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The study of molecular systems provides exceptional opportunities for the exploration of the fundamental laws of nature and for the search for physics beyond the Standard Model of particle physics. Measurements of molecules composed of…

We report the first measurement of size-resolved photoelectron angular distributions for the valence orbitals of water clusters with up to 20 molecules. A systematic decrease of the photoelectron anisotropy is found for clusters with up to…

Chemical Physics · Physics 2017-03-17 Sebastian Hartweg , Bruce L. Yoder , Gustavo A. Garcia , Laurent Nahon , Ruth Signorell

The single ionization of noble gas atoms by the combined action of XUV attopulses and an infrared laser field is theoretically investigated by means of a non-perturbative model that under certain approximations gives closed-form expressions…

Atomic Physics · Physics 2015-12-21 D. I. R. Boll , O. A. Fojón

Nondipole effects are ubiquitous and crucial in light-matter interaction. However, they are too weak to be directly observed. In strong-field physics, motion of electrons is mainly confined in transverse plane of light fields, which…

Atomic Physics · Physics 2023-03-07 Yankun Dou , Yiqi Fang , Peipei Ge , Yunquan Liu

The angular distribution of the emitted electrons, following the two-photon ionization of the hydrogen-like ions, is studied within the framework of second order perturbation theory and the Dirac equation. Using a density matrix approach,…

Atomic Physics · Physics 2007-05-23 Peter Koval , Stephan Fritzsche , Andrey Surzhykov

Photoelectron circular dichroism (PECD) is a method whereby randomly oriented chiral molecules are irradiated by circularly-polarized light, photoionizing electrons, which are measured in a momentum-resolved manner. This scheme permits…

Chemical Physics · Physics 2025-05-23 Ofer Neufeld

Tracking the coupled motion of electrons and nuclei on their intrinsic timescales is essential to understanding and controlling photochemical transformations. While attosecond techniques have provided unprecedented insight into electronic…

We present a novel approach to model ultrafast time-dependent nonlinear optical polarization sensitive signals emitted from randomly-oriented molecules. By projecting the laboratory-frame analyzer polarization axis into the molecular frame…

Chemical Physics · Physics 2025-07-17 R. L. Thurston , N. Shivaram , Th. Weber , L. Z. Tan , D. S. Slaughter

The photodissociation of the HD+ molecular ion in intense short- pulsed linearly polarized laser fields is studied using a time- dependent wave-packet approach where molecular rotation is fully included. We show that applying a coherent…

chem-ph · Physics 2019-04-04 Eric Charron , Annick Giusti-Suzor , Frederick Mies

Molecular orientation fluctuations in ferroelectric smectic liquid crystals produce space charges, due to the divergence of the spontaneous polarization. These space charges interact with mobile ions, so that one must consider the coupled…

Soft Condensed Matter · Physics 2007-08-16 Robert A. Pelcovits , J. -B. Lee , R. B. Meyer

In strong field ionization, the pump pulse not only photoionizes the molecule, but also drives efficient population exchanges between its ionic ground and excited states.In this study, we investigated the population dynamics accompanying…

Chemical Physics · Physics 2021-07-15 Xiangxu Mu , Ming Zhang , Hanwei Yang , Haitan Xu , Song Bin Zhang , Lushuai Cao , Min Li , Zijian Lü , Chengyin Wu , Zheng Li

It is demonstrated for the first time that in spite of well known big similarities between atomic ionization by photons and fast electrons, a qualitative difference exists in angular anisotropy parameters of electrons knocked out in these…

Atomic Physics · Physics 2015-05-30 M. Ya. Amusia , L. V. Chernysheva , E. Z. Liverts

Population of levels of the hyperfine and fine split ground state of an atom is affected by radiative transitions induced by anisotropic radiation flux. Such aligned atoms precess in the external magnetic field and this affects properties…

Astrophysics · Physics 2007-05-23 Huirong Yan , A. Lazarian

We show that the complete photoemission dynamics in situations of electron-ion entanglement can be retrieved from photoelectron spectral measurements without information on the ion. To this end, we develop an energy-time analysis of the…

We present a theoretical study of the impact of an electrostatic field combined with nonresonant linearly polarized laser pulses on the rotational dynamics of a thermal ensemble of linear molecules. We solve the time-dependent Schr\"odinger…

Quantum Physics · Physics 2015-06-16 Juan J. Omiste , Rosario González Férez

Radiation emitted by unpolarized high-energy electrons penetrating crystals may be linearly polarized. This occurs when the particle velocity makes an angle, with respect to some major crystal axis, being sufficiently larger than the…

High Energy Physics - Phenomenology · Physics 2008-11-26 V. M. Strakhovenko

The Fraunhofer diffraction of quantum particles from materials with sharp electron-density edges or symmetric bond structures is ubiquitous. In contrast, diffraction from atoms with characteristic asymptotically-diffused electron…

Electron energy loss spectroscopy is consolidating as a powerful tool to explore electronic (as well as vibrational) excitations of matter, including molecules. Performed in a scanning transmission electron microscope, this technique is…

Chemical Physics · Physics 2021-03-05 Ciro A. Guido , Enzo Rotunno , Matteo Zanfrognini , Stefano Corni , Vincenzo Grillo

We use three dimensional time-dependent Schr\"odinger equation (3D--TDSE) to calculate angular electron momentum distributions and photoelectron spectra of atoms driven by spatially inhomogeneous fields. An example for such inhomogeneous…

Atomic Physics · Physics 2013-06-26 M. F. Ciappina , J. A. Pérez-Hernández , T. Shaaran , L. Roso , M. Lewenstein

The photoionization of a two-shell endohedral A@CN1@CN2 is considered. Formulas are presented for cross-sections and angular anisotropy parameters, both dipole and non-dipole. The effect of the fullerenes shell upon photoelectron from atom…

Atomic and Molecular Clusters · Physics 2013-05-29 M. Ya. Amusia , L. V. Chernysheva , E. Z. Liverts