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We consider the formation of cold ground-state polar molecules in a low vibrational level by laser fields. Starting from a pair of cold colliding atoms of dissimilar species, we propose a strategy consisting of three steps. In the first…

Atomic Physics · Physics 2026-01-14 Emanuel F. de Lima

Recently it has been shown that pairs of atoms can form metastable bonds due to non-conservative forces induced by dissipation [Lemeshko&Weimer, Nature Comm. 4, 2230 (2013)]. Here we study the dynamics of interaction-induced coherent…

Atomic Physics · Physics 2013-10-09 Mikhail Lemeshko

The creation of ultracold molecules is currently limited to diatomic species. In this letter we present a theoretical description of the photoassociation of ultracold atoms and molecules to create ultracold excited triatomic molecules, thus…

Atomic Physics · Physics 2015-09-02 Jesús Pérez-Ríos , Maxence Lepers , Olivier Dulieu

Optical Feshbach resonances [Phys. Rev. Lett. 94, 193001 (2005)] and pump-dump photoassociation with short laser pulses [Phys. Rev. A 73, 033408 (2006)] have been proposed as means to coherently form stable ultracold alkali dimer molecules.…

Atomic Physics · Physics 2009-01-05 Christiane P. Koch

Photoassociation of ultracold atoms is shown to lead to alignment of the product molecules along the excitation laser polarization axis. We theoretically investigate pulsed photoassociation of $^{87}Rb$ atoms into a specific weakly-bound…

Quantum Physics · Physics 2017-11-15 S. Kallush , J. L. Carini , P. L. Gould , R. Kosloff

The general formalism of the multipolar expansion of electrostatic interactions is applied to the calculation the potential energy between an excited atom (without fine structure) and a ground state diatomic molecule at large separations.…

Quantum Physics · Physics 2017-04-11 M. Lepers , O. Dulieu , V. Kokoouline

While many-particle entanglement can be found in natural solids and strongly interacting atomic and molecular gases, generating highly entangled states between weakly interacting particles in a controlled and scalable way presents a…

Atomic Physics · Physics 2013-02-27 Felipe Herrera , Sabre Kais , K. Birgitta Whaley

We theoretically explore photoassociation by Adiabatic Passage of two colliding cold ^{85}Rb atoms in an atomic trap to form an ultracold Rb_2 molecule. We consider the incoherent thermal nature of the scattering process in a trap and show…

Quantum Physics · Physics 2009-11-13 Evgeny A. Shapiro , Moshe Shapiro , Avi Pe'er , Jun Ye

We propose a new approach to excite ion-pair states of ultracold dimers. The central idea is a two-step process where first long-range Rydberg molecules are formed by photoassociation, which are then driven by stimulated emission towards…

Atomic Physics · Physics 2020-02-25 Michael Peper , Johannes Deiglmayr

The generation of cold molecules is a core topic in the field of cold atoms and molecules, which has advanced relevant research like ultracold chemistry, quantum computation, and quantum metrology. With high atomic phase space density,…

Atomic Physics · Physics 2024-02-27 Li Li , Yi-Jia Liu , Xiao-Long Zhou , Ze-Min Shen , Si-Jian He , Zhao-Di Liu , Jian Wang

Quantum degenerate molecules represent a new paradigm for fundamental studies and practical applications. Association of already quantum degenerate atoms into molecules provides a crucial shortcut around the difficulty of cooling molecules…

Quantum Gases · Physics 2010-08-11 Matt Mackie , Pierre Phou

Two-photon photoassociation of hot magnesium atoms by femtosecond laser pulses, creating electronically excited magnesium dimer molecules, is studied from first principles, combining \textit{ab initio} quantum chemistry and molecular…

We study the time-resolved photoassociation of ultracold sodium in an optical dipole trap. The photoassociation laser excites pairs of atoms to molecular states of large total angular momentum at high intensities (above 20 kW/cm$^{2}$).…

Atomic Physics · Physics 2009-11-13 E. Gomez , A. T. Black , L. D. Turner , E. Tiesinga , P. D. Lett

A strongly coupled ultracold plasma can be used as an excellent test platform for studying many-body interactions associated with various plasma phenomena. In this paper we discuss an approach that makes possible creation of the…

Photoassociation of ultracold atoms induced by chirped picosecond pulses is analyzed in a non-perturbative treatment by following the wavepackets dynamics on the ground and excited surfaces. The initial state is described by a Boltzmann…

Atomic and Molecular Clusters · Physics 2009-06-10 Eliane Luc-Koenig , Mihaela Vatasescu , Francoise Masnou-Seeuws

This theoretical paper investigates the formation of ground state molecules from ultracold cesium atoms in a two-color scheme. Following previous work on photoassociation with chirped picosecond pulses [Luc-Koenig et al., Phys. Rev. A {\bf…

Atomic Physics · Physics 2007-05-23 Christiane P. Koch , Eliane Luc-Koenig , Françoise Masnou-Seeuws

Photoassociation of two ultracold rubidium atoms and the subsequent formation of stable molecules in the singlet ground and lowest triplet states is investigated theoretically. The method employs laser pulses inducing transitions via…

Atomic Physics · Physics 2007-05-23 Christiane P. Koch , Ronnie Kosloff , Françoise Masnou-Seeuws

Chemical reactions can be surprisingly efficient at ultracold temperatures ( < 1mK) due to the wave nature of atoms and molecules. The study of reactions in the ultracold regime is a new research frontier enabled by cooling and trapping…

Atomic Physics · Physics 2017-01-16 Lee R. Liu , Jessie T. Zhang , Yichao Yu , Nicholas R. Hutzler , Yu Liu , Till Rosenband , Kang-Kuen Ni

The methods producing cold molecules from cold atoms tend to leave molecular ensembles with substantial residual internal energy. For instance, Cs2 molecules initially formed via photoassociation of cold Cs atoms are in several vibrational…

Ultracold collisions of neutral atoms and molecules have been of great interest since experimental advances enabled the cooling and trapping of such species. This study is a theoretical investigation of a low-energy collision between an…

Atomic Physics · Physics 2025-11-25 Ahmed A. Elkamshishy , Chris H. Greene
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