Related papers: Nonadiabatic transitions in a Stark decelerator
We evaluate the shifts imparted to vibrational and rotational levels of a linear molecule by a nonresonant laser field at intensities of up to 10^12 W/cm^2. Both types of shift are found to be either positive or negative, depending on the…
In many quantum technologies adiabatic processes are used for coherent quantum state operations, offering inherent robustness to errors in the control parameters. The main limitation is the long operation time resulting from the requirement…
We use a numerically exact real-time path integral Monte Carlo scheme to compute electron transfer dynamics between two redox sites within a spin-boson approach. The case of asymmetric reactions is studied in detail in the least understood…
The observation of significant dipolar effects in gases of ultra-cold polar molecules typically demands a strong external electric field to polarize the molecules. We show that even in the absence of a significant polarization, dipolar…
Polar molecules in selected quantum states can be guided, decelerated, and trapped using electric fields created by microstructured electrodes on a chip. Here we explore how transitions between two of these quantum states can be induced…
Nontrivial spectral properties of non-Hermitian systems can give rise to intriguing effects that lack counterparts in Hermitian systems. For instance, when dynamically varying system parameters along a path enclosing an exceptional point…
A class of bistable "stator-rotor" molecules is proposed, where a stationary bridge (stator) connects the two electrodes and facilitates electron transport between them. The rotor part, which has a large dipole moment, is attached to an…
Collisions of polar $^{1}\Sigma$ state molecules at ultralow energies are considered, within a model that accounts for long-range dipole-dipole interactions, plus rotation of the molecules. We predict a substantial suppression of…
Topological phase transitions can occur in the dissipative dynamics of a quantum system when the ratio of matrix elements for competing transport channels is varied. Here we establish a relation between such behavior in a class of…
Nonadiabatic transition dynamics lies at the core of many electron/hole transfer, photoactivated, and vacuum field-coupled processes. About a century after Ehrenfest proposed "Phasenraum" and the Ehrenfest theorem, we report a conceptually…
By performing a slow adiabatic change between two traps of a quantum particle, it is possible to transform an eigenstate of the original trap into the corresponding eigenstate of the final trap. If no level crossings are involved, the…
We explore nonadiabatic quantum phase transitions in an Ising spin chain with a linearly time-dependent transverse field and two different spins per unit cell. Such a spin system passes through critical points with gapless excitations,…
Cold supersonic beams of molecules can be slowed down using a switched sequence of electrostatic field gradients. The energy to be removed is proportional to the mass of the molecules. Here we report deceleration of YbF, which is 7 times…
We present calculations for the action of laser pulses on vibrational transfer within the H2+ and Na2 molecules in the presence of dissipation due to photodissociation of the molecule. The laser fields perform closed loops surrounding…
Autocatalytic reaction system with a small number of molecules is studied numerically by stochastic particle simulations. A novel state due to fluctuation and discreteness in molecular numbers is found, characterized as extinction of…
Quasi-forbidden electronic transitions in atoms and quasi-degenerate vibronic transitions in molecules serve as powerful probes of hypothetical temporal variations of fundamental constants. Computation of the sensitivity of a transition to…
Electron conduction opacities are one of the main physics inputs for the calculation of low- and intermediate-mass stellar models, and a critical question is how to bridge calculations for moderate and strong degeneracy, which are…
We study the motion of electrons in a periodic background potential (usually resulting from a crystalline solid). For small velocities one would use either the non-magnetic or the magnetic Bloch hamiltonian, while in the relativistic regime…
A shortcut-to-adiabatic protocol for the realization of a fast and high-fidelity controlled-phase gate in Rydberg atoms is developed. The adiabatic state transfer, driven in the high-blockade limit, is sped up by compensating nonadiabatic…
We investigate the Lamb shift of centripetally accelerated atoms coupled to electromagnetic vacuum fluctuations. Focusing on a very small orbital radius (so that the tangential speed remains nonrelativistic and the proper centripetal…