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Adsorption of $O_{2}$ molecule on Al surface has been a long standing puzzle for the first principles calculation. We have studied the adsorption of $O_{2}$ molecule on the Al(111) surface using hybrid functionals. In contrast to the…

Materials Science · Physics 2012-10-30 Heng-Rui Liu , Hongjun Xiang , X. G. Gong

The interactions of atomic and molecular hydrogen with bare interstellar dust grain surfaces are important for understanding H2 formation at relatively high temperatures (>20 K). We investigate the diffusion of physisorbed H atoms and the…

Astrophysics of Galaxies · Physics 2019-11-14 Masashi Tsuge , Tetsuya Hama , Yuki Kimura , Akira Kouchi , Naoki Watanabe

Penta-Graphene (PG) was theoretically proposed as a new carbon allotrope with a 2D structure. PG has revealed interesting gas sensing properties. Here, the structural and electronic properties of defective PG lattices interacting with an…

Two-dimensional (2D) materials offer a prospect of membranes that combine negligible gas permeability with high proton conductivity and could outperform the existing proton exchange membranes used in various applications including fuel…

Graphene, Silicene, $\mathrm{MoS}_2$ and other similar two-dimensional structures have unusual electronic properties that lend themselves to exotic device applications. These properties emanate from the fact that the electrons are endowed…

Mesoscale and Nanoscale Physics · Physics 2019-05-01 Sushanta Dattagupta , Manvendra Singh

Ultraviolet photodesorption of molecules from icy interstellar grains can explain observations of cold gas in regions where thermal desorption is negligible. This non-thermal desorption mechanism should be especially important where UV…

Using ab initio calculations, we study the electronic and structural properties of vacancies and hydrogen adsorbates on trilayer graphene. Those defects are found to share similar low-energy electronic features, since they both remove a pz…

Materials Science · Physics 2015-08-19 Marcos G. Menezes , Rodrigo B. Capaz

Adsorption of ammonia at NH3/NH2/H covered GaN(0001) surface was analyzed using results of ab initio calculations. The whole configuration space of partially NH3/NH2/H covered GaN(0001) surface was divided into zones differently pinned…

Materials Science · Physics 2016-11-09 Pawel Kempisty , Stanislaw Krukowski

The understanding of atomic adsorption on graphene is of high importance for many advanced technologies. Here we present a complete database of the atomic adsorption energies for the elements of the Periodic Table up to the atomic number 86…

Well-known effect of mechanical stiffness degradation under the influence of point defects in macroscopic solids can be controversially reversed in the case of low-dimensional materials. Using atomistic simulation, we showed here that a…

Mesoscale and Nanoscale Physics · Physics 2015-08-18 Dmitry G. Kvashnin , Pavel B. Sorokin

Hydrogen adsorption on graphene can be increased by functionalization with Ti. This requires dispersing Ti islands on graphene as small and dense as possible, in order to increase the number of hydrogen adsorption sites per Ti atom. In this…

Materials Science · Physics 2020-02-17 Yuya Murata , Stefano Veronesi , Dongmok Whang , Stefan Heun

Optical reflectivity and transmission measurements over photon energies between 0.2 and 1.2 eV were performed on single-crystal graphene samples on a transparent SiO2 substrate. For photon energies above 0.5 eV, graphene yielded a…

Materials Science · Physics 2009-11-13 Kin Fai Mak , Matthew Y. Sfeir , Yang Wu , Chun Hung Lui , James A. Misewich , Tony F. Heinz

We probe the local inhomogeneities of the electronic properties of graphene at the nanoscale using scanning probe microscopy techniques. First, we focus on the study of the electronic inhomogeneities caused by the graphene-substrate…

Mesoscale and Nanoscale Physics · Physics 2012-10-16 A. Castellanos-Gomez , Arramel , M. Wojtaszek , R. H. M. Smit , N. Tombros , N. Agraït , B. J. van Wees , G. Rubio-Bollinger

In cold astrophysical environments, some molecules are observed in the gas phase whereas they should have been depleted, frozen on dust grains. In order to solve this problem, astrochemists have proposed that a fraction of molecules…

Chemical Physics · Physics 2016-03-02 Minissale Marco , Dulieu François

In this paper we systemically study the optical conductivity and density of states of disorded graphene beyond the Dirac cone approximation. The optical conductivity of graphene is computed by using the Kubo formula, within the framework of…

Mesoscale and Nanoscale Physics · Physics 2011-11-08 Shengjun Yuan , Rafael Roldán , Hans De Raedt , Mikhail I. Katsnelson

We have performed a density functional study of graphene adsorbed on Au(111) surface using both a local density approximation and a semiempirical van der Waals approach proposed by Grimme, known as the DFT-D2 method. Graphene physisorbed on…

Materials Science · Physics 2015-05-27 J. Slawinska , P. Dabrowski , I. Zasada

The geometric and electronic properties of Bi-adsorbed monolayer graphene, enriched by the strong effect of substrate, are investigated by first-principles calculations. The six-layered substrate, corrugated buffer layer, and slightly…

Materials Science · Physics 2016-08-24 S. Y. Lin , S. L. Chang , H. H. Chen , S. H. Su , J. C. A. Huang , M. -F. Lin

Ab initio calculations within the density-functional theory formalism are performed to investigate the ground state, electric charge doping, and electronic properties of titanium and titanium dioxide monolayers adsorbed on a graphene…

Materials Science · Physics 2013-01-17 Jozef Sivek , Ortwin Leenaerts , Bart Partoens , Francois Peeters

Molybdenum supported thin films of ScN, MgO and NaF with a Cu adatom have been studied in the framework of density functional theory. We have observed a charge transfer from the metal/film interface to the Cu atom and investigated its…

Materials Science · Physics 2015-07-14 Pjotrs A. Žguns , Michael Wessel , Natalia V. Skorodumova

Electronic, optical and transport properties of the graphene/ZnO heterostructure have been explored using first-principles density functional theory. The results show that Zn12O12 can open a band gap of 14.5 meV in graphene, increase its…

Materials Science · Physics 2017-06-21 Md Monirojjaman Monshi , Sadegh Mehdi Aghaei , Irene Calizo
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