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We show that the $d^{0}$ ferromagnetism with high Curie temperature ($T_c$) can be achieved in the electron doped hydrogenated epitaxial graphene on some certain SiC substrates through first-principles calculations. The pristine systems are…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Pengcheng Chen , Yuanchang Li , Wenhui Duan

We perform density functional theory calculations for the determination of the structural and electronic properties of epitaxial graphene on 4H-SiC(000$\bar{1}$). Using commensurate supercells that minimize non-physical stresses we show…

Mesoscale and Nanoscale Physics · Physics 2011-03-07 I. Deretzis , A. La Magna

Graphene grown on metal surface, Cu(111), with a boron nitride(BN) buffer layer is studied for the first time. Our first-principles calculations reveal that charge is transferred from the copper substrate to graphene through the BN buffer…

Materials Science · Physics 2007-12-27 Y. H. Lu , P. M. He , Y. P. Feng

Since hydrogen fuel involves the highest energy density among all fuels, production of this gas through the solar water splitting approach has been suggested as a green remedy for greenhouse environmental issues due to extensive consumption…

Computational Physics · Physics 2018-03-22 Meysam Makaremi , Sean Grixti , Keith T. Butler , Geoffrey A. Ozin , Chandra Veer Singh

We study the effects of metallic doping on the electronic properties of graphene using density functional theory in the local density approximation in the presence of a local charging energy (LDA+U). The electronic properties are sensitive…

Materials Science · Physics 2009-11-13 B. Uchoa , C. -Y. Lin , A. H. Castro Neto

The single-band current-dipole Kubo formula for the dynamical conductivity of heavily doped graphene from Kup\v{c}i\'{c} [Phys. Rev. B 91, 205428 (2015)] is extended to a two-band model for conduction $\pi$ electrons in lightly doped…

Mesoscale and Nanoscale Physics · Physics 2016-08-25 I. Kupčić , G. Nikšić , Z. Rukelj , D. Pelc

We report on spectroscopy results from the mid- to far-infrared on wafer-scale graphene, grown either epitaxially on silicon carbide, or by chemical vapor deposition. The free carrier absorption (Drude peak) is simultaneously obtained with…

Mesoscale and Nanoscale Physics · Physics 2011-11-17 Hugen Yan , Fengnian Xia , Wenjuan Zhu , Marcus Freitag , Christos Dimitrakopoulos , Ageeth A. Bol , George Tulevski , Phaedon Avouris

We present electronic structure calculations of few-layer epitaxial graphene nanoribbons on SiC(0001). Trough an atomistic description of the graphene layers and the substrate within the extended H\"{u}ckel Theory and real/momentum space…

Mesoscale and Nanoscale Physics · Physics 2009-08-19 I. Deretzis , A. La Magna

The electronic and optical properties of the paradigmatic F4TCNQ-doped pentacene in the low-doping limit are investigated by a combination of state-of-the-art many-body \emph{ab initio} methods accounting for environmental screening…

Materials Science · Physics 2017-07-25 Jing Li , Gabriele D'Avino , Anton Pershin , Denis Jacquemin , Ivan Duchemin , David Beljonne , Xavier Blase

We have performed scanning gate microscopy (SGM) on graphene field effect transistors (GFET), using a biased metallic nanowire coated with a dielectric layer as a contact mode tip and local top gate. Electrical transport through graphene at…

Intercalation is a robust approach for modulating the properties of epitaxial graphene on SiC and stabilizing two-dimensional (2D) intercalant layers at the graphene/SiC interface. In this work, we present synchrotron-based angle resolved…

Mesoscale and Nanoscale Physics · Physics 2025-05-14 Bharti Matta , Philipp Rosenzweig , Kathrin Küster , Craig Polley , Ulrich Starke

We investigate the electronic, thermal, and optical characteristics of graphene like SiC$_x$ structure using model calculations based on density functional theory. The change in the energy bandgap can be tuned by the Si atomic…

Mesoscale and Nanoscale Physics · Physics 2020-06-12 Nzar Rauf Abdullah , Gullan Ahmed Mohammed , Hunar Omar Rashid , Vidar Gudmundsson

Since advanced Silicon-based device components are moderately chemically tunable, doped graphene has emerged as a promising candidate to replace this semiconducting material in flexible miniaturized electronic devices. Indeed, heteroatom…

Materials Science · Physics 2022-10-27 Laura Caputo , Viet-Hung Nguyen , Jean-Christophe Charlier

We calculate the theoretical contribution to the doping and temperature ($T$) dependence of electrical resistivity due to scattering by acoustic phonons in Bernal bilayer graphene (BBG) and rhombohedral trilayer graphene (RTG). We focus on…

Mesoscale and Nanoscale Physics · Physics 2023-01-31 Seth M. Davis , Yang-Zhi Chou , Fengcheng Wu , Sankar Das Sarma

We demonstrate, by femtosecond time- and angle-resolved photoemission spectroscopy, that photoinduced interlayer charge transfer in a heterostructure consisting of Bernal-stacked bilayer graphene and a single atomic layer of silver on…

Mesoscale and Nanoscale Physics · Physics 2026-02-23 Eduard Moos , Zhi-Yuan Deng , Hauke Beyer , Arpit Jain , Chengye Dong , Li-Syuan Lu , Joshua A. Robinson , Kai Rossnagel , Michael Bauer

Graphene monolayer is a material with zero band gap, because of which its applications in optoelectronics are limited. The question arises, can we modify the optoelectronic properties of graphene by doping it with other atoms? Synthesis of…

Materials Science · Physics 2026-03-18 Samayita Das , Alok Shukla

We report on the charge spill-out and work function of epitaxial few-layer graphene on 6H-SiC(0001). Experiments from high-resolution, energy-filtered X-ray photoelectron emission microscopy (XPEEM) are combined with ab initio Density…

We report that the $\pi$ band of graphene sensitively changes as a function of an external potential induced by Na especially when the potential becomes periodic at low temperature. We have measured the band structures from the graphene…

We explain the robust p-type doping observed for quasi-free standing graphene on hexagonal silicon carbide by the spontaneous polarization of the substrate. This mechanism is based on a bulk property of SiC, unavoidable for any hexagonal…

Materials Science · Physics 2015-05-30 J. Ristein , S. Mammadov , Th. Seyller

Functional manipulation of graphene is an important topic in view of both fundamental researches and practical applications. In this study, we show that intercalation of 5$d$ transition metals in epitaxial graphene on SiC is a promising…

Mesoscale and Nanoscale Physics · Physics 2019-03-06 Minsung Kim , Cai-Zhuang Wang , Michael C. Tringides , Myron Hupalo , Kai-Ming Ho
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