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A generalised phase-space kinetic Boltzmann equation for highly non-equilibrium charged particle transport via localised and delocalised states is used to develop continuity, momentum and energy balance equations, accounting explicitly for…

Statistical Mechanics · Physics 2017-04-19 Peter W. Stokes , Bronson Philippa , Daniel Cocks , Ronald D. White

Generalized Einstein relation between the mobility and diffusion in conductors with a large built-in field near the thermodynamic equilibrium has been derived.

Materials Science · Physics 2010-10-06 S. A. Ktitorov

The ratio between mobility and diffusion parameters is derived for a Gaussian-like density of states. This steady-state analysis is expected to be applicable to a wide range of organic materials (polymers or small molecules) as it relies on…

Statistical Mechanics · Physics 2007-05-23 Yohai Roichman , Nir Tessler

A generalized Einstein relation is studied for Brownian motion in a tilted potential. The exact form of the diffusion constant of the Brownian motion is compared with the generalized Einstein relation. The generalized Einstein relation is a…

Statistical Mechanics · Physics 2015-06-25 Hidetsugu Sakaguchi

The Einstein relation connecting the diffusion constant and the mobility is violated beyond the linear response regime. For a colloidal particle driven along a periodic potential imposed by laser traps, we test the recent theoretical…

Statistical Mechanics · Physics 2007-06-20 V. Blickle , T. Speck , C. Lutz , U. Seifert , C. Bechinger

A generalized Green-Kubo formula is derived for a quantum dissipative system of driven Brownian particle, in which the coupling between the system and the environment is linear. The structure is essentially the same as that for the…

Statistical Mechanics · Physics 2015-05-14 Hisao Hayakawa

Fluctuation theorem is derived for a quantum current system around a nonequilibrium steady state. It is demonstrated that the fluctuation theorem can be a part of the generalized Green-Kubo formula or a nonlinear response theory of an…

Statistical Mechanics · Physics 2011-03-30 Hisao Hayakawa

A recently introduced stochastic model for fluid flow can be made Galilean invariant by introducing a random shift of the computational grid before collisions. This grid shifting procedure accelerates momentum transfer between cells and…

Soft Condensed Matter · Physics 2009-11-10 Thomas Ihle , Erkan Tuzel , Daniel M. Kroll

We address the question of whether transport coefficients obtained from a unitary closed system setting, i.e., the standard equilibrium Green-Kubo formula, are the same as the ones obtained from a weakly driven nonequilibrium steady-state…

Statistical Mechanics · Physics 2019-01-25 Marko Znidaric

We present a theoretical framework to understand a modified fluctuation-dissipation theorem valid for systems close to non-equilibrium steady-states and obeying markovian dynamics. We discuss the interpretation of this result in terms of…

Statistical Mechanics · Physics 2015-05-20 G. Verley , K. Mallick , D. Lacoste

A stochastic dynamics has a natural decomposition into a drift capturing mean rate of change and a martingale increment capturing randomness. They are two statistically uncorrelated, but not necessarily independent mechanisms contributing…

Statistical Mechanics · Physics 2021-06-28 Ying-Jen Yang , Hong Qian

In order to study the stochastic Markov processes conditioned on a specific value of a time-integrated observable, the concept of ensembles of trajectories has been recently used extensively. In this paper, we consider a generic…

Statistical Mechanics · Physics 2019-02-15 Sara Kaviani , Farhad H. Jafarpour

We consider a non-interacting one-dimensional gas accelerated by a constant and uniform external field. The energy absorbed from the field is transferred via elastic collisions to a bath of scattering obstacles. At gas-obstacle encounters…

Statistical Mechanics · Physics 2009-11-11 Jaroslaw Piasecki , Rodrigo Soto

The Green-Kubo formula relates the spatial diffusion coefficient to the stationary velocity autocorrelation function. We derive a generalization of the Green-Kubo formula valid for systems with long-range or nonstationary correlations for…

Statistical Mechanics · Physics 2014-03-05 A. Dechant , E. Lutz , D. A. Kessler , E. Barkai

We present generalized Green-Kubo expressions for thermal transport coefficients $\mu$ in non-conservative fluid-type systems, of the generic form, $\mu$ $= \mu_\infty$ $+\int^\infty_0 dt V^{-1} \av{I_\epsilon \exp(t {\cal L}) I}_0$ where…

Statistical Mechanics · Physics 2007-05-23 M. H. Ernst , R. Brito

The transport coefficients for a gas of smooth, inelastic hard spheres are obtained from the Boltzmann equation in the form of Green-Kubo relations. The associated time correlation functions are not simply those constructed from the fluxes…

Statistical Mechanics · Physics 2015-06-24 James W. Dufty , J. Javier Brey

We derive generalized charge energy rate equations for organic solids and biomolecular aggregates, even when these are dynamically disordered. These equations suggest that the transport in such cases rely on both drift and diffusion…

Mesoscale and Nanoscale Physics · Physics 2017-12-25 K. Navamani , Swapan K. Pati

Green-Kubo and Einstein expressions for the transport coefficients of a fluid in a nonequilibrium steady state can be derived using the Fluctuation Theorem and by assuming the probability distribution of the time-averaged dissipative flux…

Statistical Mechanics · Physics 2009-10-31 Debra J. Searles , Denis J. Evans

The theory of transport phenomena in multicomponent electrolyte solutions is presented here through the integration of continuum mechanics, electromagnetism, and non-equilibrium thermodynamics. The governing equations of irreversible…

Statistical Mechanics · Physics 2020-11-02 Kara D. Fong , Helen K. Bergstrom , Bryan D. McCloskey , Kranthi K. Mandadapu

The Green-Kubo relation, the Einstein relation, and the fluctuation-response relation are representative universal relations among measurable quantities that are valid in the linear response regime. We provide pedagogical proofs of these…

Statistical Mechanics · Physics 2009-11-11 Kumiko Hayashi , Shin-ichi Sasa
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