Related papers: Derivation of Boltzmann Principle
The domain of validity of standard thermodynamics and Boltzmann-Gibbs statistical mechanics is discussed and then formally enlarged in order to hopefully cover a variety of anomalous systems. The generalization concerns {\it nonextensive}…
We argue that one can model deviations from the ensemble average in non-equilibrium statistical mechanics by promoting the Boltzmann equation to an equation in terms of {\em functionals} , representing possible candidates for phase space…
When making the connection between the thermodynamics of irreversible processes and the theory of stochastic processes through the fluctuation-dissipation theorem, it is necessary to invoke a postulate of the Einstein-Boltzmann type. For…
Thermodynamics, introduced over two centuries ago, remains foundational to our understanding of physical, chemical, biological, and engineering systems. Its principles are traditionally grounded in the statistical mechanics framework, which…
This paper's objective is to improve the existing proof of the derivation of the Rayleigh--Boltzmann equation from the nonideal Rayleigh gas [6], yielding a far faster convergence rate. This equation is a linear version of the Boltzmann…
The atomic scale is the only relevant thermodynamic scale in our universe, since quantum properties restrict classical considerations of subatomic physics and disappear for larger scales. Then the characteristic energy that dictates the…
We derive the Hamiltonian formulation of classical mechanics directly, without reference to Lagrangian mechanics. We start from the definition of states in terms of labels used to identify them, and show how, under a deterministic and…
Quantum mechanics is one of the basic theories of modern physics. Here, the famous Schr\"odinger equation and the differential operators representing mechanical quantities in quantum mechanics are derived, just based on the principle that…
The $H$-theorem, originally derived at the level of Boltzmann non-linear kinetic equation for a dilute gas undergoing elastic collisions, strongly constrains the velocity distribution of the gas to evolve irreversibly towards equilibrium.…
We introduce a class of Boltzmann equations on the real line, which constitute extensions of the classical Kac caricature. The collisional gain operators are defined by smoothing transformations with quite general properties. By…
Boltzmann's H-Theorem, formulated 150 years ago in terms of H-function that also bears his name, is one of the most celebrated theorems of science and paved the way for the development of nonequilibrium statistical mechanics. Nevertheless,…
A detailed derivation of the Lattice Boltzmann (LB) scheme for relativistic fluids recently proposed in Ref. [1], is presented. The method is numerically validated and applied to the case of two quite different relativistic fluid dynamic…
Gravity is so different from other fundamental forces that it is now essentially treated as a non-fundamental force of entropic origin. A number of good studies have been carried out in this direction. Quantum gravity has also significantly…
We review Boltzmann machines and energy-based models. A Boltzmann machine defines a probability distribution over binary-valued patterns. One can learn parameters of a Boltzmann machine via gradient based approaches in a way that log…
We present a mathematical theory of dynamical fluctuations for the hard sphere gas in the Boltzmann-Grad limit. We prove that: (1) fluctuations of the empirical measure from the solution of the Boltzmann equation, scaled with the square…
We derive the classical Hamilton-Jacobi equation from first principles as the natural description for smooth stochastic processes when one neglects stochastic velocity fluctuations. The Schr\"{o}dinger equation is shown to be the natural…
It is shown that Schroedinger's equation may be derived from three postulates. The first is a kind of statistical metamorphosis of classical mechanics, a set of two relations which are obtained from the canonical equations of particle…
The purpose of this paper is two-fold. First, to make clear (and de-mystify) the basic concepts of classical thermodynamics, and thus to enable the integration of thermodynamics within systems modeling and control. Second, to demonstrate…
The housekeeping heat is the energy exchanged between a system and its environment in a nonequilibrium process that results from the violation of detailed balance. We describe fluctuations of the housekeeping heat in mesoscopic systems…
We have proved the quantum mechanical H-theorem for dilute Bose and Fermi gases by generalizing the quantum statistical Boltzmann equation for all possible many-body elastic collisions among the particles in the quantum gases within the…