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In this paper we study the electrostatic properties of `Janus' spheres with unequal charge densities on both hemispheres. We introduce a method to compare primitive-model Monte Carlo simulations of the ionic double layer with predictions of…

Soft Condensed Matter · Physics 2012-09-18 Joost de Graaf , Niels Boon , Marjolein Dijkstra , René van Roij

We apply general variational techniques to the problem of the counterion distribution around highly charged objects where strong condensation of counterions takes place. Within a field-theoretic formulation using a fluctuating electrostatic…

Soft Condensed Matter · Physics 2009-11-07 Roland R. Netz , Henri Orland

In the study of colloidal, biological and electrochemical systems, it is customary to treat surfaces, macromolecules and electrodes as homogeneously charged. This simplified approach is proven successful in most cases, but fails to describe…

Soft Condensed Matter · Physics 2022-08-04 Ram M. Adar , David Andelman , Haim Diamant

We analyze theoretically the electrostatic interaction of surface-charged colloids at water interfaces with special attention to the experimentally relevant case of large charge densities on the colloid-water interface. Whereas linear…

Soft Condensed Matter · Physics 2007-11-13 D. Frydel , S. Dietrich , M. Oettel

Screening is a ubiquitous phenomenon through which the polarization of bound or mobile charges tends to reduce the strengths of electric fields inside materials. Here we show how photoexcitation can be used as a knob to transform…

Mesoscale and Nanoscale Physics · Physics 2025-01-29 Ying Xiong , Mark S. Rudner , Justin C. W. Song

Screening is one of the most important concepts in the study of charged systems. Near a dielectric interface, the ion distribution in a salt solution can be highly nonuniform. Here, we develop a theory that self-consistently treats the…

Soft Condensed Matter · Physics 2016-05-04 Rui Wang , Zhen-Gang Wang

We revisit the popular notion of effective or renormalized charge, which is a concept of central importance in the field of highly charged colloidal or polyelectrolyte solutions. Working at the level of a linear Debye-H\"uckel like theory…

Soft Condensed Matter · Physics 2009-11-07 Emmanuel Trizac , Lyderic Bocquet , Miguel Aubouy

Ions in ionic liquids and concentrated electrolytes reside in a crowded, strongly-interacting environment, leading to the formation of discrete layers of charges at interfaces. Here, we propose a continuum theory that captures the…

Screening effects of electrons on inhomogeneous nuclear matter, which includes spherical, slablike, and rodlike nuclei as well as spherical and rodlike nuclear bubbles, are investigated in view of possible application to cold neutron star…

Nuclear Theory · Physics 2009-11-10 Gentaro Watanabe , Kei Iida

We propose a model for the calculation of renormalized charges and osmotic properties of mixtures of highly charged colloidal particles. The model is a generalization of the cell model and the notion of charge renormalization as introduced…

Soft Condensed Matter · Physics 2009-03-19 Aldemar Torres , Gabriel Tellez , Rene van Roij

The problem of the equilibrium state of the charged many-particle system above dielectric surface is formulated.We consider the case of the presence of the external attractive pressing field and the case of its absence. The equilibrium…

Statistical Mechanics · Physics 2009-05-21 Dmytro M. Lytvynenko , Yuriy V. Slyusarenko

The interfacial screening charge that arises to compensate electric fields of dielectric or ferroelectric thin films is now recognized as the most important factor in determining the capacitance or polarization of ultrathin ferroelectrics.…

Materials Science · Physics 2015-05-20 Matthew F. Chisholm , Weidong Luo , Mark P. Oxley , Sokrates T. Pantelides , Ho Nyung Lee

In this work, we use Molecular Dynamics and Lattice-Boltzmann simulations to study the properties of charged Janus particles in an electric field. We show that for relatively small net charge and thick electrostatic diffuse layer mobilities…

Soft Condensed Matter · Physics 2017-09-12 Taras Y. Molotilin , Vladimir Lobaskin , Olga I. Vinogradova

We show that topological defects in an ion-doped nematic liquid crystal can be used to manipulate the surface charge distribution on chemically homogeneous, charge-regulating external surfaces, using a minimal theoretical model. In…

Soft Condensed Matter · Physics 2020-07-16 Miha Ravnik , Jeffrey C. Everts

The properties of surfaces with charge-regulated patches are studied using non-linear Poisson-Boltzmann theory. Using a mode expansion to solve the non-linear problem efficiently, we reveal the charging behaviour of Debye-length sized…

Soft Condensed Matter · Physics 2015-05-20 Niels Boon , René van Roij

A novel strategy is introduced in order to include variations of the nonlinearity into the nonlinear schrodinger Equation. This technique, which relies on renormalization, is in particular well adapted to nanostructured optical systems…

Optics · Physics 2015-06-09 P. Colman

Janus monolayers have long been captivated as a popular notion for breaking in-plane and out-of-plane structural symmetry. Originated from chemistry and materials science, the concept of Janus functions have been recently extended to…

We construct, numerically, stationary and spherically symmetric nontopological soliton solutions in the system composed of a complex scalar field, a U(1) gauge field, and a complex Higgs scalar field that causes spontaneous symmetry…

High Energy Physics - Theory · Physics 2019-12-06 Hideki Ishihara , Tatsuya Ogawa

Charge regulation is an important aspect of electrostatics in biological and colloidal systems, where the charges are generally not fixed, but depend on the environmental variables. Here, we analyze the charge regulation mechanism in…

Soft Condensed Matter · Physics 2018-08-01 Anže Lošdorfer Božič , Rudolf Podgornik

This work reveals a counter-intuitive but basic process of ionic screening in nano-fluidic channels. Steady-state numerical simulations and mathematical analysis show that, under significant longitudinal ionic transport, the screening ionic…

Fluid Dynamics · Physics 2017-01-10 Xin Zhu , Lingzi Guo , Sheng Ni , Xingye Zhang , Yang Liu
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