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In this work, we were able to significantly increase the activity of boron nitride catalysts used for the oxidative dehydrogenation (ODH) of propane by designing and synthesising boron nitride (BN) supported on dendritic fibrous nanosilica…

Carbon nanotubes have properties depending on the arrangement of carbon atoms on the tube walls, called chirality. Also it has been tried to grow nanotubes of only one chirality for more than a decade it is still not possible today. A…

Materials Science · Physics 2013-05-02 Heiko Dumlich , John Robertson , Stephanie Reich

Using first principles calculations, we model the chemical vapor deposition (CVD) growth of carbon nanotubes (CNT) on nanoparticles of late transition (Ni, Pd, Pt) and coinage (Cu, Ag, Au) metals. The process is analyzed in terms of the…

Materials Science · Physics 2008-04-17 Oleg V. Yazyev , Alfredo Pasquarello

Despite recent successes in the synthesis of boron nanotubes (BNTs), the atomic arrangement of their walls has not yet been determined and many questions about their basic properties do remain. Here, we unveil the dynamical stability of…

Mesoscale and Nanoscale Physics · Physics 2014-04-18 Jens Kunstmann , Viktor Bezugly , Hauke Rabbel , Mark H. Rümmeli , Gianaurelio Cuniberti

Controlling the chirality and yield of carbon nanotubes is essential for their diverse applications from macroscopic composites to nanoelectronics. Floating-catalyst chemical vapor deposition is widely employed as a scalable synthesis…

Materials Science · Physics 2026-01-08 K. Otsuka , R. Fujiwara , S. Maruyama

Boron nitride (BN) has been explored these days because of its extraordinary optical, chemical and mechanical properties. BN is sensitive to its crystal structure that slight change in lattice parameters enormously change its properties.…

Materials Science · Physics 2019-10-01 Bikramjeet Singh , Kulwinder Singh , Manjeet Kumar , Akshay Kumar

We report the stability and electronic structures of the boron nitride nanotubes (BNNTs) with diameters below 4 A by semi-empirical quantum mechanical molecular dynamics simulations and ab initio calculations. Among them (3,0), (3,1),…

Materials Science · Physics 2009-12-07 Zhuhua Zhang , Wanlin Guo , Yitao Dai

The electronic and piezoelectric properties of the boron nitride (BN) nanotubes are investigated with the hybrid density functional (B3LYP) method. We first study bulk h-BN and BN sheet and find that the B3LYP band structure and energy gap…

Materials Science · Physics 2007-05-23 H. J. Xiang , Z. Y. Chen , Jinlong Yang

The stability of a single-walled carbon nanotube placed on top of a catalytic nickel nanoparticle is investigated by means of molecular dynamics simulations. As a case study, we consider the $(12,0)$ nanotube consisting of 720 carbon atoms…

Chemical Physics · Physics 2016-10-07 Alexey V. Verkhovtsev , Stefan Schramm , Andrey V. Solov'yov

The cutting of single-walled carbon nanotubes by an 80 keV electron beam catalyzed by nickel clusters is imaged in situ using aberration-corrected high-resolution transmission electron microscopy. Extensive molecular dynamics simulations…

The growth of monolayer hexagonal boron nitride (h-BN) on Ir(110) through low-pressure chemical vapor deposition is investigated using low energy electron diffraction and scanning tunneling microscopy. We find that the growth of aligned…

Materials Science · Physics 2024-02-16 Thomas Michely , Jason Bergelt , Affan Safeer , Alexander Bäder , Tobias Hartl , Jeison Fischer

Carbon nanotubes (CNT) have been recently proposed as stabilizers against grain growth that can happen even at low temperature inputs in nano-crystalline and ultrafine-grained materials obtained by severe plastic deformation. In this study,…

The synthesis of Ni filled multiwalled carbon nanotubes was performed by atmospheric pressure chemical vapor deposition with propane on Si at 850 C using a simple mixture of Ni(salen), and a conventional photoresist. Analysis of the carbon…

Applied Physics · Physics 2019-08-14 Joydip Sengupta , Avijit Jana , N D Pradeep Singh , C Mitra , Chacko Jacob

The effects of edge hydrogenation and hydroxylation on the relative stability and electronic properties of hexagonal boron nitride quantum dots (h-BNQDs) are investigated. Zigzag edge hydroxylation is found to result in considerable…

Materials Science · Physics 2014-09-23 Dana Krepel , Lena Kalikhman-Razvozov , Oded Hod

Boron-doped single crystal diamond films were grown homoepitaxially on synthetic (100) Type Ib diamond substrates using microwave plasma assisted chemical vapor deposition. A modification in surface morphology of the film with increasing…

Materials Science · Physics 2013-11-06 S. K. Karna , Y. K. Vohra , P. Kung , S. T. Weir

Boron nitride (BN) is a material with outstanding technological promise because of its exceptional thermochemical stability, structural, electronic and thermal conductivity properties, and extreme hardness. Yet, the relative thermodynamic…

Materials Science · Physics 2018-12-13 Claudio Cazorla , Tim Gould

Dielectrophoresis can potentially be used as an efficient trapping tool in the fabrication of molecular devices. For nanoscale objects, however, the Brownian motion poses a challenge. We show that the use of carbon nanotube electrodes makes…

In this study, the synthesis of multi-walled carbon nanotubes (MWCNTs) was carried out by chemical vapor deposition (CVD) using propane as the carbon source and Si as the catalyst support. The effect of CVD process variables such as…

Applied Physics · Physics 2018-08-21 Joydip Sengupta

Nanotubular materials inspired by crystalline diborides such as AlB_2 are proposed. The atomic structure, in particular the basic chemical question of where to put Al atoms in order to stabilize nanotubular Al-B systems, is investigated…

Materials Science · Physics 2007-05-23 Alexander Quandt , Amy Y. Liu , Ihsan Boustani

Having access to the chemical environment at the atomic level of a dopant in a nanostructure is crucial for the understanding of its properties. We have performed atomically-resolved electron energy-loss spectroscopy to detect individual…