Related papers: Are all Quasi-static Processes Reversible?
Two approaches are outlined to characterize the fluctuation behavior of work applied to a system by a slow change of a parameter. One approach uses the adiabatic theorems of quantum and classical mechanics, the other one is based on the…
The characterization of irreversibility in general quantum processes is an open problem of increasing techno- logical relevance. Yet, the tools currently available to this aim are mostly limited to the assessment of dynamics induced by…
The dynamics of irreversible relaxation of non-equilibrium macroscopic systems is discussed. Arguments are developed showing that the general process is supported by two independent successive mechanisms. One is mixing and it follows pure…
The performance of a generic, cyclic heat engine between two heat reservoirs is discussed within a linear-irreversible framework. The Onsager reciprocal relation is derived as a consequence of the equivalence between quasi-static and…
Transitions from reversible to irreversible or fluctuating states above a critical density and shear amplitude have been extensively studied in non-thermal cyclically sheared suspensions and amorphous solids. Here, we propose that the same…
The minimal set of thermodynamic control parameters consists of a statistical (thermal) and a mechanical one. These suffice to introduce all the pertinent thermodynamic variables; thermodynamic processes can then be defined as paths on this…
Understanding the dynamical consequences of quantum phase transitions on thermodynamical quantities, such as work statistics and entropy production, is one of the most intriguing aspect of quantum many-body systems, pinpointing the…
We experimentally realize quasistatic adiabatic processes using a single optically-trapped micro- sphere immersed in water whose effective temperature is controlled by an external random electric field. A full energetic characterization of…
The relationship between thermodynamics and statistical physics is valid in the thermodynamic limit - when the number of particles becomes very large. Here, we study thermodynamics in the opposite regime - at both the nano scale, and when…
When a physical system is put in contact with a very large thermal bath, it undergoes a dissipative (i.e., an apparently irreversible) process that leads to thermal equilibrium. This dynamical process can be described fully within quantum…
The direction of the steady-state heat currents across a generic quantum system connected to multiple baths may be engineered so as to realize virtually any thermodynamic cycle. In spite of their versatility such continuous…
Nonequilibrium steady state of isothermal biochemical cycle kinetics has been extensively studied, but much less investigated under non-isothermal conditions. However, once the heat exchange between subsystems is rather slow, the isothermal…
We consider a macroscopic system in contact with boundary reservoirs and/or under the action of an external field. We discuss the case in which the external forcing depends explicitly on time and drives the system from a nonequilibrium…
A semi-process is an analog of the semi-flow for non-autonomous differential equations or inclusions. We prove an abstract result on the existence of measurable semi-processes in the situations where there is no uniqueness. Also, we allow…
The entropy production rate is a key quantity in irreversible thermodynamics. In this work, we concentrate on the realization of entropy production rate in chemical reaction systems in terms of the experimentally measurable reaction rate.…
If a system is at thermodynamic equilibrium, an observer cannot tell whether a film of it is being played forward or in reverse: any transition will occur with the same frequency in the forward as in the reverse direction. However, if…
A dynamical phase transition from reversible to irreversible behavior occurs when particle suspensions are subjected to uniform oscillatory shear, even in the Stokes flow limit. We consider a more general situation with non-uniform strain…
The aim of this paper is to determine lost works in a molecular engine and compare results with macro (classical) heat engines. Firstly, irreversible thermodynamics are reviewed for macro and molecular cycles. Secondly, irreversible…
Quasi-static protocols for systems that feature a mixed phase-space with both chaos and quasi-regular regions are beyond the standard paradigm of adiabatic processes. We focus on a many-body system of atoms that are described by the…
The training algorithms for AI systems all introduce far-from-equilibrium dynamical processes, and understanding the irreversibility of these algorithms is a fundamental step towards understanding the learning dynamics of modern AI systems.…