Related papers: Derivation of Boltzmann Principle
Boltzmann's Principle S = k ln W was repeatedly criticized by Einstein since it lacked a proper dynamical foundation in view of the thermal motion of the particles, out of which a physical system consists. This suggests, in particular, that…
In the last decades the theory of large deviations has become a main tool in statistical mechanics especially in the study of non--equilibrium. In a rational reconstruction of the story one must recognize the ideal connection and debt of…
In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann's analysis,…
Introducing the Boltzmann distribution very early in a statistical thermodynamics course (in the spirit of Feynmann) has many didactic advantages, in particular that of easily deriving the Gibbs entropy formula. In this note, a short…
A framework for relativistic thermodynamics and statistical physics is built by first exploiting the symmetries between energy and momentum in the derivation of the Boltzmann distribution, then using Einstein's energy-momentum relationship…
The application of classical methods of statistical mechanics, originally developed by Ludwig Boltzmann in gas dynamics, to the description of social phenomena is a successful story that we try to outline in this paper. On one hand, it is…
In the mid-19th century, both the laws of mechanics and thermodynamics were known, and both appeared fundamental. This was changed by Boltzmann and Gibbs, who showed that thermodynamics can be *derived*, by applying mechanics to very large…
The Boltzmann equation is one of the most famous equations and has vast applications in modern science. In the current study, we take the randomness of binary collisions into consideration and generalize the classical Boltzmann equation…
Boltzmann's principle S=k ln W allows to extend equilibrium thermo-statistics to ``Small'' systems without invoking the thermodynamic limit. The clue is to base statistical probability on ensemble averaging and not on time averaging. It is…
It will be shown, how the Boltzmannian ideas on statistical physics can be naturally applied to nonequilibrium thermodynamics. A similar approach for treating nonequilibrium phenomena has been successfully used by Einstein and Smoluchowski…
We reconsider the thermodynamic derivation by L. Boltzmann of the Stefan law and we generalize it for various different physical systems {\it whose chemical potential vanishes}. Being only based on classical arguments, therefore independent…
The Stefan-Boltzmann (SB) law relates the emissivity $q$, given in $Wm^{-2}$, of an ideal black-body cavity at thermal equilibrium to the fourth power of the absolute temperature $T$ as $q=\sigma T^4$, with $\sigma = 5.67 \times 10^{-8} \ W…
In statistical mechanics the zeroth law of thermodynamics is taken as a postulate which, as its name indicates, logically precedes the first and second laws. Treating it as a postulate has consequences for how temperature is introduced into…
Stefan-Boltzmann law was empirically deduced by Stefan in 1874 by fitting existing experiments and theoretically validated by Boltzmann in 1884 on the basis of a classical model involving thermodynamics principles and the Maxwell equations.…
We review the derivation of the Boltzmann equation and its cosmological applications in this paper. The derivation of the Boltzmann equation, especially the collision term, is discussed in detail in the language of the quantum field theory…
Through the H theorem, Bolzmann attempted to validate the foundations of statistical mechanics. However, it is incompatible with the fundamental laws of mechanics because its deduction requires the introduction of probability. In this paper…
We study the possibility of applying statistical mechanics to generally covariant quantum theories with a vanishing Hamiltonian. We show that (under certain appropiate conditions) this makes sense, in spite of the absence of a notion of…
The problem of energy conservation in the lattice Boltzmann method is solved. A novel model with energy conservation is derived from Boltzmann's kinetic theory. It is demonstrated that the full thermo-hydrodynamics pertinent to the…
Emergence of one-time-direction macroscopic evolution of a classical system of two mixed gases having different temperatures is derived and explained. The analysis performed at the microscopic level, where the time-symmetric laws of…
We review some results concerning the derivation of the Boltzmann equation starting from the many-body classical Hamiltonian dynamics. In particular, the celebrated paper by O. E. Lanford III and the more recent papers [13, 23] are…