliard equation. Our focus is on the sharp interface regime, where the interface width parameter $\varepsilon > 0$ is small. For well-prepared…
The formalism developed in Refs.~\cite{Guo:2023ecc,Guo:2024zal,Guo:2024pvt} that relates the integrated correlation functions for a trapped system to the infinite volume scattering phase shifts through a weighted integral is further…
We consider a variational model for periodic partitions of the upper half-space into three regions, where two of them have prescribed volume and are subject to the geometrical constraint that their union is the subgraph of a function, whose…
We establish the behavior of the energy of minimizers of non-local Ginzburg-Landau energies with Coulomb repulsion in two space dimensions near the onset of multi-droplet patterns. Under suitable scaling of the background charge density…
We study a two-dimensional quaternary inhibitory system. This free energy functional combines an interface energy favoring micro-domain growth with a Coulomb-type long range interaction energy which prevents micro-domains from unlimited…
We study a non-local Cahn-Hilliard energy arising in the study of di-block copolymer melts, often referred to as the Ohta-Kawasaki energy in that context. In this model, two phases appear, which interact via a Coulombic energy. As in our…
We propose finite-volume schemes for the Cahn-Hilliard equation which unconditionally and discretely preserve the boundedness of the phase field and the dissipation of the free energy. Our numerical framework is applicable to a variety of…