Related papers: Disconnected Glass-Glass Transitions and Diffusion…
The dynamics of dislocations is reported to exhibit glassy properties. We study numerically various versions of 2d edge dislocation systems in the absence of externally applied stress. Two types of glassy behavior are identified: (i)…
We report molecular-dynamics simulations on a three-dimensional two-component Lennard-Jones fluid. We identify two distinct static length scales. The longer length scale, which diverges at low temperatures, is continuous with the…
Using a general model for the equilibrium dynamics of supercooled liquids, I compute from molecular properties the emergent length and time scales that govern the nonequilibrium relaxation behavior of amorphous ice prepared by rapid…
Attractive colloids display two distinct amorphous solid phases: the attractive glass, due to particle bonding, and the repulsive glass, due to the hard core repulsion. By means of a microscopic mean field approach, we analyze their…
The most accepted origin for the water anomalous behavior is the phase transition between two liquids (LLPT) in the supercooled regime connected to the glassy first order phase transition at lower temperatures. Two length scales potentials…
Relaxation of shear bands in a Pd40Ni40P20 bulk metallic glass was investigated by a combination of radiotracer diffusion and molecular dynamics (MD) simulations, allowing to determine for the first time the effective activation enthalpy of…
It has been demonstrated recently that supercooled liquids sharing simple structural features (e.g. pair distribution functions) may exhibit strikingly distinct dynamical behavior. Here we show that a more subtle structural feature…
Computer simulations are used to study a three-dimensional polydisperse model glassformer in a replica-coupling setup where an attractive field $\propto - \varepsilon Q$ of strength $\varepsilon$ can adjust the similarity of the system to a…
We develop a replicated liquid theory for structural glasses which exhibit spatial variation of physical quantities along one axis, say $z$-axis. The theory becomes exact with infinite transverse dimension $d-1 \to \infty$. It provides an…
We study a model in which particles interact through a hard-core repulsion complemented by a short-ranged attractive potential, of the kind found in colloidal suspensions. Combining theoretical and numerical work we locate the line of…
The Gilroy-Phillips model of relaxational jumps in asymmetric double-well potentials, developed for the Arrhenius-type secondary relaxations of the glass phase, is extended to a formal description of the breakdown of the shear modulus at…
A dynamical theory is constructed to describe spectral diffusion in glasses in the temperature range near 1 Kelvin on long time scales. The theory invokes interacting tunneling centers (TLS) which provide an excess contribution to the…
According to the classical theory of Brownian motion, the mean squared displacement of diffusing particles evolves linearly with time whereas the distribution of their displacements is Gaussian. However, recent experiments on mesoscopic…
The phase behavior of hard-sphere particles interacting with a short-ranged potential is studied in the limit of infinite space dimensionality via the Franz-Parisi approach and the replica method of disordered systems. For an attractive…
Glass-to-glass and liquid-to-liquid phase transitions were observed many years ago in bulk and confined water with or without applied pressure. It is shown that they result from the competition of two-liquid phases separated by an enthalpy…
We developed a generalized replicated liquid theory for glassy phases of non-spherical uniaxial molecules and colloids, which becomes exact in the large dimensional limit $d\to\infty$. We then applied the scheme to patchy colloids with…
Because of the negative inclination of the solid-liquid phase separation line in water, ice Ih melts on compression. On further increase in pressure the liquid water transforms into a high density metastable glassy state, characterized by a…
Particle motion of a Lennard-Jones supercooled liquid near the glass transition is studied by molecular dynamics simulations. We analyze the wave vector dependence of relaxation times in the incoherent self scattering function and show that…
We analyze a one-dimensional two-scalar fields reaction advection diffusion model for the globally subcritical transition to turbulence. In this model, the homogeneous turbulent state is disconnected from the laminar one and disappears in a…
Understanding glass formation is a challenge because the existence of a true glass state, distinct from liquid and solid, remains elusive: Glasses are liquids that have become too viscous to flow. An old idea, as yet unproven…