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We study the Kern-Frenkel model for patchy colloids using Barker-Henderson second-order thermodynamic perturbation theory. The model describes a fluid where hard sphere particles are decorated with one patch, so that they interact via a…

Soft Condensed Matter · Physics 2012-03-27 Christoph Gögelein , Flavio Romano , Francesco Sciortino , Achille Giacometti

We report theoretical and numerical evaluations of the phase diagram for a model of patchy particles. Specifically we study hard-spheres whose surface is decorated by a small number f of identical sites ("sticky spots'') interacting via a…

Soft Condensed Matter · Physics 2009-11-13 Emanuela Bianchi , Piero Tartaglia , Emanuela Zaccarelli , Francesco Sciortino

We report theoretical and numerical evaluations of the phase diagram for patchy colloidal particles of new generation. We show that the reduction of the number of bonded nearest neighbours offers the possibility of generating liquid states…

Soft Condensed Matter · Physics 2009-11-11 Emanuela Bianchi , Julio Largo , Piero Tartaglia , Emanuela Zaccarelli , Francesco Sciortino

Motivated by recent experimental findings in chemical synthesis of colloidal particles, we draw an analogy between self-assembly processes occurring in biological systems (e.g. protein folding) and a new exciting possibility in the field of…

Soft Condensed Matter · Physics 2018-02-14 Achille Giacometti

We present a new two dimensional model for elliptic (i.e., shape anisotropic) patchy colloids, where the impenetrable core of the particles is decorated on its co-)vertices by Kern-Frenkel type of patches. Using (i) well-documented criteria…

Soft Condensed Matter · Physics 2019-10-02 Susanne Wagner , Gerhard Kahl

We study the thermodynamic and structural properties of a simple, one-patch fluid model using the reference hypernetted-chain (RHNC) integral equation and specialized Monte Carlo simulations. In this model, the interacting particles are…

Soft Condensed Matter · Physics 2015-05-14 Achille Giacometti , Fred Lado , Julio Largo , Giorgio Pastore , Francesco Sciortino

We report event-driven molecular dynamics simulations of the irreversible gelation of hard ellipsoids of revolution containing several associating groups, characterizing how the cluster size distribution evolves as a function of the extent…

We consider a fluid of hard spheres bearing one or two uniform circular adhesive patches, distributed so as not to overlap. Two spheres interact via a ``sticky'' Baxter potential if the line joining the centers of the two spheres intersects…

Statistical Mechanics · Physics 2009-11-13 Riccardo Fantoni , Domenico Gazzillo , Achille Giacometti , Mark A. Miller , Giorgio Pastore

A simple model for functionalized disordered porous media is proposed and the effects of confinement on self-association, percolation and phase behavior of a fluid of patchy particles are studied. The media is formed by a randomly…

Soft Condensed Matter · Physics 2025-03-12 Yurij V. Kalyuzhnyi , Taras Patsahan , Myroslav Holovko , Peter T. Cummings

We perform numerical simulations of a simple model of one-patch colloidal particles to investigate: (i) the behavior of the gas-liquid phase diagram on moving from a spherical attractive potential to a Janus potential and (ii) the…

Soft Condensed Matter · Physics 2017-08-23 Francesco Sciortino , Achille Giacometti , Giorgio Pastore

Colloidal patchy particles with divalent attractive interaction can self-assemble into linear polymer chains. Their equilibrium properties in 2D and 3D are well described by Wertheim's thermodynamic perturbation theory which predicts a…

Soft Condensed Matter · Physics 2022-09-21 H. J. Jonas , P. Schall , P. G. Bolhuis

We investigate the structural and thermodynamic properties of a model of particles with $2$ patches of type $A$ and $10$ patches of type $B$. Particles are placed on the sites of a face centered cubic lattice with the patches oriented along…

Soft Condensed Matter · Physics 2015-06-18 J. M. Tavares , N. G. Almarza , M. M. Telo da Gama

Patchy colloidal model with three and four equivalent patches, confined in the attractive random porous media, undergo re-entrant gas-liquid phase separation with the possibility for the liquid phase density to approach zero. This unusual…

Soft Condensed Matter · Physics 2022-05-11 Taras Hvozd , Yurij V. Kalyuzhnyi , Vojko Vlachy , Peter T. Cummings

We discuss the reliability of integral-equation methods based on several commonly used closure relations in determining the phase diagram of coarse-grained models of soft-matter systems characterized by mutually interacting soft and…

Soft Condensed Matter · Physics 2015-10-28 Roberto Menichetti , Andrea Pelissetto , Giuseppe D'Adamo , Carlo Pierleoni

Inverse Patchy Colloids (IPCs) differ from conventional patchy particles because their patches repel (rather than attract) each other and attract (rather than repel) the part of the colloidal surface that is free of patches. These…

Soft Condensed Matter · Physics 2014-12-12 Silvano Ferrari , Emanuela Bianchi , Yura V. Kalyuzhnyi , Gerhard Kahl

Fractional Chern insulators (FCI) with crystalline symmetry possess topological invariants that fundamentally have no analog in continuum fractional quantum Hall (FQH) states. Here we demonstrate through numerical calculations on model wave…

Strongly Correlated Electrons · Physics 2025-07-23 Yuxuan Zhang , Maissam Barkeshli

We study a system of few colloids confined in a small spherical cavity by event driven molecular dynamics simulations in the canonical ensemble. The colloidal particles interact through a short range square-well potential, which takes into…

Soft Condensed Matter · Physics 2015-04-10 Iván Paganini , Claudio Pastorino , Ignacio Urrutia

We study the equilibrium thermodynamics of quantum hard spheres in the infinite-dimensional limit, determining the boundary between liquid and glass phases in the temperature-density plane by means of the Franz-Parisi potential. We find…

Statistical Mechanics · Physics 2023-11-10 Michael Winer , Christopher L. Baldwin , Richard Barney , Victor Galitski , Brian Swingle

Nano- to micro-sized particles with differently charged surface areas exhibit complex interaction patterns, characterized by both opposite-charge attraction and like-charge repulsion. While several successful models have been proposed in…

Soft Condensed Matter · Physics 2025-01-16 Daniele Notarmuzi , Silvano Ferrari , Emanuele Locatelli , Emanuela Bianchi

In this study, we have derived a thermodynamically consistent phase-field model for two-phase flows with thermocapillary effects. This model accommodates variations in physical properties such as density, viscosity, heat capacity, and…

Fluid Dynamics · Physics 2024-04-09 Yanxiao Sun , Jiang Wu , Maosheng Jiang , Steven M. Wise , Zhenlin Guo
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