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The (isothermic) compressibility of lattice knots can be examined as a model of the effects of topology and geometry on the compressibility of ring polymers. In this paper, the compressibility of minimal length lattice knots in the simple…

Soft Condensed Matter · Physics 2015-06-04 Esaias J Janse van Rensburg , Andrew Rechnitzer

This study investigates the probability of threading in star catenanes under good solvent conditions using molecular dynamics simulations, emphasizing the influence of ring rigidity. Threading in these systems arises from the interplay…

Computational Physics · Physics 2024-12-12 Zahra Ahmadian Dehaghani

Using a model of idealized, crossed one-dimensional quantum wires we construct a novel model for a single electron on tunneling-coupled systems of one-dimensional quantum rings. We explore and find that topology can affect the energetics of…

Mesoscale and Nanoscale Physics · Physics 2020-07-07 Colin Riggert , Kieran Mullen

It is nontrivial whether the average size of a ring polymer should become smaller or larger under a topological constraint. Making use of some knot invariants, we evaluate numerically the mean square radius of gyration for ring polymers…

Statistical Mechanics · Physics 2016-08-31 Miyuki K. Shimamura , Tetsuo Deguchi

The effects of entanglement in solutions and melts of unknotted ring polymers have been addressed by several theoretical and numerical studies. The system properties have been typically profiled as a function of ring contour length at fixed…

Soft Condensed Matter · Physics 2011-11-29 Angelo Rosa , Enzo Orlandini , Luca Tubiana , Cristian Micheletti

In the first part of this work a summary is provided of some recent experiments and theoretical results which are relevant in the research of systems of polymer rings in nontrivial topological conformations. Next, some advances in modeling…

Soft Condensed Matter · Physics 2014-02-04 Yani Zhao , Franco Ferrari

The statistical mechanics of single polymer knots is studied using Monte Carlo simulations. The polymers are considered on a cubic lattice and their conformations are randomly changed with the help of pivot transformations. After each…

Soft Condensed Matter · Physics 2015-06-12 Yani Zhao , Franco Ferrari

One measure of geometrical complexity of a spatial curve is the number of crossings in a planar projection of the curve. For $N$-noded ring polymers with a fixed knot type, we evaluate numerically the average of the crossing number over…

Soft Condensed Matter · Physics 2016-08-31 Miyuki K. Shimamura , Tetsuo Deguchi

Scaling arguments are used to analyze the size of topologically constrained closed ring polymer with excluded volume. It is found that there exists a finite range of polymer thickness (excluded volume) in which self-avoidance is unimportant…

Soft Condensed Matter · Physics 2007-05-23 A. Yu. Grosberg

A coarse-grained computational model is used to investigate how the bending rigidity of a polymer under tension affects the formation of a trefoil knot. Thermodynamic integration techniques are applied to demonstrate that the free-energy…

Soft Condensed Matter · Physics 2012-11-13 Richard Matthews , Ard A. Louis , Christos N. Likos

In this work the thermodynamic properties of short polymer knots (up to 120 segments) defined on a simple cubic lattice are studied with the help of the Wang-Landau Monte Carlo algorithm. The sampling process is performed using pivot…

Soft Condensed Matter · Physics 2015-06-16 Yani Zhao , Franco Ferrari

In this paper we examine the relative knotting probabilities in a lattice model of ring polymers confined in a cavity. The model is of a lattice knot of size $n$ in the cubic lattice, confined to a cube of side-length $L$ and with volume…

Soft Condensed Matter · Physics 2025-03-17 EJ Janse van Rensburg , E Orlandini , MC Tesi

Topological entanglements are abundant, and often detrimental, in polymeric systems in biology and materials science. Here we theoretically investigate the topological simplification of knots by diffusing slip-links (SLs), which may…

Soft Condensed Matter · Physics 2020-11-02 Andrea Bonato , Davide Marenduzzo , Davide Michieletto

We develop a theoretical description of the topological disentanglement occurring when torus knots reach the ends of a semi-flexible polymer under tension. These include decays into simpler knots and total unknotting. The minimal number of…

Statistical Mechanics · Physics 2020-11-04 Michele Caraglio , Boris Marcone , Fulvio Baldovin , Enzo Orlandini , Attilio L. Stella

Hydrodynamic interactions as modeled by Multi-Particle Collision Dynamics can dramatically influence the dynamics of fully flexible, ring-shaped polymers in ways not known for any other polymer architecture or topology. We show that steady…

Soft Condensed Matter · Physics 2019-09-09 M. Liebetreu , C. N. Likos

Many experiments have been done to determine the relative strength of different knots, and these show that the break in a knotted rope almost invariably occurs at a point just outside the `entrance' to the knot. The influence of knots on…

Materials Science · Physics 2009-10-31 A. Marco Saitta , Paul D. Soper , E. Wasserman , Michael L. Klein

Elucidating the physics of a concentrated suspension of ring polymers, or of an ensemble of ring polymers in a complex environment, is an important outstanding question in polymer physics. Many of the characteristic features of these…

Soft Condensed Matter · Physics 2017-08-09 Davide Michieletto , Enzo Orlandini , Davide Marenduzzo , Matthew S. Turner

In polymer physics it is typically assumed that excluded volume interactions are effectively screened in polymer melts. Hence, chains could be described by an effective random walk without excluded volume interactions. In this letter, we…

Soft Condensed Matter · Physics 2017-10-31 Hendrik Meyer , Eric Horwath , Peter Virnau

We study how confinement affects topology and conformations in polymer films of varying thickness $h$. The knotting probability exhibits a maximum at intermediate thicknesses near the bulk radius of gyration $h \approx R_\mathrm{g,bulk}$,…

Soft Condensed Matter · Physics 2026-05-05 Maurice P. Schmitt , Hendrik Meyer , Peter Virnau

Knots are deeply entangled with every branch of science. One of the biggest open challenges in knot theory is to formalise a knot invariant that can unambiguously and efficiently distinguish any two knotted curves. Additionally, the…