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Two intermetallic FeAl compounds with Al content of 70.68 and 72.17 at.pct were studied using M\"ossbauer spectroscopy (5 to 296 K) and X-ray diffraction (15 to 300 K). The compounds were found to crystallize in the orthorhombic Cmcm space…

Materials Science · Physics 2021-05-19 Stanisław M. Dubiel , Łukasz Gondek , Tilo Zienert , Jan Żukrowski

The magnetic and lattice properties of the $S$=1/2 quantum-spin-chain ferromagnet, CuAs$_2$O$_4$, mineral name trippkeite, were investigated. The crystal structure of CuAs$_2$O$_4$ is characterized by the presence of corrugated CuO$_2$…

Materials Science · Physics 2015-06-18 K. Caslin , R. K. Kremer , F. S. Razavi , A. Schulz , A. Muñoz , F. Pertlik , J. Liu , M. -H. Whangbo , J. M. Law

Synchrotron x-ray diffraction experiments were performed on BaFe$_2$As$_2$ and Sr(Fe$_{1-x}$Co$_{x}$)$_2$As$_2$ single crystals as a function of temperature and applied magnetic field along the tetragonal $[1 \bar{1} 0]$ direction,…

Superconductivity · Physics 2018-07-02 U. F. Kaneko , C. B. R. Jesus , M. E. Saleta , P. G. Pagliuso , R. R. Urbano , E. Granado

We refined crystal structures of newly found members of the Fe-1111 superconductor family, CaFe\_{1-x}Co\_{x}AsF and SrFe\_{1-x}Co\_{x}AsF (x = 0, 0.06, 0.12) by powder synchrotron X-ray diffraction analysis. The tetragonal to orthorhombic…

The structural and magnetic anomaly of the layered compound SrFeO$_{2}$ were examined by first principles density functional calculations and Monte Carlo simulations. The down-spin Fe 3$d$ electron occupies the $d_{z^2}$ level rather than…

Materials Science · Physics 2008-04-25 H. J. Xiang , Su-Huai Wei , M. -H. Whangbo

We report 75As-NMR measurements of the ternary iron arsenide BaFe2As2. 75As-NMR spectra clearly revealed that magnetic transition occurs at around 131 K in our samples, which corresponds to the emergence of spin density wave. Temperature…

Superconductivity · Physics 2009-11-13 H. Fukazawa , K. Hirayama , K. Kondo , T. Yamazaki , Y. Kohori , N. Takeshita , K. Miyazawa , H. Kito , H. Eisaki , A. Iyo

We systematically measure the superconducting (SC) and mixed state properties of high-quality CsV3Sb5 single crystals with Tc ~ 3.5 K. We find that the upper critical field Hc2(T) exhibits a large anisotropic ratio of Hc2^(ab)/Hc2^(c) ~ 9…

We set forth the structural and magnetic properties of the frustrated spin-$5/2$ triangle lattice antiferromagnet Na$_3$Fe(PO$_4$)$_2$ examined via x-ray diffraction, magnetization, heat capacity, and neutron diffraction measurements on the…

Materials Science · Physics 2022-01-26 Sebin J. Sebastian , A. Jain , S. M. Yusuf , M. Uhlarz , R. Nath

The magnetic structure for the newly discovered iron-arsenide compound \CaFeAs has been studied by neutron powder diffraction. Long-range magnetic order is detected below 85K, with an incommensurate modulation described by the propagation…

Strongly Correlated Electrons · Physics 2011-06-30 P. Manuel , L. C. Chapon , I. S. Todorov , D. Y. Chung , J. -P. Castellan , S. Rosenkranz , R. Osborn , P. Toledano , M. G. Kanatzidis

In the ternary system Sr-Cu-Ge, a clathrate type-I phase, Sr8Cu5.3Ge40.7 (a = 1.06311(3), exists close to the Zintl limit in a small temperature interval. Sr8Cu5.3Ge40.7 decomposes eutectoidally on cooling at 730{\deg}C into (Ge), SrGe2 and…

Materials Science · Physics 2017-02-16 I. Zeiringer , A. Grytsiv , F. Kneidinger , E. Royanian , E. Bauer , G. Giester , M. Falmbigl , P. Rogl

A site-selective $^{27}$Al nuclear magnetic resonance (NMR) study is carried out on the Kondo lattice compound CePtAl$_4$Ge$_2$, which crystallizes in a rhombohedral lattice with quasi-two-dimensional Ce layers forming a triangular lattice…

Strongly Correlated Electrons · Physics 2025-12-11 H. Sakai , S. Shin , S. Kambe , Y. Tokunaga , H. Harima , E. Pomjakushina , T. Park

We report inelastic light scattering studies on Ca(Fe0.97Co0.03)2As2 in a wide spectral range of 120-5200 cm-1 from 5K to 300K, covering the tetragonal to orthorhombic structural transition as well as magnetic transition at Tsm ~ 160K. The…

Superconductivity · Physics 2014-07-11 Pradeep Kumar , D. V. S. Muthu , L. Harnagea , S. Wurmehl , B. Büchner , A. K. Sood

Neutron diffraction and small angle scattering experiments have been carried out on the double-isotopic polycrystalline sample (7Li0.82Fe0.18OD)FeSe. Profile refinements of the diffraction data establish the composition and reveal an…

With the use of lattice dynamics calculation within hybrid HSE06 framework we were able to understand vibrational spectra of MAgF3 M = K, Rb, Cs compounds. Comparative theoretical study uncovered lack of monotonicity in calculated optical…

Materials Science · Physics 2022-01-17 Kacper Koteras , Jakub Gawraczynski , Gasper Tavcar , Zoran Mazej , Wojciech Grochala

We report a study on the anisotropy of superconducting properties in single crystalline Ca10(Pt4-{\delta}As8)(Fe1.79Pt0.21As2)5 with Tc ~13.6 K. Under a field of 5 Oe, the sample reaches fully-diamagnetic state at ~10 K for H//c, and ~8 K…

Superconductivity · Physics 2012-11-09 Qing-Ping Ding , Yuji Tsuchiya , Yue Sun , Toshihiro Taen , Yasuyuki Nakajima , Tsuyoshi Tamegai

Single-layer TaS$_2$ is epitaxially grown on Au(111) substrates. The resulting two-dimensional crystals adopt the 1H polymorph. The electronic structure is determined by angle-resolved photoemission spectroscopy and found to be in excellent…

The interplay of magnetism and superconductivity (SC) has been a focus of interest in condensed matter physics for decades. EuFe2As2 has been identified as a potential platform to investigate interactions between structural, magnetic,…

CoSe$_2$O$_5$ has a crystal structure consisting of zig-zag chains of edge shared CoO$_6$ octahedra running along the c axis, with the chains separated by Se$_2$O$_5^{2-}$ units. Magnetic susceptibility measurements indicate a transition at…

Materials Science · Physics 2012-02-02 Brent C. Melot , Brian Paden , Ram Seshadri , Ambesh Dixit , Gavin Lawes , Emmanuelle Suard

We report detailed measurements of temperature dependence and ab initio lattice dynamical calculations of the phonon density-of-states of two Sr based iron pnictide parent compounds; SrFe2As2 and SrFeAsF. Although both compounds undergo a…

We have synthesized 10 new iron oxyarsenides, K$Ln_2$Fe$_4$As$_4$O$_2$ ($Ln$ = Gd, Tb, Dy, and Ho) and Cs$Ln_2$Fe$_4$As$_4$O$_2$ ($Ln$ = Nd, Sm, Gd, Tb, Dy, and Ho), with the aid of lattice-match [between $A$Fe$_2$As$_2$ ($A$ = K and Cs)…

Superconductivity · Physics 2017-09-13 Si-Qi Wu , Zhi-Cheng Wang , Chao-Yang He , Zhang-Tu Tang , Yi Liu , Guang-Han Cao