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Recently, some of us developed a novel model glass-forming liquid with k extra interactions with pseudo neighbours to each liquid particle over and above the regular interactions with its neighbours. Analysis of the structure and dynamics…

In a glassy system different degrees of freedom have well-separated characteristic times, and are described by different temperatures. The stationary state is essentially non-equilibrium. A generalized statistical thermodynamics is…

Disordered Systems and Neural Networks · Physics 2007-05-23 A. E. Allahverdyan , Th. M. Nieuwenhuizen

Systems driven away from thermal equilibrium constantly deliver entropy to their environment. Determining this entropy production requires detailed information about the system's internal states and dynamics. However, in most practical…

Statistical Mechanics · Physics 2017-10-03 Gili Bisker , Matteo Polettini , Todd R. Gingrich , Jordan M. Horowitz

We show that systems with negative specific heat can violate the zeroth law of thermodynamics. By both numerical simulations and by using exact expressions for free energy and microcanonical entropy it is shown that if two systems with the…

Statistical Mechanics · Physics 2009-11-13 A. Ramirez-Hernandez , H. Larralde , F. Leyvraz

In the weak-coupling limit approach to open quantum systems, the presence of the bath is eliminated and accounted for by a master equation that introduces dissipative contributions to the system reduced dynamics. Within this framework,…

Quantum Physics · Physics 2017-10-03 S. Marcantoni , S. Alipour , F. Benatti , R. Floreanini , A. T. Rezakhani

In the scientific and engineering literature, the second law of thermodynamics is expressed in terms of the behavior of entropy in reversible and irreversible processes. According to the prevailing statistical mechanics interpretation the…

Quantum Physics · Physics 2007-05-23 Elias P. Gyftopoulos , Gian Paolo Beretta

This paper addresses fundamental aspects of statistical mechanics such as the motivation of a classical state space with spontaneous transitions, the meaning of non-equilibrium in the context of thermalization, and the justification of…

Statistical Mechanics · Physics 2011-05-31 Haye Hinrichsen , Christian Gogolin , Peter Janotta

We give meaning to the first and second laws of thermodynamics in case of mesoscopic out-of-equilibrium systems which are driven by diffusion processes. The notion of the entropy production is analyzed. The role of the Helmholtz extremum…

Statistical Mechanics · Physics 2008-11-26 Piotr Garbaczewski

An interesting question to explore in physics classes is whether gravity violates the second law of thermodynamics. Standard physics textbooks provide little to no discussion of the relationship between entropy and gravity, and the same is…

General Physics · Physics 2026-05-19 Jorge Pinochet , Giorgio Sonnino

The mixing of two different gases is one of the most common natural phenomena, with applications ranging from CO$_2$ capture to water purification. Traditionally, mixing is analyzed in the context of local thermal equilibrium, where systems…

Quantum Physics · Physics 2025-07-08 Budhaditya Bhattacharjee , Rohit Kishan Ray , Dominik Šafránek

In these decades, it has been revealed that there is rich information-theoretic structure in thermodynamics of out-of-equilibrium systems in both the classical and quantum regimes. This has led to the fruitful interplay among statistical…

Quantum Physics · Physics 2020-09-29 Takahiro Sagawa

The science of thermodynamics was put together in the Nineteenth Century to describe large systems in equilibrium. One part of thermodynamics defines entropy for equilibrium systems and demands an ever-increasing entropy for non-equilibrium…

Statistical Mechanics · Physics 2014-03-26 Leo P. Kadanoff

The thermodynamic equilibrium states of a static thin ring shell in a (2+1)-dimensional flat spacetime is analyzed. Inside the ring the spacetime is flat, whereas outside it is conical flat. The first law of thermodynamics applied to the…

General Relativity and Quantum Cosmology · Physics 2015-06-17 José P. S. Lemos , Gonçalo M. Quinta

Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…

Statistical Mechanics · Physics 2024-09-20 Ananth Govind Rajan

We review on a recently proposed quantum exception to the second law of thermodynamics. We emphasize that $^4$He superflows, like any other forms of flows, shall carry entropy or heat in a thermal environment. Following that, one can use a…

General Physics · Physics 2016-11-09 Yongle Yu

Thermodynamics can be formulated in either of two approaches, the phenomenological approach, which refers to the macroscopic properties of systems, and the statistical approach, which describes systems in terms of their microscopic…

Quantum Physics · Physics 2019-05-01 Mirjam Weilenmann , Lea Krämer Gabriel , Philippe Faist , Renato Renner

Thermodynamics allows the application of Statistical Mechanics to finite and even small systems. As surface effects cannot be scaled away, one has to be careful with the standard arguments of splitting a system into two or bringing two…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

Chemical Physics · Physics 2007-05-23 Elias P. Gyftopoulos

We argue that the entanglement entropy for a very small subsystem obeys a property which is analogous to the first law of thermodynamics when we excite the system. In relativistic setups, its effective temperature is proportional to the…

High Energy Physics - Theory · Physics 2013-03-14 Jyotirmoy Bhattacharya , Masahiro Nozaki , Tadashi Takayanagi , Tomonori Ugajin

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where…

Quantum Physics · Physics 2021-08-31 Philipp Strasberg , Andreas Winter