Related papers: Interface free energy or surface tension: definiti…
The surface free energy is the difference between the free energies for a system with open boundary conditions and the same system with periodic boundary conditions. We use the quantum transfer matrix formalism to express the surface free…
Even though the study of interfacial phenomena dates back to Laplace and was formalised by Gibbs, it appears that some concepts and relations among them are still causing some confusion and debates in the literature, particularly for…
Within a semi--infinite thre--dimensional lattice gas model describing the coexistence of two phases on a substrate, we study, by cluster expansion techniques, the free energy (line tension) associated with the contact line between the two…
We study interfaces with periodic boundary conditions in the low temperature phase of the improved Blume-Capel model on the simple cubic lattice. The interface free energy is defined by the difference of the free energy of a system with…
The properties of the interface between solid and melt are key to solidification and melting, as the interfacial free energy introduces a kinetic barrier to phase transitions. This makes solidification happen below the melting temperature,…
The statistical mechanics of equilibrium interfaces has been well-established for over a half century. In the last decade, a wealth of observations have made increasingly clear that a new perspective is required to describe interfaces…
The variation of energies associated with soft matter interfaces where surface inhomogeneities are present. These energies include the total bending and splay energy, the variable surface tension energy, a coupling energy between the total…
Particles bound to an interface interact because they deform its shape. The stresses that result are fully encoded in the geometry and described by a divergence-free surface stress tensor. This stress tensor can be used to express the force…
We study the dependence of the surface tension of a fluid interface on the density profile of a third suspended phase. By means of an approximated model for the binary mixture and of a perturbative approach we derive close formulas for the…
When the surface of a first material is brought into contact with the surface of a second material the contact region is called an interface. Since the time of James Clerk Maxwell it has been customary to treat a material electrically as…
From energy considerations there is reason to expect that the work done by Casimir forces during a slow displacement of the parallel plates reflects the free energy of the surface tension of the adjacent surfaces. We show this explicitly,…
We analyze the surface tension exerted at the interface between an active fluid and a solid boundary in terms of tangential forces. Focusing on active systems known to possess an equation of state for the pressure, we show that interfacial…
The contribution of the smectic-nematic interface to the surface energy of a nematic liquid crystal sample is analyzed. By means of a simple model it is shown that the surface energy depends on the thickness of the region over which the…
The surface free energies, interfacial tensions and correlation lengths of the Andrews-Baxter-Forrester models in regimes III and IV are calculated with fixed boundary conditions. The interfacial tensions are calculated between arbitrary…
An example of capillary phenomena commonly seen and often studied is a droplet of water hanging in air from a horizontal surface. A thin capillary surface interface between the liquid and gas develops tangential surface tension, which…
We consider an interface with surface tension that separates a perfectly conducting inviscid fluid from a vacuum. The fluid flow is governed by the equations of ideal compressible magnetohydrodynamics (MHD), while the electric and magnetic…
We derive the interfacial tension of a semi infinite two phase binary mixture of partially miscible fluids in contact with a planar surface. In our model we take a surface free energy term into account omitted by Cahn [J. W. Cahn, J.…
We derive the energy of the surface between the normal and superfluid components of a mixed phase of a system composed of two particle species with different densities. The surface energy is obtained by the integration of the free energy…
Several aspects of the theory of the coexistence of phases and equilibrium forms are discussed. In section 1, the problem is studied from the point of view of thermodynamics. In section 2, the statistical mechanical theory is introduced. We…
We consider the atomistic origin and the main mechanisms determining the energy of a liquid interface after relaxation. A simple theory is constructed for the monatomic densely packed liquids that allows calculation of the surface tension…