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Enskog theory is extended for the description of the self-diffusion coefficient of patchy colloidal fluid in disordered porous media. The theory includes the contact values of fluid-fluid and fluid-matrix pair distribution functions that…

Soft Condensed Matter · Physics 2021-10-12 M. F. Holovko , M. Ya. Korvatska

The influence of confinement, due to flat parallel structureless walls, on phase separation in colloid-polymer mixtures, is investigated by means of grand-canonical Monte Carlo simulations. Ultra-thin films, with thicknesses between…

Soft Condensed Matter · Physics 2009-11-11 Richard L. C. Vink , Andres De Virgiliis , Juergen Horbach , Kurt Binder

Certain models with purely repulsive pair interactions can form cluster crystals with multiply-occupied lattice sites. Simulating these models' equilibrium properties is, however, quite challenging. Here, we develop an expanded…

Soft Condensed Matter · Physics 2015-03-20 Kai Zhang , Patrick Charbonneau

We present a quantitative comparison between extensive Monte Carlo simulations and self-consistent field calculations on the phase diagram and wetting behavior of a symmetric, binary (AB) polymer blend confined into a film. The flat walls…

Statistical Mechanics · Physics 2009-10-31 M. Mueller , K. Binder

The coverage of vicinal, stepped surfaces with molecules is simulated with the help of a two-dimensional Ising model including local distortions and an Ehrlich-Schwoebel barrier term at the steps. An effective two-spin model is capable to…

Statistical Mechanics · Physics 2015-06-25 K. Morawetz , C. Olbrich , S. Gemming , M. Schreiber

The analysis of phase transitions of gauge theories has relied heavily on simplifications that arise at the boundaries of phase diagrams, where certain excitations are forbidden. Taking 2+1 dimensional $\mathbb{Z}_2$ gauge theory as an…

Strongly Correlated Electrons · Physics 2024-08-20 Pablo Serna , Andrés M. Somoza , Adam Nahum

We report extensive numerical simulations in the {\it glass} region for a simple model of short-ranged attractive colloids, the square well model. We investigate the behavior of the density autocorrelation function and of the static…

Soft Condensed Matter · Physics 2009-11-10 Emanuela Zaccarelli , Francesco Sciortino , Piero Tartaglia

Shell effects in the coordinate space can be seen with degenerate Fermi vapors in non-uniform trapping potentials. In particular, below the Fermi temperature, the density profile of a Fermi gas in a confining harmonic potential is…

Statistical Mechanics · Physics 2016-11-23 L. Salasnich , A. Parola , L. Reatto

We consider a model of fermions interacting via point interactions, defined via a certain weighted Dirichlet form. While for two particles the interaction corresponds to infinite scattering length, the presence of further particles…

Mathematical Physics · Physics 2017-06-29 Thomas Moser , Robert Seiringer

Hard-sphere colloids are popular as models for testing fundamental theories in condensed matter and statistical physics, from crystal nucleation to the glass transition. A single parameter, the volume fraction (phi), characterizes an ideal,…

Soft Condensed Matter · Physics 2017-12-27 Wilson C. K. Poon , Eric R. Weeks , C. Patrick Royall

In experimental systems, colloidal particles are virtually always at least somewhat polydisperse, which can have profound effects on their ability to crystallize. Unfortunately, accurately predicting the effects of polydispersity on phase…

Soft Condensed Matter · Physics 2025-10-09 Antoine Castagnède , Laura Filion , Frank Smallenburg

We introduce a simple spherical model whose structural properties are similar to the ones generated by models with directional interactions, by employing a binary mixture of large and small hard spheres, with a square-well attraction acting…

Disordered Systems and Neural Networks · Physics 2009-11-13 Emanuela Zaccarelli , Francesco Sciortino , Piero Tartaglia

We present a comparative computer simulation study of the phase diagrams and anomalous behavior of two-dimensional ($2D$) and quasi-two-dimensional ($q2D$) classical particles interacting with each other through isotropic core-softened…

Soft Condensed Matter · Physics 2019-06-14 Yu. D. Fomin , E. N. Tsiok , V. N. Ryzhov

We investigate the phase behaviour of 2D mixtures of bi-functional and three-functional patchy particles and 3D mixtures of bi-functional and tetra-functional patchy particles by means of Monte Carlo simulations and Wertheim theory. We…

We study a system formed by soft colloidal spheres attracting each other via a square-well potential, using extensive Monte Carlo simulations of various nature. The softness is implemented through a reduction of the infinite part of the…

Soft Condensed Matter · Physics 2011-02-03 Riccardo Fantoni , Alexandr Malijevsky , Andres Santos , Achille Giacometti

We combine particle-based simulations, mean-field rate equations, and Wertheim's theory to study the dynamics of patchy particles in and out of equilibrium, at different temperatures and densities. We consider an initial random distribution…

Soft Condensed Matter · Physics 2017-11-01 J. M. Tavares , C. S. Dias , N. A. M. Araújo , M. M. Telo da Gama

We present a new model of patchy particles in which the interaction sites can be activated or deactivated by varying the temperature of the system. We study the thermodynamics of the system by means of Wertheim's first order perturbation…

Soft Condensed Matter · Physics 2016-05-25 Daniel de las Heras , Margarida M. Telo da Gama

The possibility to induce demixing in a colloidal mixture by adding small polymers, or other equivalent depletant agents, is theoretically investigated. By use of Mean Field Theory, suitably generalized to deal with short range effective…

Soft Condensed Matter · Physics 2015-10-28 Alberto Parola , Luciano Reatto

We propose a minimal model for spherical proteins with aeolotopic pair interactions to describe the equilibrium phase behavior of lysozyme. The repulsive screened Coulomb interactions between the particles are taken into account assuming…

Soft Condensed Matter · Physics 2012-03-27 Christoph Gogelein , Gerhard Nagele , Remco Tuinier , Thomas Gibaud , Anna Stradner , Peter Schurtenberger

In this work we extend Wertheim's thermodynamic perturbation theory (TPT) to binary mixtures (species A and species B) of patchy colloids where each species has a single patch which can bond a maximum of twice (divalent). Colloids are…

Soft Condensed Matter · Physics 2014-08-16 B. D. Marshall , W. G. Chapman