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We report the experimental discovery of superconductivity with critical temperature Tc above 70 K in zirconium polyhydrides, the record high so far for 3d transition metal hydrides. The superconducting zirconium polyhydrides are synthesized…

Superconductivity · Physics 2022-04-01 C. L. Zhang , X. He , Z. W. Li , S. J. Zhang , S. M. Feng , X. C. Wang , R. C. Yu , C. Q. Jin

Metal-stuffed B$-$C compounds with sodalite clathrate structure have captured increasing attention due to their predicted exceptional superconductivity above liquid nitrogen temperature at ambient pressure. However, by neglecting the…

Superconductivity · Physics 2026-01-13 Wenbo Zhao , Ying Sun , Jiaxiang Li , Peng Yuan , Toshiaki Iitaka , Xin Zhong , Hefei Li , Yue-Wen Fang , Hanyu Liu , Ion Errea , Yu Xie

The crystal structure of Nb22O54 is reported for the first time, and the structure of orthorhombic Nb12O29 is reexamined, resolving previous ambiguities. Single crystal x-ray and electron diffraction were employed. These compounds were…

Materials Science · Physics 2009-02-02 T. McQueen , Q. Xu , E. N. Andersen , H. W. Zandbergen , R. J. Cava

A new superconductor (Na0.25K0.45)Ba3Bi4O12, having an A-site-ordered double perovskite structure, with a maximum Tc ~ 27 K has very recently been discovered through hydrothermal synthesis at 593 K. The structural, elastic, electronic, and…

The basic known and hypothetic one- and two-element phases of the B-C-N-O system (both superhard phases having diamond and boron structures and precursors to synthesize them) are described. The attention has been given to the structure,…

Materials Science · Physics 2011-01-18 O. O. Kurakevych

The discovery of clathrate superhydrides has approached the long-standing dream of room-temperature superconductivity and thus inspired their prosperous research under high pressure. However, how to experimentally optimize these compelling…

Superconductivity · Physics 2025-09-30 Jingkai Bi , Yuki Nakamoto , Katsuya Shimizu , Mi Zhou , Hongbo Wang , Guangtao Liu , Yanming Ma

Transition metal oxides are considered promising thermoelectric materials for harvesting high-temperature waste heat due to their stability, abundance and low toxicity. Despite their typically strong ionic character, they can exhibit…

Materials Science · Physics 2019-12-04 Simon Thébaud , Christophe Adessi , Georges Bouzerar

The high pressure structural properties of bismuth oxide Bi2SiO5 have been investigated up to 28 GPa using in situ powder synchrotron X-ray diffraction and up to 50 GPa with DFT calculations. The monoclinic structure is found to persist up…

Layered d-metal pnictide oxides are a unique class of compounds which consists of characteristic d-metal pnictide layers and metal oxide layers. More than 100 of these layered compounds, including the recently discovered Fe-based…

Superconductivity · Physics 2010-10-26 Tadashi C. Ozawa , Susan M. Kauzlarich

We present high-pressure resistance measurements up to 40 GPa on recently discovered titanium-based kagome metal CsTi$_3$Bi$_5$. At ambient pressure, CsTi$_3$Bi$_5$ shows no evidence of superconductivity in resistivity and specific heat. By…

Superconductivity · Physics 2023-08-22 J. Y. Nie , X. F. Yang , X. Zhang , X. Q. Liu , W. Xia , D. Z. Dai , C. C. Zhao , C. P. Tu , X. M. Kong , X. B. Jin , Y. F. Guo , S. Y. Li

Ternary hydrides are considered as the ideal candidates with high critical temperature (Tc) stabilized at submegabar pressure, evidenced by the recent discoveries in LaBeH8 (110 K at 80 GPa) and LaB2H8 (106 K at 90 GPa). Here, we…

Superconductivity · Physics 2024-12-02 Tingting Gu , Wenwen Cui , Jian Hao , Jingming Shi , Artur P. Durajski , Hanyu Liu , Yinwei Li

To investigate the interaction between carbon and Mobius-type carbon nanobelts and nickel, cadmium, and lead nanoclusters, we utilized the semiempirical tight binding framework provided by xTB software. Through our calculations, we…

Materials Science · Physics 2025-09-01 C. Aguiar , N. Dattani , I. Camps

A structurally stable crystalline carbon allotrope is predicted by means of the first-principles calculations. This allotrope can be derived by substituting each atom in diamond with a carbon tetrahedron, and possesses the same space group…

Materials Science · Physics 2015-05-28 Xian-Lei Sheng , Qing-Bo Yan , Fei Ye , Qing-Rong Zheng , Gang Su

The discovery of the first high critical temperature (Tc) transition metal diboride superconductor, MgB2 structure alpha-MoB2 under pressure with Tc up to 32 K at 100 GPa, provides new input into some unexplained aspects of electron-phonon…

Superconductivity · Physics 2021-12-22 Yundi Quan , Kwan-woo Lee , Warren E. Pickett

In the present paper we performed the analysis of available data on structural, thermodynamic and mechanical properties of B6O. Although the compound is known for half a century and has been extensively studied, many properties of this…

Materials Science · Physics 2012-03-27 Oleksandr O. Kurakevych , Vladimir L. Solozhenko

We calculate the structural and electronic properties of OsB2 using density functional theory with or without taking into account spin-orbit (SO) interaction. Our results show that the bulk modulus with and without SO interaction are 364…

Materials Science · Physics 2007-05-23 Z. Y. Chen , H. J. Xiang , Jinlong Yang , J. G. Hou , Qingshi Zhu

Our goals are to assist a non-practitioner understand likely resolution of the controversy about the boson that couples Cooper pairs in Cu oxides and to consider if high temperature superconductivity (HTS) in solid oxides might be related…

Superconductivity · Physics 2007-05-23 W. J. Nellis

Decoherence in superconducting qubits has long been attributed to two level systems arising from the surfaces and interfaces present in real devices. A recent significant step in reducing decoherence was the replacement of superconducting…

It is challenging to search for high Tc superconductivity (SC) in transition metal elements wherein d electrons are usually not favored by conventional BCS theory. Here we report discovery of surprising SC up to 310 GPa with Tc above 20 K…