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In the last several years, there has been a wealth of studies to clarify the role of thin layers of electrocatalysts on semiconducting photoelectrodes to the efficiency of the oxygen evolution reaction (OER). It has been shown that the…

In high-performance solar cells based on polymeric semiconductors, the mechanism of photocarrier generation on $<100$-fs timescales is yet to be unravelled. In particular the dynamics of early-time electronic coupling between excitons on…

Exciton-polaritons (EPs) arising from strong light-matter coupling offer new pathways for controlling optoelectronic properties. While typically requiring closed optical cavities for strong coupling, we demonstrate that 2D metal-organic…

Optics · Physics 2025-12-11 Bongjun Choi , Adam D. Alfieri , Wangleong Chen , Deep Jariwala

Using a combination of first principles molecular dynamics simulations (FPMD) and electronic structure calculations, we characterize the atomistic structure and vibrational properties of a photocatalytic surface of In$_2$O$_3$, a promising…

Materials Science · Physics 2025-03-12 Matthew Bousquet , Jiawei Zhan , Chunxin Luo , Alex B. Martinson , Francois Gygi , Giulia Galli

Electron-electron correlation forms the basis of difficulties encountered in multi-electron systems. Accurate treatment of the correlation problem is likely to unravel some nice physical properties of matter embedded in this correlation. In…

Quantum Physics · Physics 2022-03-24 Eric Ouma Jobunga

We report measurements on the H$^{+}$ + H$^{+}$ fragmentation channel following direct single-photon double ionization of neutral NH$_{3}$ at 61.5 eV, where the two photoelectrons and two protons are measured in coincidence using 3-D…

Hard X-ray (HXR) spectroscopy is the most direct method of diagnosing energetic electrons in solar flares. Here we present a technique which allows us to use a single HXR spectrum to determine an effectively stereoscopic electron energy…

Astrophysics · Physics 2009-11-11 Eduard P. Kontar , John C. Brown

Perovskite photovoltaics has witnessed an unprecedented increase in power conversion efficiency over the last decade. The choice of transport layers, through which photo-generated electrons and holes are transported to the electrodes, is a…

Applied Physics · Physics 2020-07-10 Eline M. Hutter , Thomas Kirchartz , Bruno Ehrler , David Cahen , Elizabeth von Hauff

The $^6$He+$^{12}$C elastic scattering data at beam energies of 3, 38.3 and 41.6 MeV/nucleon are studied utilizing the microscopic optical potentials obtained by a double-folding procedure and also by using those inherent in the high-energy…

Operando synchrotron X-ray techniques have become essential tools for investigating rechargeable batteries as they provide real-time insights into electrochemical processes. However, the high brilliance of synchrotron radiation can alter…

For the description of an H2 molecule an effective one-electron model potential is proposed which is fully determined by the exact ionization potential of the H2 molecule. In order to test the model potential and examine its properties it…

Chemical Physics · Physics 2009-11-13 Armin Lühr , Yulian V. Vanne , Alejandro Saenz

We propose a computationally lean, two-stage approach that reliably predicts self-assembly behavior of complex charged molecules on a metallic surfaces under electrochemical conditions. Stage one uses ab initio simulations to provide…

Computational Physics · Physics 2020-07-15 Benedikt Hartl , Shubham Sharma , Oliver Brügner , Stijn F. L. Mertens , Michael Walter , Gerhard Kahl

Accurate tracking of the internal electrochemical states of lithium-ion battery during cycling enables advanced battery management systems to operate the battery safely and maintain high performance while minimizing battery degradation. To…

Systems and Control · Electrical Eng. & Systems 2020-10-01 Sravan Pannala , Puneet Valecha , Peyman Mohtat , Jason B. Siegel , Anna G. Stefanopoulou

Electron energy-loss spectroscopy (EELS) performed in transmission electron microscopes is shown to directly render the photonic local density of states (LDOS) with unprecedented spatial resolution, currently below the nanometer. Two…

Materials Science · Physics 2012-11-13 F. J. Garcia de Abajo , M. Kociak

Single molecules that exhibit narrow optical transitions at cryogenic temperatures can be used as local electric-field sensors. We derive the single charge sensitivity of aromatic organic dye molecules, based on first principles. Through…

Mesoscale and Nanoscale Physics · Physics 2015-06-23 Sanli Faez , Sense Jan van der Molen , Michel Orrit

Above-treshold ionization (ATI) by femtosecond laser pulses centered at 515\,nm is studied for a gas mixture containing the Van-der-Waals complex Ar-H$_2$O. By detecting photoions and -electrons in coincidence, the ATI spectra for Ar,…

Atomic Physics · Physics 2023-10-26 Adrian Platz , Sebastian Hell , Yinyu Zhang , Bo Ying , Gerhard G. Paulus , Matthias Kübel

Organic light emitting devices and solar cells are machines that create, manipulate and destroy excited states in organic semiconductors. It is crucial to characterize these excited states, or excitons, to optimize device performance in…

Materials Science · Physics 2019-06-07 Sebastian Reineke , Marc A. Baldo

Absolute photoionization cross-section measurements are reported for Se+ in the photon energy range 18.0-31.0 eV, which spans the ionization thresholds of the 4S_{3/2} ground state and the low-lying 2P_{3/2,1/2} and 2D_{5/2,3/2} metastable…

In situ scanning transmission electron microscopy (STEM) through liquids is a promising approach for exploring biological and materials processes. However, options for in situ chemical identification are limited: X-ray analysis is precluded…

Chemical Physics · Physics 2015-06-12 Megan E. Holtz , Yingchao Yu , Jie Gao , Héctor D. Abruña , David A. Muller

We propose a pseudopotential for the electron-electron Coulomb interaction to improve the efficiency of many-body electronic structure calculations. The pseudopotential accurately replicates the scattering properties of the Coulomb…

Strongly Correlated Electrons · Physics 2015-09-02 J. H. Lloyd-Williams , R. J. Needs , G. J. Conduit