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We have performed x-ray absorption spectroscopy (XAS) and x-ray photoemission spectroscopy (XPS) studies of single crystal Ba_{1-x}K_{x}BiO_{3} (BKBO) covering the whole composition range $0 \leq x \leq 0.60$. Several features in the oxygen…

Superconductivity · Physics 2009-10-31 K. Kobayashi , T. Mizokawa , A. Ino , J. Matsuno , A. Fujimori , H. Samata , A. Mishiro , Y. Nagata , F. M. F. de Groot

The electronic and magnetic properties of a new diluted magnetic semiconductor (DMS) Ba$_{1-x}$K$_{x}$(Zn$_{1-y}$Mn$_{y}$)$_{2}$As$_{2}$, which is isostructural to so-called 122-type Fe-based superconductors, are investigated by x-ray…

After a review of temperature-dependent experimental x-ray absorption near-edge structure (XANES) and related theoretical developments, we present the Al K-edge XANES spectra of corundum and beryl for temperature ranging from 300K to 930K.…

Strongly Correlated Electrons · Physics 2015-06-04 Damien Manuel , Delphine Cabaret , Christian Brouder , Philippe Sainctavit , Amélie Bordage , Nicolas Trcera

We have investigated 3d electronic states of doped transition metals in II-VI diluted magnetic semiconductors, Zn1-xMxSe (M = Mn, Fe, Co) and Zn1-xMnxY (Y = Se, Te), using the transition-metal L2,3-edge X-ray absorption spectroscopy (XAS)…

Strongly Correlated Electrons · Physics 2009-10-31 Kwanghyun Cho , Hoon Koh , S. -J. Oh , Hyeong-Do Kim , Moonsup Han , J. -H. Park , C. T. Chen , Y. D. Kim , J. -S. Kim , B. T. Jonker

By including phonon-assisted transitions within plane-wave DFT methods for calculating the X-ray absorption spectrum (XAS) we obtain the Al K-edge XAS at 300 K for two Al$_2$O$_3$ phases. The 300 K XAS reproduces the pre-edge peak for…

Materials Science · Physics 2022-06-29 Angela F. Harper , Bartomeu Monserrat , Andrew J. Morris

The influence of atomic vibrations on x-ray absorption near edge structure (XANES) is calculated by assuming that vibrational energies are small with respect to the instrumental resolution. The resulting expression shows that, at the…

Materials Science · Physics 2010-07-26 Christian Brouder , Delphine Cabaret , Amélie Juhin , Philippe Sainctavit

We have performed an angle-resolved photoemission spectroscopy study of the new superconductor Ba$_{0.6}$K$_{0.4}$Fe$_2$As$_2$ in the low energy range. We report the observation of an anomaly around 25 meV in the dispersion of…

Superconductivity · Physics 2009-01-30 P. Richard , T. Sato , K. Nakayama , S. Souma , T. Takahashi , Y. -M. Xu , G. F. Chen , J. L. Luo , N. L. Wang , H. Ding

Two-dimensional iron-chalcogenide intercalates display a remarkable correlation of the interlayer spacing with the enhancement of the superconducting critical temperature ($T_c$). In this work, synchrotron x-ray absorption ($XAS$, at Fe and…

The upper critical field Hc2 anisotropy of Ca10(PtnAs8)(Fe2-xPtxAs2)5 (n = 3, 4) single crystals with long FeAs interlayer distance (d) was studied by angular dependent resistivity measurements. A scaling of the angular dependent…

Superconductivity · Physics 2015-07-13 F. F. Yuan , Y. Sun , W. Zhou , X. Zhou , Q. P. Ding , K. Iida , R. Huehne , L. Schultz , T. Tamegai , Z. X. Shi

Quantum transitions in Fe-based systems are believed to involve spin, charge and nematic fluctuations. Complex structural phase diagram in these materials often emphasizes importance of covalency in their exotic properties, which is…

The densities of the valence and conduction band electronic states of the newly discovered layered superconductors LaOFeAs, LaO$_{0.87}$F$_{0.13}$FeAs (Tc=26 K), SmO$_{0.95}$F$_{0.05}$FeAs and SmO$_{0.85}$F$_{0.15}$FeAs (Tc=43 K) are…

We report the novel preparation of single crystals of tetragonal iron sulfide, FeS, which exhibits a nearly ideal tetrahedral geometry with S--Fe--S bond angles of 110.2(2) $^\circ$ and 108.1(2) $^\circ$. Grown via hydrothermal…

Local structure of NdFeAsO$_{1-x}$F$_{x}$ ($x$=0.0, 0.05, 0.15 and 0.18) high temperature iron pnictide superconductor system is studied using arsenic $K$-edge extended x-ray absorption fine structure measurements as a function of…

Superconductivity · Physics 2011-06-15 Boby Joseph , Antonella Iadecola , Lorenzo Malavasi , Naurang L. Saini

The theoretical description of photoemission spectra of transition metals was greatly improved recently by accounting for the correlations between the d electrons within the local spin density approximation (LSDA) plus dynamical mean field…

Strongly Correlated Electrons · Physics 2013-03-22 O. Sipr , J. Minar , A. Scherz , H. Wende , H. Ebert

By using a hydrothermal method, we have successfully grown crystals of the newly discovered superconductor FeS, which has an isostructure of the iron based superconductor FeSe. The superconductivity appears at about 4.5K, as revealed by…

Superconductivity · Physics 2016-04-13 Hai Lin , Yufeng Li , Qiang Deng , Jie Xing , Jianzhong Liu , Xiyu Zhu , Huan Yang , Hai-Hu Wen

Operando X-ray absorption spectroscopy (XAS) can probe the electrode-electrolyte interface with single-digit nanometer depth resolution and offers a wealth of insight into the evolution and Coulombic efficiency or degradation of prototype…

We present a reciprocal-space pseudopotential scheme for calculating X-ray absorption near-edge structure (XANES) spectra. The scheme incorporates a recursive method to compute absorption cross section as a continued fraction. The continued…

Condensed Matter · Physics 2009-11-07 Mathieu Taillefumier , Delphine Cabaret , Anne-Marie Flank , Francesco Mauri

We study the bending of rectangular atomic monolayers along different directions from first principles. Specifically, choosing the phosphorene, GeS, TiS$_3$, and As$_2$S$_3$ monolayers as representative examples, we perform Kohn-Sham…

Materials Science · Physics 2022-12-21 Shashikant Kumar , Phanish Suryanarayana

In Fe-As based superconductors magnetism and superconductivity show strong sensitivity to the lattice, suggesting a possibility of unconventional electron-phonon coupling. We investigated c-axis polarized phonons in doped and undoped…

Polarized x-ray absorption near edge structure (XANES) spectra at both the Cu and the Ge K-edges of CuGeO3 are measured and calculated relying on the real-space multiple-scattering formalism within a one-electron approach. The polarization…

Condensed Matter · Physics 2009-11-07 Ondrej Sipr , Antonin Simunek , Sergey Bocharov , Gunther Drager