Related papers: Heat and Gravitation. III. Mixtures
This first article of a series formulates the thermodynamics of ideal gases in a constant gravitational field in terms of an action principle that is closely integrated with thermodynamics. The theory, in its simplest form, does not deviate…
Some features of hydro- and thermodynamics, as applied to atmospheres and to stellar structures, are puzzling: 1. The suggestion, first made by Laplace, that our atmosphere has an adiabatic temperature distribution, is confirmed for the…
The formulas for the entropy of ideal gases mixture and the entropy change in mixing of ideal gases on the basis of the third law of thermodynamics were obtained. It is shown that when using these formulas, the Gibbs paradox within the…
There is the Gibbs theorem in thermodynamics, according to which the entropy of the mixture of ideal gases is equal to the sum of the entropies of the components of the mixture. J. W. Gibbs proved this by a mathematical derivation from the…
For binary mixtures of fluids without chemical reactions, but with components having different temperatures, the Hamilton principle of least action is able to produce the equation of motion for each component and a balance equation of the…
A convenient model for estimating the total entropy ({\Sigma}Si) of atmospheric gases based on physical action is proposed. This realistic approach is fully consistent with statistical mechanics, but uses the properties of translational,…
Starting from a formulation for the $dS$ element that includes movement, and considering the variation of the entropy Lorentz invariant, we found the relativistic transformations for thermodynamic systems that satisfy the three laws of…
This work is devoted to the consistent modeling of a three-phase mixture of a gas, a liquid and its vapor. Since the gas and the vapor are mis-cible, the mixture is subjected to a non-symmetric constraint on the volume. Adopting the Gibbs…
A classical (non-quantum-mechanical) relativistic ideal gas in thermodynamic equilibrium in a uniformly accelerated frame of reference is studied using Gibbs's microcanonical and grand canonical formulations of statistical mechanics. Using…
As no heat effect and mechanical work are observed, we have a simple experimental resolution of the Gibbs paradox: both the thermodynamic entropy of mixing and the Gibbs free energy change are zero during the formation of any ideal…
The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature of the theory since every material in…
The equations of state for an ideal generalized gas, like an ideal quantum gas, are expressed in terms of power laws of the temperature. The reduction of an ideal generalized gas to an ideal classical case occurs when the characteristic…
The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature since every material absorbs and…
The mixing of two different gases is one of the most common natural phenomena, with applications ranging from CO$_2$ capture to water purification. Traditionally, mixing is analyzed in the context of local thermal equilibrium, where systems…
The issue of the Gibbs paradox is that when considering mixing of two gases within classical thermodynamics, the entropy of mixing appears to be a discontinuous function of the difference between the gases: it is finite for whatever small…
A new lattice Boltzmann model for reactive ideal gas mixtures is presented. The model is an extension to reactive flows of the recently proposed multi-component lattice Boltzmann model for compressible ideal gas mixtures with Stefan-Maxwell…
The restriction of hydrodynamics to non-viscous, potential (gradient, irrotational) flows is a theory both simple and elegant; a favorite topic of introductory textbooks. It is known that this theory can be formulated as an action principle…
The thermodynamical entropy of a system which consists of different kinds of ideal gases is known to be defined successfully in the case when the differences are described by classical or quantum theory. Since these theories are special…
Arguments are presented that the assumption, implicit to traditional statistical thermodynamics, that at zero temperature all erratic motions cease, should be dispensed with. Assuming instead a random ultrarelativistic unobservable motion,…
Transport is one of the most important physical processes in all energy and length scales. Ideal gases and hydrodynamics are, respectively, two opposite limits of transport. Here, we present an unexpected mathematical connection between…