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When solid surfaces are immersed in aqueous solutions, some of their charges can dissociate and leave behind charge patches on the surface. Although the charges are distributed heterogeneously on the surface, most of the theoretical models…

Soft Condensed Matter · Physics 2013-11-19 Dan Ben-Yaakov , David Andelman , Haim Diamant

The reversible reactions like A+B <-> C in the many-component diffusive system affect the diffusive properties of the constituents. The effective conjugation of irreversible processes of different dimensionality takes place due to the…

Other Condensed Matter · Physics 2007-05-23 Serge Shpyrko , Vladimir M. Sysoev

Chemical reactions involving diffusion of reactants and subsequent chemical fixation steps are generally termed "diffusion-influenced" (DI). Virtually all biochemical processes in living media can be counted among them, together with those…

Chemical Physics · Physics 2016-06-29 Marta Galanti , Duccio Fanelli , Francesco Piazza

We study the diffusion phenomena on the negatively curved surface made up of congruent heptagons. Unlike the usual two-dimensional plane, this structure makes the boundary increase exponentially with the distance from the center, and hence…

Statistical Mechanics · Physics 2008-07-15 Seung Ki Baek , Su Do Yi , Beom Jun Kim

In this work we investigate 1+2 reactions within the framework of the hyperspherical adiabatic expansion method. To this aim two integral relations, derived from the Kohn variational principle, are used. A detailed derivation of these…

Atomic and Molecular Clusters · Physics 2012-04-03 C. Romero-Redondo , E. Garrido , P. Barletta , A. Kievsky , M. Viviani

When two or more atoms bind to a solid surface, the substrate can mediate an interaction between them. In this paper, we use density-functional theory to quantify the substrate-mediated pair interaction between two adatoms on a…

Materials Science · Physics 2007-05-23 Kristen A. Fichthorn , Matthias Scheffler

This work presents algebraic closure models associated with advective transport and nonlinear reactions in a Reynolds-averaged Navier-Stokes context for a system of species subject to binary reactions and transport by advection and…

Fluid Dynamics · Physics 2021-11-29 Omkar B. Shende , Ali Mani

Adsorption of dimers is modelled using random sequential adsorption algorithm. The interaction between molecules is given by screened electrostatic potential. The paper focuses on the properties of adsorbed monolayers as well as the…

Materials Science · Physics 2013-05-14 Michal Ciesla , Jakub Barbasz

In this paper we develop a hybrid version of the encounter-based approach to diffusion-mediated absorption at a reactive surface, which takes into account stochastic switching of a diffusing particle's conformational state. For simplicity,…

Statistical Mechanics · Physics 2022-09-21 Paul C. Bressloff

We explore the pressure of active particles on curved surfaces and its relation to other interfacial properties. We use both direct simulations of the active systems as well as simulations of an equilibrium system with effective (pair)…

Soft Condensed Matter · Physics 2019-05-14 René Wittmann , Frank Smallenburg , Joseph M. Brader

In recent letter [Phys. Rev. Lett {\bf 105}, 150606 (2010)], the surface-mediated diffusion problem is theoretically discussed, and interesting results have been obtained. However, for more general cases, the ansatz of solutions of the…

Mathematical Physics · Physics 2015-03-06 Yunxin Zhang

We consider a diffusion process on an evolving surface with a piecewise Lipschitz-continuous boundary from an energetic point of view. We employ an energetic variational approach with both surface divergence and transport theorems to derive…

Mathematical Physics · Physics 2018-10-19 Hajime Koba

One way to reduce the lattice thermal conductivity of solids is to induce additional phonon surface scattering through nanostructures. However, how phonons interact with boundaries, especially at the atomic level, is not well understood. In…

Mesoscale and Nanoscale Physics · Physics 2017-11-15 Cheng Shao , Qingyuan Rong , Ming Hu , Hua Bao

Diffusion-mediated surface phenomena are crucial for human life and industry, with examples ranging from oxygen capture by lung alveolar surface to heterogeneous catalysis, gene regulation, membrane permeation and filtration processes.…

Statistical Mechanics · Physics 2020-08-19 Denis S. Grebenkov

The ad-atom dynamic equation, a Langevin type equation is analyzed and solved using some non-linear analytical and numerical tools. We noticeably show that the effect of the surface acoustic wave is to induce an effective potential that…

Other Condensed Matter · Physics 2012-03-14 Nicolas Combe , C. Taillan , J. Morillo

In many biological and small scale technological applications particles may transiently bind to a cylindrical surface. In between two binding events the particles diffuse in the bulk, thus producing an effective translation on the cylinder…

Statistical Mechanics · Physics 2015-05-27 Aleksei V. Chechkin , Irwin M. Zaid , Michael A. Lomholt , Igor M. Sokolov , Ralf Metzler

This work investigates the two-dimensional thermal behavior of a bilayer medium subject to both internal and external heat sources. The model incorporates diffusion, advection, and temperature-dependent volumetric heat generation or…

Fluid Dynamics · Physics 2025-11-12 Guillermo Federico Umbricht , Diana Rubio , Domingo Alberto Tarzia

A horizontal $N$-dimensional plane, having a diffusion of its own, exchanges with the lower half space. There, a reaction-diffusion process, modelled by a free boundary problem, takes place. We wish to understand whether, and how, the free…

Analysis of PDEs · Mathematics 2022-12-21 Luis A. Caffarelli , Jean-Michel Roquejoffre , Ignacio Tomasetti

A macroscopic hydrodynamic system that couples a particle and a wave has recently renewed interest in the question as to what extent a classical system may reproduce quantum phenomena. Here we investigate single-particle diffraction with a…

Fluid Dynamics · Physics 2024-10-31 Giuseppe Pucci , Antoine Bellaigue , Alessia Cirimele , Giuseppe Ali , Anand U. Oza

The interactions between diffusing molecules and membrane-bound receptors drive numerous cellular processes. In this work, we develop a spatial model of molecular interactions with membrane receptors by homogenizing the cell membrane and…

Quantitative Methods · Quantitative Biology 2025-01-24 Anil Cengiz , Sean D Lawley