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Unlike atoms, colloidal particles are not identical, but can only be synthesised within a finite size tolerance. Colloids are therefore polydisperse, i.e. mixtures of infinitely many components with sizes drawn from a continuous…

Soft Condensed Matter · Physics 2009-11-07 R. M. L. Evans , C. B. Holmes

We use numerical simulations to study the crystallization of monodisperse systems of hard aspherical particles. We find that particle shape and crystallizability can be easily related to each other when particles are characterized in terms…

Soft Condensed Matter · Physics 2015-05-18 William L. Miller , Behnaz Bozorgui , Angelo Cacciuto

We address the crystallization of monodisperse hard spheres in terms of the properties of finite- size crystalline clusters. By means of large scale event-driven Molecular Dynamics simulations, we study systems at different packing…

The crystal-melt interfaces of a binary hard-sphere fluid mixture in coexistence with a single-component hard-sphere crystal is investigated using molecular-dynamics simulation. In the system under study, the fluid phase consists of a…

Chemical Physics · Physics 2009-11-07 Rachel Sibug-Aga , Brian B. Laird

We have carried out computer simulations of overcompressed suspensions of hard monodisperse ellipsoids and observed their crystallization dynamics. The system was compressed very rapidly in order to reach the regime of slow, glass-like…

Soft Condensed Matter · Physics 2013-10-01 Sven Dorosz , Tanja Schilling

We use dynamic light scattering and numerical simulations to study the approach to equilibrium and the equilibrium dynamics of systems of colloidal hard spheres over a broad range of density, from dilute systems up to very concentrated…

We use dynamic light scattering and computer simulations to study equilibrium dynamics and dynamic heterogeneity in concentrated suspensions of colloidal hard spheres. Our study covers an unprecedented density range and spans seven decades…

We determined bulk crystal nucleation rates in aqueous suspensions of charged spheres at low metastability. Experiments were performed in dependence on electrolyte concen-tration and for two different particle number densities. The…

Soft Condensed Matter · Physics 2021-11-04 Jürgen Schwarz , Paul Leiderer , Thomas Palberg

We consider a system of spherical particles interacting by means of a pair potential equal to a finite constant for interparticle distances smaller than the sphere diameter and zero outside. The model may be a prototype for the interaction…

Statistical Mechanics · Physics 2009-10-31 C. N. Likos , M. Watzlawek , H. Loewen

Hard sphere colloidal particles are a basic model system for general research into phase behavior, ordering and out-equilibrium glass transitions. Experimentally it has been shown that oscillatory shearing of a monodisperse hard sphere…

Soft Condensed Matter · Physics 2016-01-13 Nick Koumakis , John F. Brady , George Petekidis

We investigate the formation of cluster crystals with multiply occupied lattice sites on a spherical surface in systems of ultra-soft particles interacting via repulsive, bounded pair potentials. Not all interactions of this kind lead to…

Soft Condensed Matter · Physics 2018-07-31 Stefano Franzini , Luciano Reatto , Davide Pini

Competing short-range attractive (SA) and long range repulsive (LR) interactions have been invoked to describe colloid or protein solutions, as well as membrane proteins interactions mediated by lipid molecules. Using Langevin dynamics…

Soft Condensed Matter · Physics 2025-05-26 Zihan Tan , Vania Calandrini , Jan K. G. Dhont , Gerhard Nägele

We study the phase behavior of hard spheres confined between two parallel hard plates using extensive computer simulations. We determine the full equilibrium phase diagram for arbitrary densities and plate separations from one to five…

Soft Condensed Matter · Physics 2009-11-11 Andrea Fortini , Marjolein Dijkstra

We study theoretically and numerically the elastic properties of hard sphere glasses, and provide a real-space description of their mechanical stability. In contrast to repulsive particles at zero-temperature, we argue that the presence of…

Soft Condensed Matter · Physics 2015-06-18 E. DeGiuli , E. Lerner , C. Brito , M. Wyart

We investigate the phase diagram of a fluid of hard-core disks confined to the surface of a sphere and whose interaction potential contains a short-range attraction followed by a long-range repulsive tail (SALR). Based on previous works in…

Soft Condensed Matter · Physics 2021-11-24 Stefano Franzini , Luciano Reatto , Davide Pini

Liquids in systems with spherically symmetric interactions are not thermodynamically stable when the range of the attraction is reduced sufficiently. However, these metastable liquids have lifetimes long enough that they are readily…

Soft Condensed Matter · Physics 2018-06-15 C. Patrick Royall

The rapid collapse of a polymer, due to external forces or changes in solvent, yields a long-lived `crumpled globule.' The conjectured fractal structure shaped by hierarchical collapse dynamics has proved difficult to establish, even with…

Soft Condensed Matter · Physics 2015-10-07 Guy Bunin , Mehran Kardar

We performed dynamic simulations of spheres with short-range attractive interactions for many values of interaction strength and range. Fast crystallization occurs in a localized region of this parameter space, but the character of…

Soft Condensed Matter · Physics 2015-07-27 Thomas K. Haxton , Lester O. Hedges , Stephen Whitelam

We explore the glassy dynamics of soft colloids using microgels and charged particles interacting by steric and screened Coulomb interactions, respectively. In the supercooled regime, the structural relaxation time $\tau_\alpha$ of both…

When colloidal particles form a crystal phase on a spherical template, their packing is governed by the effective interaction between them and the elastic strain of bending the growing crystal. For example, if growth commences under…

Soft Condensed Matter · Physics 2017-08-09 Stefan Paquay , Gert-Jan Both , Paul van der Schoot