Related papers: Capillary rise of water in hydrophilic nanopores
This paper investigates the structural identifiability and a comparative calibration of four water retention curves (WRCs) within the framework of the Richards equation coupled with Darcy's law for capillary imbibition in porous media. The…
Molecular Dynamics simulations of water confined in nanometer sized, hydrophobic channels show that water forms localized cavities for pore diameter ~ 2.0 nm. The cavities present non-spherical shape and lay preferentially adjacent to the…
Polymers are known to wet nanopores with high surface energy through an atomically thin precursor film followed by slower capillary filling. We present here light interference spectroscopy using a nanoporous membrane-based chip that allows…
The dynamics of capillary rise under different geometric and fluid conditions have the common signatures of rapid rise followed by an equilibrium state that describe the underlying competing forces. We present a new interpretation of…
A Molecular Dynamics simulation of the microscopic structure of water confined in a silica pore is presented. A single cavity in the silica glass has been modeled as to reproduce the main features of the pores of real Vycor glass. A layer…
We study the dynamics of a fluid rising in a capillary tube with corners. In the cornered tube, unlike the circular tube, fluid rises with two parts, the bulk part where the entire cross-section is occupied by the fluid, and the finger part…
Recently anomalous scaling properties of front broadening during spontaneous imbibition of water in Vycor glass, a nano-porous medium, were reported: the mean height and the width of the propagating front increase with time $t$ both…
The anomalous dynamics of capillary rise in a porous medium discovered experimentally more than a decade ago (Delker et al., Phys. Rev. Lett. 76 (1996) 2902) is described. The developed theory is based on considering the principal modes of…
The rate of water flow through hydrophobic nanocapillaries is greatly enhanced as compared to that expected from macroscopic hydrodynamics. This phenomenon is usually described in terms of a relatively large slip length, which is in turn…
Silica (SiO$_2$) nanotubes (NTs) are used in a wide range of applications that go from sensors to nanofluidics. Currently, these NTs can be grown with diameters as small as 3 nm, with walls 1.5 nm thick. Recent experimental advances…
Capillary-driven flow of fluids occurs frequently in nature and has a wide range of technological applications in the fields of industry, agriculture, medicine, biotechnology, and microfluidics. By using the Onsager variational principle,…
At room temperature and under ambient conditions, due to the adsorption, a water film is always present on silica surfaces. If the surface is investigated with a scanning probe method in Contact mode, this causes the formation of a meniscus…
We have developed a poly(dimethylsiloxane) (PDMS) microfluidic chip to study the directional drying of a colloidal dispersion confined in a channel. Our measurements on a dispersion of silica nanoparticles once again revealed the…
Molecular Dynamics simulations of water molecules in nanometre sized cylindrical channels connecting two reservoirs show that the permeation of water is very sensitive to the channel radius and to electric polarization of the embedding…
We present direct experimental evidence that water droplets can spontaneously penetrate non-wetting capillaries, driven by the action of Laplace pressure due to high droplet curvature. Using high-speed optical imaging, microcapillaries of…
Carbonates are highly heterogeneous formations with large variations in pore size distribution and pore space topology, which results in complex multiphase flow behavior. Here we investigate the spontaneous imbibition behavior of fluids in…
The low frequency vibrational spectra of hydrated porous silica are specifically sensitive to the hydrogen bond interactions and provides a wealth of information on the structural and dynamical properties of the water contained in the pores…
In this two-part study we investigate the phase behaviour of a fluid spatially confined in a semi-infinite rectangular pore formed by three orthogonal walls and connected to a reservoir maintaining constant values of pressure and…
The geometry of walls forming a narrow pore may qualitatively affect the phase behaviour of the confined fluid. Specifically, the nature of condensation in nanopores formed of sinusoidally-shaped walls (with amplitude $A$ and period $P$) is…
Thermodynamics of imbibition (intrusion and extrusion) in capillaries of double conical structures is theoretically studied using the classical capillary model. By extending the knowledge of the thermodynamics of a single conical capillary,…