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In this paper we study a distance-dependent surface tension, defined as the free-energy cost to put metastable states at a given distance. This will be done in the framework of a disordered microscopic model with Kac interactions that can…

Statistical Mechanics · Physics 2015-05-14 Elia Zarinelli , Silvio Franz

The elastic deformation of a soft solid induced by capillary forces crucially relies on the excess stress inside the solid-liquid interface. While for a liquid-liquid interface this "surface stress" is strictly identical to the "surface…

Soft Condensed Matter · Physics 2015-06-17 Joost H. Weijs , Jacco H. Snoeijer , Bruno Andreotti

The influence of nonequilibrium bulk conditions on the properties of the interfaces exhibited by a kinetic Ising--like model system with nonequilibrium steady states is studied. The system is maintained out of equilibrium by perturbing the…

Statistical Mechanics · Physics 2009-11-10 P. I. Hurtado , P. L. Garrido , J. Marro

We propose and analyze a simple variational model for dislocations at semi-coherent interfaces. The energy functional describes the competition between two terms: a surface energy induced by dislocations that compensate the lattice misfit…

Analysis of PDEs · Mathematics 2019-02-19 Silvio Fanzon , Mariapia Palombaro , Marcello Ponsiglione

We consider the wetting transition on a planar surface in contact with a semi-infinite fluid. In the classical approach, the surface is assumed to be solid, and when interaction between solid and fluid is sufficiently short-range, the…

Chemical Physics · Physics 2008-01-30 Henri Gouin

Surface tension and wetting are dominating physical effects in micro and nanoscale flows. We present an efficient and reliable model of surface tension and equilibrium contact angles in Smoothed Particle Hydrodynamics for free-surface…

Fluid Dynamics · Physics 2024-05-22 Michael Blank , Prapanch Nair , Thorsten Pöschel

Interfaces in phase-separated driven liquids are one example of how energy input at the single-particle level changes the long-length-scale material properties of nonequilibrium systems. Here, we measure interfacial fluctuations in…

Statistical Mechanics · Physics 2019-03-27 Clara del Junco , Suriyanarayanan Vaikuntanathan

The transport of energy in a moving fluid with a simply connected free surface is analyzed, taking into account the contribution of surface tension. This is done by following a "control volume" with arbitrary, specified velocity,…

Fluid Dynamics · Physics 2021-06-02 Tomas Bohr , Bernhard Scheichl

One may impose to a system with spontaneous broken symmetry, boundary conditions which correspond to different pure states at two ends of a sample. For a discrete Ising-like broken symmetry, boundary conditions with opposite spins in two…

Condensed Matter · Physics 2007-05-23 E. Brézin , C. De Dominicis

Recent developments in statistical mechanics have allowed the estimation of equilibrium free energies from the statistics of work measurements during processes that drive the system out of equilibrium. Here a different class of processes is…

Statistical Mechanics · Physics 2009-11-11 Artur B. Adib

Starting for the Stillinger and Weber expression for the free energy of supercooled liquids, we extend the free energy to the case in which two time scales separate and the system is in quasi-equilibrium. The concept of an effective…

Soft Condensed Matter · Physics 2012-11-26 Antonio Scala , Francesco Sciortino

This work addresses the question of whether it is possible to define simple pair-wise interaction terms to approximate free energies of proteins or polymers. Rather than ask how reliable a potential of mean force is, one can ask how…

Soft Condensed Matter · Physics 2009-10-31 Dirk Reith , Thomas Huber , Florian Mueller-Plathe , Andrew E. Torda

Surface stress and surface energy are fundamental quantities which characterize the interface between two materials. Although these quantities are identical for interfaces involving only fluids, the Shuttleworth effect demonstrates that…

Soft Condensed Matter · Physics 2018-05-09 Rafael D. Schulman , Miguel Trejo , Thomas Salez , Elie Raphael , Kari Dalnoki-Veress

We study an ideal-gas-like model where the particles exchange energy stochastically, through energy conserving scattering processes, which take place if and only if at least one of the two particles has energy below a certain energy…

Statistical Mechanics · Physics 2015-05-27 Asim Ghosh , Urna Basu , Anirban Chakraborti , Bikas K. Chakrabarti

A variational model for describing the morphology of two-phase continua by allowing for the interplay between coherent and incoherent interfaces is introduced. Coherent interfaces are characterized by the microscopical arrangement of atoms…

Analysis of PDEs · Mathematics 2023-10-24 Randy Llerena , Paolo Piovano

We consider membranes adhered through specific receptor-ligand bonds. Thermal undulations of the membrane induce effective interactions between adhesion sites. We derive an upper bound to the free energy that is independent of interaction…

Soft Condensed Matter · Physics 2011-07-04 Thomas Speck

The equation of motions and the conditions on surfaces and edges between fluids and solids in presence of non-constant surface energies, as in the case of surfactants attached to the fluid particles at the interfaces, are revisited under…

Soft Condensed Matter · Physics 2013-11-06 Henri Gouin

We present in this Letter a free-energy approach to the dynamics of a fluid near a nanostructured surface. The model accounts both for the static phase equilibrium in the vicinity of the surface (wetting angles, Cassie-Wenzel transition)…

Soft Condensed Matter · Physics 2016-09-08 Thierry Biben , Laurent Joly

The quantitative knowledge of interface anisotropy in lattice models is a major issue, both for the parametrization of continuum interface models, and for the analysis of experimental observations. In this paper, we focus on the anisotropy…

Statistical Mechanics · Physics 2022-02-09 Luca Gagliardi , Olivier Pierre-Louis

An intrinsic feature of nearly all internal interfaces in crystalline systems (homo- and hetero-phase) is the presence of disconnections (topological line defects constrained to the interface that have both step and dislocation character).…

Materials Science · Physics 2023-05-12 Caihao Qiu , Marco Salvalaglio , David J. Srolovitz , Jian Han