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Energy relaxation in light-harvesting complexes has been extensively studied by various ultrafast spectroscopic techniques, the fastest processes being in the sub-100 fs range. At the same time much slower dynamics have been observed in…

Biological Physics · Physics 2016-04-27 Pavel Malý , J. Michael Gruber , Richard J. Cogdell , Tomáš Mančal , Rienk van Grondelle

The nature of excited states of open quantum systems produced by incoherent natural thermal light is analyzed based on a description of the generator of the dynamics. Natural thermal light is shown to generate long-lasting coherent dynamics…

Quantum Physics · Physics 2017-09-05 Leonardo A. Pachon , Juan D. Botero , Paul Brumer

Heat transfer is studied in the system of electron double layers of correlated composite fermion quantum liquids. In the near-field regime, the primary mechanism governing interlayer energy transfer is mediated by the Coulomb interaction of…

Mesoscale and Nanoscale Physics · Physics 2024-04-16 Dmitry Zverevich , Alex Levchenko

Chlorosomes are likely the largest and most efficient natural light-harvesting photosynthetic antenna systems. They are composed of large numbers of bacteriochlorophylls organized into supramolecular aggregates. We explore the microscopic…

Chemical Physics · Physics 2012-08-28 Takatoshi Fujita , Jennifer C. Brookes , Semion K. Saikin , Alan Aspuru-Guzik

Photoreduction of carbon dioxide (CO$_2$) on plasmonic structures is of great interest in photocatalysis to aid selectivity. While species commonly found in reaction environments and associated intermediates can steer the reaction down…

Computational Physics · Physics 2024-02-20 Zelio Fusco , Dirk Koenig , Sean C. Smith , Fiona Jean Beck

We have evaluated excitation energy transfer rates in photosyntetic complexes using the exact HEOM method and various approximate methods frequently used in the literature, namely, the F\"orster method, the Redfield method, the modified…

Chemical Physics · Physics 2014-05-19 Simon Jesenko , Marko Žnidarič

Light harvesting by photosystem II (PSII) in plants is highly efficient and acclimates to rapid changes in the intensity of sunlight. However, the mechanisms of PSII light harvesting have remained experimentally inaccessible. Using a…

Biological Physics · Physics 2016-04-27 Kapil Amarnath , Doran I. G. Bennett , Anna R. Schneider , Graham R. Fleming

We explore various design principles for efficient excitation energy transport in complex quantum systems. We investigate energy transfer efficiency in randomly disordered geometries consisting of up to 20 chromophores to explore spatial…

Quantum Physics · Physics 2014-02-25 M. Mohseni , A. Shabani , S. Lloyd , Y. Omar , H. Rabitz

Organic semiconducting polymers are currently of broad interest as potential low-cost materials for photovoltaic and light-emitting display applications. I will give an overview of our work in developing a consistent quantum dynamical…

Materials Science · Physics 2007-05-23 Eric R. Bittner , John Glen S. Ramon

The dynamics of a dimer coupled to two different environments each in a spin star configuration under the influence of decoherence is studied. The exact analytical expression for the transition probability in the dimer system is obtained…

Quantum Physics · Physics 2014-01-15 I. Sinayskiy , A. Marais , F. Petruccione , A. Ekert

We study transfer of coherent nuclear oscillations between an excitation energy donor and an acceptor in a simple dimeric electronic system coupled to an unstructured thermodynamic bath and some pronounced vibrational intramolecular mode.…

Chemical Physics · Physics 2015-01-08 Tomáš Mančal , Jakub Dostál , Jakub Pšenčík , Donatas Zigmantas

The high energy transfer efficiency of photosynthetic complexes has been a topic of research across many disciplines. Several attempts have been made in order to explain this energy transfer enhancement in terms of quantum mechanical…

Quantum Physics · Physics 2022-09-02 Ali Pedram , Barış Çakmak , Özgür E. Müstecaplıoğlu

We simulate the long-range inter-complex electronic energy transfer in Photosystem II -- from the antenna complex, via a core complex, to the reaction center -- using a non-Markovian (ZOFE) quantum master equation description that allows us…

Chemical Physics · Physics 2016-07-27 Jan J. J. Roden , Doran I. G. Bennett , K. Birgitta Whaley

Photochromic molecular structures constitute a unique platform for constructing molecular switches, sensors and memory devices. One of their most promising applications is as light-switchable electron acceptor or donor units. Here, we…

Chemical Physics · Physics 2020-07-21 Jakub K. Sowa , Emily A. Weiss , Tamar Seideman

Elucidating quantum coherence effects and geometrical factors for efficient energy transfer in photosynthesis has the potential to uncover non-classical design principles for advanced organic materials. We study energy transfer in a linear…

Biological Physics · Physics 2013-07-30 Qing Ai , Tzu-Chi Yen , Bih-Yaw Jin , Yuan-Chung Cheng

Dimer decimation scheme is introduced in order to study the kicked quantum systems exhibiting localization transition. The tight-binding representation of the model is mapped to a vectorized dimer where an asymptotic dissociation of the…

Chaotic Dynamics · Physics 2008-11-26 Tomaž Prosen , Indubala I Satija , Nausheen R. Shah

Rate equations are used to model spectroscopic observation of incoherent energy transfer in light-harvesting antenna systems based upon known structures. A two-parameter two-dimensional model is proposed. The transfer rates obtained, by…

Biological Physics · Physics 2009-10-31 Juhi-Lian Julian Ting

Based on the reduced density matrix method, we compare two different approaches to calculate the dynamics of the electron transfer in systems with donor, bridge, and acceptor. In the first approach a vibrational substructure is taken into…

Quantum Physics · Physics 2009-10-31 M. Schreiber , D. Kilin , U. Kleinekathoefer

We explore energy transfer in a generic three-level system, which is coupled to three non-equilibrium baths. Built on the concept of quantum heat engine, our three-level model describes non-equilibrium quantum processes including…

Quantum Physics · Physics 2016-02-17 Dazhi Xu , Chen Wang , Yang Zhao , Jianshu Cao

The fundamental physical mechanisms of energy transfer in photosynthetic complexes is not yet fully understood. In particular, the degree of efficiency or sensitivity of these systems for energy transfer is not known given their…

Quantum Physics · Physics 2013-05-30 Alireza Shabani , Masoud Mohseni , Herschel Rabitz , Seth Lloyd