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We numerically study a simple model for thermo-reversible colloidal gelation in which particles can form reversible bonds with a predefined maximum number of neighbors. We focus on three and four maximally coordinated particles, since in…

The interplay between short-range attractions and long-range repulsions (SALR) characterizes the so called liquids with competing interactions, which are known to exhibit a variety of equilibrium and non-equilibrium phases. The theoretical…

We numerically and analytically analyze transitions between different synchronous states in a network of globally coupled phase oscillators with attractive and repulsive interactions. The elements within the attractive or repulsive group…

Chaotic Dynamics · Physics 2019-10-23 Erik Teichmann , Michael Rosenblum

The dynamical arrest of attractive colloidal particles into out-of-equilibrium structures, known as gelation, is central to biophysics, materials science, nanotechnology, and food and cosmetic applications, but a complete understanding is…

Soft Condensed Matter · Physics 2020-07-22 Joep Rouwhorst , Christopher Ness , Simeon Stoyanov , Alessio Zaccone , Peter Schall

A colloidal system of spheres interacting with both a deep and narrow attractive potential and a shallow long-ranged barrier exhibits a prepeak in the static structure factor. This peak can be related to an additional mesoscopic length…

Soft Condensed Matter · Physics 2009-11-13 O. Henrich , A. M. Puertas , M. Sperl , J. Baschnagel , M. Fuchs

The binary hard-sphere mixture is one of the simplest representations of a many-body system with competing time and length scales. This model is relevant to fundamentally understand both the structural and dynamical properties of materials,…

Colloidal particles, amphiphiles, and functionalized nanoparticles are examples of systems that frequently exhibit short-range attractions coupled with long-range repulsions. In this work, we observe striking differences in the dynamics of…

Soft Condensed Matter · Physics 2017-06-01 Jakub Pȩkalski , Andrew P. Santos , Athanassios Z. Panagiotopoulos

We study analytically the structural properties of a system with a short-range attraction and a competing long-range screened repulsion. This model contains the essential features of the effective interaction potential among charged…

Soft Condensed Matter · Physics 2009-11-11 M. Tarzia , A. Coniglio

We here discuss the results of 3d MonteCarlo simulations of a minimal lattice model for gelling systems. We focus on the dynamics, investigated by means of the time autocorrelation function of the density fluctuations and the particle mean…

Soft Condensed Matter · Physics 2007-05-23 E. Del Gado , A. Fierro , L. de Arcangelis , A. Coniglio

When classical systems fail to explore their entire configurational space, intriguing macroscopic phenomena like aging and glass formation may emerge. Also closed quanto-mechanical systems may stop wandering freely around the whole Hilbert…

Statistical Mechanics · Physics 2012-02-07 Giuseppe Carleo , Federico Becca , Marco Schiró , Michele Fabrizio

We demonstrate that an extended picture of kinetic constraints in glass-forming liquids is sufficient to explain dynamic anomalies observed in dense suspensions of strongly attracting colloidal particles. We augment a simple model of…

Statistical Mechanics · Physics 2009-11-10 Phillip L. Geissler , David R. Reichman

We present simulation results addressing the dynamics of a colloidal system with attractive interactions close to gelation. Our interaction also has a soft, long range repulsive barrier which suppresses liquid-gas type phase separation at…

Soft Condensed Matter · Physics 2007-05-23 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

We study the phase ordering dynamics of a two dimensional model colloidal solid using molecular dynamics simulations. The colloid particles interact with each other with a Hamaker potential modified by the presence of equatorial "patches"…

Disordered Systems and Neural Networks · Physics 2014-12-30 Chandana Mondal , Smarajit Karmakar , Surajit Sengupta

We study the formation of a colloidal gel by means of Molecular Dynamics simulations of a model for colloidal suspensions. A slowing down with gel-like features is observed at low temperatures and low volume fractions, due to the formation…

Soft Condensed Matter · Physics 2009-11-13 A. Fierro , E. Del Gado , A. de Candia , A. Coniglio

Using molecular dynamics simulations, we have determined that the nature of dynamical heterogeneity in jammed liquids is very sensitive to short-ranged attractions. Weakly attractive systems differ little from dense hard-sphere and…

Soft Condensed Matter · Physics 2007-05-23 David R. Reichman , Eran Rabani , Phillip L. Geissler

We study the effective electrostatic interactions between a pair of charged colloidal particles without salt ions while the system is confined in two dimensions. In particular we use a simplified model to elucidate the effects of rotational…

Soft Condensed Matter · Physics 2010-09-09 Chi-Lun Lee , Sio-Kit Ng

We present molecular dynamics simulations of aggregation kinetics in a colloidal suspension modeled as a highly asymmetric binary mixture. Starting from a configuration with largely uncorrelated colloidal particles the system relaxes by…

Statistical Mechanics · Physics 2007-05-23 Sorin Bastea

We use a combination of original light scattering techniques and particles with unique optical properties to investigate the behavior of suspensions of attractive colloids under gravitational stress, following over time the concentration…

Soft Condensed Matter · Physics 2015-05-27 Giovanni Brambilla , Stefano Buzzaccaro , R. Piazza , Ludovic Berthier , Luca Cipelletti

We describe a simple nearest-neighbor Ising model that is capable of supporting a gas, liquid, crystal, in characteristic relationship to each other. As the parameters of the model are varied one obtains characteristic patterns of phase…

Statistical Mechanics · Physics 2009-11-10 Davide Cellai , Hector Cuevas , Aonghus Lawlor , Gavin D. McCullagh , Kenneth A. Dawson

Gels in soft-matter systems are an important nonergodic state of matter. We study a colloid-polymer mixture which is quenched by increasing the polymer concentration, from a fluid to a gel. Using confocal microscopy, we study both the…

Soft Condensed Matter · Physics 2009-04-20 Takehiro Ohtsuka , C. Patrick Royall , Hajime Tanaka