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Extremal principles are fundamental in our interpretation of phenomena in nature. One of the best known examples is the second law of thermodynamics, governing most physical and chemical systems and stating the continuous increase of…

Statistical Mechanics · Physics 2007-05-23 Dirk Helbing , Tamas Vicsek

Stochastic thermodynamics and the associated fluctuation relations provide the means to extend the fundamental laws of thermodynamics to small scales and systems out of equilibrium. The fluctuating thermodynamic variables are usually…

Statistical Mechanics · Physics 2015-05-29 Aki Kutvonen , Tapio Ala-Nissilä , Jukka P. Pekola

This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized…

Quantum Physics · Physics 2015-08-14 Marius Krumm

This work assembles some basic theoretical elements on thermal equilibrium, stability conditions, and fluctuation theory in self-gravitating systems illustrated with a few examples. Thermodynamics deals with states that have settled down…

Astrophysics · Physics 2022-10-12 Joseph Katz

Fluctuation theorems and the second law of thermodynamics are powerful relations constraining the behavior of out-of-equilibrium systems. While there exist generalizations of these relations to feedback controlled quantum systems, their…

Quantum Physics · Physics 2024-10-07 Kacper Prech , Patrick P. Potts

We study the Fluctuation Theorem (FT) for entropy production in chaotic discrete-time dynamical systems on compact metric spaces, and extend it to empirical measures, all continuous potentials, and all weak Gibbs states. In particular, we…

Mathematical Physics · Physics 2026-02-13 Noé Cuneo , Vojkan Jakšić , Claude-Alain Pillet , Armen Shirikyan

From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…

Mathematical Physics · Physics 2014-11-21 Gian Paolo Beretta , Enzo Zanchini

The usual formulation of thermodynamics is based on the additivity of macroscopic systems. However, there are numerous examples of macroscopic systems that are not additive, due to the long-range character of the interaction among the…

Statistical Mechanics · Physics 2022-06-22 Ivan Latella , Agustín Pérez-Madrid , Alessandro Campa , Lapo Casetti , Stefano Ruffo

Crystallization is a process of great practical relevance in which rare but crucial fluctuations lead to the formation of a solid phase starting from the liquid. Like in all first order first transitions there is an interplay between…

Statistical Mechanics · Physics 2017-07-12 Pablo M. Piaggi , Omar Valsson , Michele Parrinello

Entropy is one of the most fundamental quantities in physics. For systems with few degrees of freedom, the value of entropy provides a powerful insight into its microscopic dynamics, such as the number, degeneracy and relative energies of…

Mesoscale and Nanoscale Physics · Physics 2024-06-19 Eugenia Pyurbeeva , Jan A. Mol , Pascal Gehring

We provide an extension of a recent approach to study non-equilibrium thermodynamics [Phys. Rev. E 81, 051130 (2010), to be denoted by I in this work] to inhomogeneous systems by considering the latter to be composed of quasi-independent…

Statistical Mechanics · Physics 2013-05-30 P. D. Gujrati

Understanding the evolution of entropy in the universe is a fundamental aspect of cosmology. This paper investigates the evolution of entropy in a spatially flat $K=0$ universe, focusing on the contributions of matter, radiation, and dark…

General Relativity and Quantum Cosmology · Physics 2025-07-16 Tanisha Joshi , S. D Pathak

We consider critical models in one dimension. We study the ground state in thermodynamic limit [infinite lattice]. Following Bennett, Bernstein, Popescu, and Schumacher, we use the entropy of a sub-system as a measure of entanglement. We…

Strongly Correlated Electrons · Physics 2009-11-10 Vladimir Korepin

The thermodynamic second law in the evaporating black hole space-time is examined in the context of two-dimensional dilaton black hole. The dynamical evolution of entropy is investigated by using the analytical perturbation method and the…

General Relativity and Quantum Cosmology · Physics 2009-10-28 Kouichirou Hirata , Yoshi Fujiwara , Jiro Soda

Classical thermodynamics is unrivalled in its range of applications and relevance to everyday life. It enables a description of complex systems, made up of microscopic particles, in terms of a small number of macroscopic quantities, such as…

Quantum Physics · Physics 2016-01-13 James Millen , André Xuereb

We have recently applied the second law to an isolated system, consisting of a system {\Sigma} such as a glass surrounded by an extremely large medium {\Sigma}, to show that the instantaneous temperature T(t), thermodynamic entropy S(T_0,t)…

Statistical Mechanics · Physics 2011-03-02 P. D. Gujrati

It has been observed in both natural and man-made materials that volume sometimes decreases with increasing temperature. Though mechanistic understanding has been gained for some individual materials, a general answer to the question "Why…

Materials Science · Physics 2023-03-28 Zi-Kui Liu , Yi Wang , Shun-Li Shang

Entropy has emerged as a dynamic, interdisciplinary, and widely accepted quantitative measure of uncertainty across different disciplines. A unified understanding of entropy measures, supported by a detailed review of their theoretical…

Probability · Mathematics 2025-03-21 Naveen Kumar , Ambesh Dixit , Vivek Vijay

We consider an isolated gaseous system, divided in two parts by an adiabatic movable frictionless internal wall undergoing Brownian motion. We show how this kind of motion can lead to a substantial decrease of the system entropy. This…

Classical Physics · Physics 2007-05-23 B. Crosignani , P. Di Porto

We analyze the production of entropy along non-equilibrium processes in quantum systems coupled to generic environments. First, we show that the entropy production due to final measurements and the loss of correlations obeys a fluctuation…

Quantum Physics · Physics 2018-08-08 Gonzalo Manzano , Jordan M. Horowitz , Juan M. R. Parrondo