Related papers: Capillary rise of water in hydrophilic nanopores
We consider theoretically liquid rise against gravity in capillaries with height-dependent cross-section. For a conical capillary made from a hydrophobic surface and dipped in a liquid reservoir, the equilibrium liquid height depends on the…
Optical birefringence and light absorption measurements reveal four regimes for the thermotropic behavior of a nematogen liquid (7CB) upon sequential filling of parallel-aligned capillaries of 12 nm diameter in a monolithic, mesoporous…
This work revisits capillary filling dynamics in the regime of nanometric to subnanometric channels. Using molecular dynamics simulations of water in carbon nanotubes, we show that for tube radii below one nanometer, both the filling…
We present a theoretical study of spontaneous imbibition of liquid 4He in silica aerogels focusing on the effect of porosity on the fluid dynamical behavior. We adopt a coarse-grained three-dimensional lattice-gas description like in…
We investigated the vibrational dynamics and the structural relaxation of water nanoconfined in porous silica samples with pore size of 4 nm at different levels of hydration and temperature. We used as spectroscopic technique the…
Liquid in grooved capillaries, made by e.g. inserting a plate in a cylindrical tube, exhibits unusual spreading and flow properties. One example is capillary rise, where a long, upward tongue on top of the usual meniscus has been observed…
Water plays a key role in biological membrane transport. In ion channels and water-conducting pores (aquaporins), one dimensional confinement in conjunction with strong surface effects changes the physical behavior of water. In molecular…
Capillary rise occurs when a thin tube contacts a liquid, which rises against gravity due to the capillary force. This phenomenon is present in a wide range of everyday and industrial settings and provides the means to measure the physical…
We describe the imbibition process from a point source into a homogeneous semi-infinite porous material. When body forces are negligible, the advance of the wetting front is driven by capillary pressure and resisted by viscous forces. With…
Condensation, melting and freezing of nitrogen in a powder of mesoporous silica grains (SBA-15) has been studied by combined volumetric sorption isotherm and scanning calorimetry measurements. Within the mean field model of Saam and Cole…
Capillary rise plays a crucial role in the construction of road embankments in flood zones, where hydrophobic compounds are added to the soil to suppress the rising of water and avoid possible damage of the pavement. Water rises through…
Thermodynamics and hydrodynamics of spontaneous and forced imbibition of liquid into conical capillaries are studied to assess the feasibility of a conical liquid diode. The analytical formulas for the Laplace pressure and the critical…
Capillary invasion of a liquid into an empty tube, which is called capillary rise when the tube axis is in the vertical direction, is one of the fundamental phenomena representing capillary effects. Usually, the tube is actually filled with…
Capillary imbibition underpins many processes of fundamental and applied relevance in fluid mechanics. A limitation to the flow is the coupling to the confining solid, which induces friction forces. Our work proposes a general theoretical…
We revisit the classical problem of liquid imbibition in a single pore with spatially varying wettability. Starting from the Lucas-Washburn equation, we derive analytical solutions for the imbibition time (crossing time) in systems where…
The process of colloidal drying gives way to particle self-assembly in numerous elds including photonics or biotechnology. Yet, the mechanisms and conditions driving the nal particle arrangement in dry colloidal layers remain elusive. Here,…
The structure of water confined in MCM41 silica cylindrical pores is studied to determine if confined water really is simply a version of the bulk liquid which can be substantially supercooled without crystallisation. A combination of total…
The mobility of water molecules confined in a silica pore is studied by computer simulation in the low hydration regime, where most of the molecules reside close to the hydrophilic substrate. A layer analysis of the single particle dynamics…
We investigate by scattering techniques the structure of water-based soft composite materials comprising a crystal made of Pluronic block-copolymer micelles arranged in a face-centered cubic lattice and a small amount (at most 2% by volume)…
Using grand canonical Monte Carlo simulations, we have explored the phenomenon of capillary condensation (CC) of Ar at the triple temperature inside infinitely long, cylindrical pores. Pores of radius R= 1 nm, 1.7 nm and 2.5 nm have been…