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The derivation of linear response theory within polarizable embedding is carried out from a rigorous quantum-mechanical treatment of a composite system. Two different subsystem decompositions (symmetric and nonsymmetric) of the linear…

Chemical Physics · Physics 2017-10-09 Nanna Holmgaard List , Patrick Norman , Jacob Kongsted , Hans Jørgen Aagaard Jensen

The theory is presented for resonance interaction between two atoms in an excited configuration: one atom, the "receptor" of information (i.e. energy), adsorbed on a phospholipid surface and the other atom, the "emitter" of information…

Quantum Physics · Physics 2013-05-20 Mathias Boström , Clas Persson , Dan Huang , Barry W. Ninham , Bo E. Sernelius

An analytical theory is presented for the damping of low-frequency adsorbate vibrations via resonant coupling to the substrate phonons. The system is treated classically, with the substrate modeled as a semi-infinite elastic continuum and…

Materials Science · Physics 2009-10-30 Steven P. Lewis , M. V. Pykhtin , E. J. Mele , Andrew M. Rappe

The problem of a beam of quantum particles falling through a diffractive screen is studied. The solutions for single and double slits are obtained explicitly when the potential is approximated by a linear function. It is found that the…

Quantum Physics · Physics 2018-10-24 D. Condado , J. L. Díaz-Cruz , A. Rosado , E. Sadurní

The behavior of a strongly charged polymer adsorbed on an oppositely charged surface of low-dielectric constant is formulated by the functional integral method. By separating the translational, conformational, and fluctuational degrees of…

Soft Condensed Matter · Physics 2007-05-23 Chi-Ho Cheng , Pik-Yin Lai

We use a simple generic model to study the desorption of atoms from a solid surface in contact with a liquid, by using a combination of Monte Carlo and molecular dynamics simulations. The behavior of the system depends on two parameters:…

Chemical Physics · Physics 2022-11-16 Krishna Jaiswal , Horia Metiu , Vishal Agarwal

We study the adsorption of homogeneous or heterogeneous polymers onto heterogeneous planar surfaces with exponentially decaying site-site correlations, using a variational reference system approach. As a main result, we derive simple…

Soft Condensed Matter · Physics 2009-11-11 Alexey Polotsky , Friederike Schmid , Andreas Degenhard

Phonon lineshapes in atom-surface scattering are obtained from a simple stochastic model based on the so-called Caldeira-Leggett Hamiltonian. In this single-bath model, the excited phonon resulting from a creation or annihilation event is…

Statistical Mechanics · Physics 2015-03-13 R. Martinez-Casado , A. S. Sanz , S. Miret-Artes

A solid-liquid-gas moving contact line is considered through a diffuse-interface model with the classical boundary condition of no-slip at the solid surface. Examination of the asymptotic behaviour as the contact line is approached shows…

Fluid Dynamics · Physics 2013-10-07 David N. Sibley , Andreas Nold , Nikos Savva , Serafim Kalliadasis

Using a reference system approach, we develop an analytical theory for the adsorption of random heteropolymers with exponentially decaying and/or oscillating sequence correlations on planar homogeneous surfaces. We obtain a simple equation…

Soft Condensed Matter · Physics 2009-11-11 Alexey Polotsky , Friederike Schmid , Andreas Degenhard

Realistic fluid-solid interaction potentials are essential in description of confined fluids especially in the case of geometric heterogeneous surfaces. Correlated random field is considered as a model of random surface with high geometric…

Statistical Mechanics · Physics 2017-05-24 Aleksey Khlyupin , Timur Aslyamov

The success of density functional theory for the description of the adsorption of atoms on surfaces is well established, and based on recent calculations using gradient corrections, it has been shown that it also describes well the…

mtrl-th · Physics 2008-02-03 Catherine Stampfl

A simple manner to describe the diffusive relaxation of a colloidal fluid adsorbed in a porous medium is to model the porous medium as a set of spherical particles fixed in space at random positions with prescribed statistical structural…

In this paper an analytical model is introduced to describe the impulse response of the diffusive channel between a pointwise transmitter and a given fully-absorbing (FA) receiver in a molecular communication (MC) system. The presence of…

Information Theory · Computer Science 2021-11-25 Marco Ferrari , Fardad Vakilipoor , Eric Regonesi , Mariangela Rapisarda , Maurizio Magarini

We investigate the static and dynamic behaviors of a Br adlayer electrochemically deposited onto single-crystal Ag(100) using an off-lattice model of the adlayer. Unlike previous studies using a lattice-gas model, the off-lattice model…

Materials Science · Physics 2015-06-24 S. J. Mitchell , Sanwu Wang , P. A. Rikvold

We have combined the original diffusion-limited aggregation model introduced by Witten and Sander with the surface thermodynamics of the growing solid aggregate. The theory is based on the consideration of the surface chemical potential as…

Pattern Formation and Solitons · Physics 2009-10-31 Vladislav A. Bogoyavlenskiy , Natasha A. Chernova

Several problems, issued from physics, biology or the medical science, lead to parabolic equations set in two sub-domains separated by a membrane with selective permeability to specific molecules. The corresponding boundary conditions,…

Analysis of PDEs · Mathematics 2022-06-27 Giorgia Ciavolella , Benoît Perthame

In this article we analyze the Casimir-Polder interaction of atoms with a solid grating and an additional repulsive interaction between the atoms and the grating in the presence of an external laser source. The combined potential landscape…

We consider the effective surface motion of a particle that freely diffuses in the bulk and intermittently binds to that surface. From an exact approach we derive various regimes of the effective surface motion characterized by physical…

Statistical Mechanics · Physics 2015-05-13 Aleksei V. Chechkin , Irwin M. Zaid , Michael A. Lomholt , Igor M. Sokolov , Ralf Metzler

How many times a diffusing molecule can permeate across a membrane or be adsorbed on a substrate? We employ the encounter-based approach to find the statistics of adsorption or permeation events for molecular diffusion in a general…

Chemical Physics · Physics 2025-07-15 Denis S. Grebenkov
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