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We present a characterization of the many-body lattice wave functions obtained from the conformal blocks (CBs) of the Ising conformal field theory (CFT). The formalism is interpreted as a matrix product state using continuous ancillary…

Strongly Correlated Electrons · Physics 2017-12-06 Sebastian Montes , Javier Rodríguez-Laguna , Germán Sierra

The excess free energy functional of classical density functional theory depends upon the type of fluid model, specifically on the choice of (pair) potential, is unknown in general, and is approximated reliably only in special cases. We…

Soft Condensed Matter · Physics 2025-03-12 Stefanie M. Kampa , Florian Sammüller , Matthias Schmidt , Robert Evans

Two basic correlation functions are calculated for a model of $N$ harmonically interacting identical particles in a parabolic potential well. The density and the pair correlation function of the model are investigated for the boson case.…

Statistical Mechanics · Physics 2009-10-30 F. Brosens , J. T. Devreese , L. F. Lemmens

Based on fundamental measure theory, a Helmholtz free energy density functional for three-component mixtures of hard spheres with general, non-additive interaction distances is constructed. The functional constitutes a generalization of the…

Soft Condensed Matter · Physics 2011-09-28 Matthias Schmidt

We establish one-body reduced density-matrix functional theory for the canonical ensemble in a finite basis set at an elevated temperature. Including temperature guarantees differentiability of the universal functional by occupying all…

Mathematical Physics · Physics 2023-02-22 Sarina M. Sutter , Klaas J. H. Giesbertz

We present a novel method for calculating the fundamental gap. To this end, reduced-density-matrix-functional theory is generalized to fractional particle number. For each fixed particle number, $M$, the total energy is minimized with…

Strongly Correlated Electrons · Physics 2009-11-11 N. Helbig , N. N. Lathiotakis , M. Albrecht , E. K. U. Gross

Occupation numbers of natural orbitals capture the physics of strong electron correlations in momentum space. A Natural Orbital Density Functional Theory based on the antisymmetrized geminal product provides these occupation numbers and the…

Strongly Correlated Electrons · Physics 2014-05-06 B. Barbiellini

Density functional theory for a simple model of dendrimers is proposed. The theory is based on fundamental measure theory which accounts for the hard-sphere repulsion of the segments and on the Wertheim first-order perturbation theory for…

Soft Condensed Matter · Physics 2012-11-12 Alexandr Malijevsky

The recently developed hypercomplex Kohn-Sham (HCKS) theory shows great potential to overcome the static/strong correlation issue in density functional theory (DFT), which highlights the necessity of further exploration of the HCKS theory…

Chemical Physics · Physics 2022-03-16 Neil Qiang Su

We propose a method for simulating the behaviour of small clusters of particles that explicitly accounts for all mean-field and binary-correlation effects. Our approach leads to a set of variational equations that can be used to study both…

Other Condensed Matter · Physics 2009-11-11 J. N. Milstein , K. Burnett

We use a density-functional theoretical approach to set up a computationally simple self-consistent scheme to calculate the pair distribution functions and the effective interactions in quantum Coulomb liquids. We demonstrate the accuracy…

Strongly Correlated Electrons · Physics 2007-05-23 B. Davoudi , M. Polini , R. Asgari , M. P. Tosi

The $^3P_2$-$^3F_2$ pairing model is generally considered to provide an adequate description of the superfluid states of neutron matter at densities some 2-3 times that of saturated symmetrical nuclear matter. The problem of solving the…

Nuclear Theory · Physics 2008-11-26 M. V. Zverev , J. W. Clark , V. A. Khodel

Fractional occupation numbers can be used in density functional theory to create a symmetric Kohn-Sham potential, resulting in orbitals with degenerate eigenvalues. We develop the corresponding perturbation theory and apply it to a system…

Materials Science · Physics 2016-09-09 Mark C. Palenik , Brett I. Dunlap

Non-empirical effective contact pairing forces to be used in self-consistent mean-field calculations are presented. These pairing forces, constructed so as to reproduce exactly any given microscopic pairing gaps in infinite homogeneous…

Nuclear Theory · Physics 2010-09-21 Nicolas Chamel

Density-potential functional theory (DPFT) is an alternative formulation of orbital-free density functional theory that may be suitable for modeling the electronic structure of large systems. To date, DPFT has been applied mainly to quantum…

Materials Science · Physics 2023-04-21 Martin-Isbjörn Trappe , William C. Witt , Sergei Manzhos

We provide a rigorous derivation of a class of double-hybrid approximations, combining Hartree-Fock exchange and second-order Moller-Plesset correlation with a semilocal exchange-correlation density functional. These double-hybrid…

Chemical Physics · Physics 2011-02-21 Kamal Sharkas , Julien Toulouse , Andreas Savin

Density-functional theory for superfluid systems is developed in the framework of the functional renormalization group based on the effective action formalism. We introduce the effective action for the particle-number and nonlocal pairing…

Nuclear Theory · Physics 2021-05-11 Takeru Yokota , Haruki Kasuya , Kenichi Yoshida , Teiji Kunihiro

Density-corrected density functional theory (DC-DFT) is enjoying substantial success in improving semilocal DFT calculations in a wide variety of chemical problems. This paper provides the formal theoretical framework and assumptions for…

Chemical Physics · Physics 2019-08-19 Stefan Vuckovic , Suhwan Song , John Kozlowski , Eunji Sim , Kieron Burke

Unbiased stochastic sampling of the one- and two-body reduced density matrices is achieved in full configuration interaction quantum Monte Carlo with the introduction of a second, "replica" ensemble of walkers, whose population evolves in…

Computational Physics · Physics 2015-09-02 Robert E. Thomas , Daniel Opalka , Catherine Overy , Peter J. Knowles , Ali Alavi , George H. Booth

We analyze spectral functions of mesoscopic systems with large dimensionless conductance, which can be described by a universal Hamiltonian. We show that an important class of spectral functions are dominated by one single state only, which…

Strongly Correlated Electrons · Physics 2009-11-10 Dominique Gobert , Moshe Schechter , Ulrich Schollwock , Jan von Delft